| MSDS | : | ISOCYANATE ACTIVATORS, 782S | | CAS | : | 123-86-4
141-78-6
64742-95-6
28182-81-2
822-06-0 | | NAME | : | n-butyl acetate (sara iii)
ethyl acetate (sara iii)
aromatic hydrocarbons. vp: 10 @ 20c.
isocyanic acid, hexamethylene ester, polymers (aliphatic
1,6-diisocyanatohexane (hexamethylene diisocyanate)
spill proc: soln over spill & allow to sit 10 min, minimum.
ing 06: (tergitol tmn 10) and 80% water; or 0-10% ammonia,
supp data: recurrent overexp may rslt in liver & kidney
ing 08: doses that are toxic to the mother. aliphatic
ing 09: itching, swelling. overexp may cause asthma-like
ing 10: lung sensit. this eft may be delayed for several
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===================== Product Identification =====================
MSDS NAME:ISOCYANATE ACTIVATORS, 782S
NIIN:00N015466
MSDS Number: BKMRX
=== Responsible Party ===
Company:E.I. DUPONT DE NEMOURS & CO INC
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:19898
=== Contractor Identification ===
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
Company:E.I. DUPONT DE NEMOURS & CO., INC.
Box:1635
CAGE:19898
============= Composition/Information on Ingredients =============
Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ETHYL ACETATE (SARA III)
CAS:141-78-6
RTECS #:AH5425000
OSHA PEL:400 PPM
ACGIH TLV:400 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AROMATIC HYDROCARBONS. VP: 10 @ 20C.
CAS:64742-95-6
OSHA PEL:25 PPM (MFR)
ACGIH TLV:25 PPM (MFR)
Name:ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS (ALIPHATIC
POLYISOCYANATE).
CAS:28182-81-2
RTECS #:NQ9170000
Name:1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)
CAS:822-06-0
RTECS #:MO1740000
ACGIH TLV:0.005 PPM; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SPILL PROC: SOLN OVER SPILL & ALLOW TO SIT 10 MIN, MINIMUM.
TYPICAL DECONTAMINATION SOLNS ARE: 20% SURFACTANT (ING 07)
RTECS #:9999999ZZ
Name:ING 06: (TERGITOL TMN 10) AND 80% WATER; OR 0-10% AMMONIA,
2-5% DETERGENT, BALANCE WATER.
RTECS #:9999999ZZ
Name:SUPP DATA: RECURRENT OVEREXP MAY RSLT IN LIVER & KIDNEY
INJURY. HAS BEEN TOXIC TO THE FETUS IN LAB ANIMALS AT (ING 09)
RTECS #:9999999ZZ
Name:ING 08: DOSES THAT ARE TOXIC TO THE MOTHER. ALIPHATIC
POLYISOCYANATE: RPTD EXPOS MAY CAUSE ALLERGIC SKIN RASH, (ING 10)
RTECS #:9999999ZZ
Name:ING 09: ITCHING, SWELLING. OVEREXP MAY CAUSE ASTHMA-LIKE
RXNS W/SHORTNESS OF BREATH, WHEEZING, COUGH OR PERM (ING 11)
RTECS #:9999999ZZ
Name:ING 10: LUNG SENSIT. THIS EFT MAY BE DELAYED FOR SEVERAL
HRS AFTER EXPOSURE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:GENL EFTS: INGEST: GI DISTRESS. INHAL:
MAY CAUSE NOSE & THROAT IRRIT. RPTD/PRLNG OVEREXP TO SOLV MAY LEAD
TO PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS
OF COORD ARE SIGNS THAT SO LV LEVELS ARE TOO HIGH. EXPOS TO
ISOCYANATES MAY CAUSE ASTHMA-LIKE RXNS W/SHORTNESS OF BREATH, (SEE
EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: WHEEZING, COUGH OR LUNG SENSIT. THIS
EFT MAY BE DELAYED FOR SEVERAL HRS AFTER EXPOS. SKIN/EYE: MAY CAUSE
IRRIT/BURNING OF EYES. RPTD/PRLNG LIQ CNTCT MAY CAUSE SKIN IRRIT
W/DISCOMFORT & DERM. SPECIFIC EFTS: BUTYL ACETATE: RECURRENT
OVEREXP MAY RSLT IN LIVER/KIDNEY INJURY. TESTS FOR EMBRYOTOXIC (SEE
SUPP DATA)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/:LUNG/BRTHG
PROBS/PRIOR RXN TO ISOCYANATES MUST NOT BE EXPOSED TO VAPS/SPRAY
MISTS; PREEXISTING LUNG DISEASE/ASTHMA/BRTHG DFCLTY MAY HAVE
INCREASED SUSCEPTIBILITY TO TOX OF EXCESS EXPOS.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD IMMEDIATELY AND HAVE NAMES OF INGREDIENTS
AVAILABLE. INHAL: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST,
REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY PERSISTS, OR OCCURS
LATER, CO NSULT MD. EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES; CALL MD. SKIN: WASH WITH SOAP AND WATER. IF
IRRITATION OCCURS, CONTACT MD.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:20.0F,-6.7C
Lower Limits:0.9%
Upper Limits:11.2%
Extinguishing Media:WATER SPRAY, FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL
CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS
FLAMM VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE
MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW THE FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT BREATHE VAPS. DO NOT GET IN EYES OR ON
SKIN. WEAR A POS PRESS SUPPLIED AIR VAP/PARTICULATE RESP
(NIOSH/MSHA TC-19C), EYE PROT, GLOVES & PROT CLTHG. REMOVE SOURCES
OF IGNIT. ABSORB W/INERT MATL. VENT AREA. POUR LIQ DECONTAMINATE
(SEEINGRED 06)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECS. KEEP AWAY FROM
HEAT, SPARKS & FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING
WITHOUT A NIOSH/MSHA APPROVED RESPIRATOR OR APPROPRIATE
VENTILATION. DO NOT BREATHE VAPORS OR MISTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR POS PRESS SUPPLIED AIR RESP (NIOSH/MSHA
TC-19C) WHILE MIXING ACTIVATOR W/ANY PAINT/CLEAR ENAMEL, DURING
APPLICATN & UNTIL ALL VAPS/SPRAY MISTS EXHSTD. DO NOT PERMIT ANYONE
W/O PROT IN PAINT AREA. FOLLOW RESP MFR'S DIRECTIONS FOR USE.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
% VOLAT: 19.4-80.9 (VOL), 15.3-76.0 (WT). EFTS OF OVEREXP: ACT IN
ANIMALS HAS BEEN INCONCLUSIVE. ETHYL ACETATE: PRLNG/RPTD HIGH EXPOS
OF LAB ANIMALS RSLTD IN SECONDARY ANEMIA W/INCREASE IN WHITE BLOOD
CELLS; FATTY DEGENERATION, CLOUDY SWELLING & EXCESS OF BLOOD IN
VARIOUS ORGANS. AROMATIC HYDROCARBON: (SEE INGRED 08)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:169F,76C
Vapor Pres:SEE INGRED
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MISCIBLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO*2, SMOKE
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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