spill proc:broom & dissolve matl in water. dispose of waste waste disp meth:matl by adding hydrogen peroxide (1 pint of ing 10:hypochlorite to be neut) then dilute neut matl ing 11:neut matl should be flushed to sewer. unneut matl ing 12:w/treatment plant operation. for on-site neut, ing 13:peroxide soln over all spilled matl then flush area ing 14:using/disposing of chem matls and/or their cntnrs to ing 15:matls and/or their cntnrs i/a/w clean air ct. clean ing 16:federal, state, or local laws/regulations regarding other prec:prod. such use may cause violent rxn leading to ing 18:to prod. may cause fire/explo if mixed w/other ing 19:matl such as oil, kerosene, gasoline, paint prods & calcium hypochlorite (sara iii) inert (nuisance) dust (includes 5.5-20% moisture) supdat:hypochlorite, if swallowed, causes sev burns to ing 3:calcium hypochlorite prdced pos responses in in-vitro ing 4:aberrations in chinese hamster fibroblasts. in whole ing 5:ranging from 20-160mg/kg prdced no cmpd related to first aid proc:immed to hospital/phys. if uncon, or in ing 7:vomit/give anything by mouth to uncon person. note to
LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CORROSION OF ALL TISSUE
CONTACTED. EYE IRRITATION: CORROSIVE. PRIMARY SKIN IRRITATION:
CORROSIVE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:CORROSION OF ALL TISSUE CONTACTED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN/EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, CALL MD.
INGEST: GIVE LARGE AMOUNTS OF WATER TO DRINK. DO NOT INDUCE
VOMITING, CALL MD. INHAL: REMOVE VICTIM TO FRESH AIR, CALL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:NOT COMBUSTIBLE BUT MAY IGNITE COMBUST
MATLS/ORGANIC MATTER UPON CNTCT. FLOOD W/WATER TO KEEP FIRE-EXPOSED
CNTNRS COOL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . FIRES CAN ERUPT AND SPREAD RAPIDLY.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
Spill Release Procedures:REMOVE ALL IGNIT SOURCES. WEAR NIOSH/MSHA
APPRVD RESP FOR DUST/CHLORIDE. FOLLOW OSHA REGS FOR RESP USE (SEE
29 CFR 1910.134). CHEM WORK GOGGLES, COVERALLS & RUBBER, NEOPRENE
OR PVC GLOVES/BOOTS. CLEAN UP IN A MANNER TO MINIMIZE CONTAM
(SEESUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
PLACE AWAY FROM COMBUSTIBLE MATERIALS. DRUMS MAY RUPTURE IF EXPOSED
TO HEAT.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT
TAKE INTERNALLY. AVOID BREATHING DUST. PROTECT AGAINST PHYSICAL
DAMAGE.
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:LOCAL EXHAUST VENTILATION REQUIRED WHERE EXPOSURE TO DUST
MIGHT OCCUR.
Protective Gloves:RUBBER, NEOPRENE OR PVC.
Eye Protection:CHEM WRKRS GOGGLES.SEE PROT.EQPT.
Other Protective Equipment:COVERALLS AND IMPERVIOUS BOOTS.EYE PROT:FULL
LGTH FACE SHIELD. EMERG. EYE WASH/DELUGE SHOWERS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH: 1% AQ SOLN 10.5-11.5. LD50-LC50 MIX: (ORAL,RAT)=850 MG/KG,
(SKN,RBT)>2 G/KG. SPILL PROC: W/ORG MATL. DO NOT RTN MATL TO ORIG
CNTNR. PLACE IN FRESH CNTNR & ISOLATE OUTSIDE OR IN WELL VENTED
AREA. D O NOT SEAL CNTNR. FLUSH ANY RESIDUAL MATL W/LG QTYS OF
WATER. WASH ALL CONTAM CLTHG BEFORE REUSE. LG SPILL: USE EMER NO.
HCC:D1
Melt/Freeze Pt:M.P/F.P Text:351F,177C
pH:SUPDAT
Solubility in Water:21% @ 21C
Appearance and Odor:WHITE FREE FLOWING GRANULAR SOLID WITH CHLORINOUS
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SOLVENTS, ACIDS, POOL CHEMICALS (ISOCYANURATES), ORGANIC MATERIALS. DO
NOT MIX WITH ANYTHING BUT WATER.
Stability Condition to Avoid:UNSTABLE AT 350F. WHEN HEATED TO 350F IT
DECOMPOSES RAPIDLY WITH EVOLUTION OF OXYGEN AND HEAT.
Hazardous Decomposition Products:CHLORINE.
Waste Disposal Methods:DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS
USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS
MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY
AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.