===================== Product Identification =====================
MSDS NAME:SUPER UNLEADED GASOLINE/PREMIUM
NIIN:00-148-7104
MSDS Number: BKPGC
=== Responsible Party ===
Company:CONOCO INC
Address:600 N DAIRY ASHFORD RD RM 3012
Box:4784
City:HOUSTON
State:TX
ZIP:77210-4784
Country:US
Info Phone Num:713-293-5550
Emergency Phone Num:713-293-5550/800-424-9300(CHEMTREC)
CAGE:15445
=== Contractor Identification ===
Company:CONOCO INC
Address:600 N DAIRY ASHFORD RD RM 3012
Box:4784
City:HOUSTON
State:TX
ZIP:77210-4784
Country:US
Phone:800-441-3637/800-424-9300(CHEMTREC)
CAGE:15445
============= Composition/Information on Ingredients =============
Name:HYDROCARBONS
Fraction by Wt: > 50% %
Other REC Limits:NONE SPECIFIED
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0.1-4.9%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CUMENE (SARA III)
CAS:98-82-8
RTECS #:GR8575000
Fraction by Wt: 1% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 50 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:1,2,4-TRIMETHYLBENZENE (SARA III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 2% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9192
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: < 15% %
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 12% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV GASOLINE - 300 PPM TWA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CHRONIC EXPOSURE TO BENZENE MAY
CONTRIBUTE TO LEUKEMIA. BENZENE CAN BE TOXIC TO BLOOD AND
BLOOD-FORMING TISSUES. PETROLEUM HYDROCARBONS MAY CAUSE IRRITATION
TO EYES, SKIN, LUNGS. EXTREME EXPOSURE OR A SPIRATION INTO LUNGS
MAY CAUSE PNEUMONIA. OVEREXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS, UNCONSCIOUSNESS.
Explanation of Carcinogenicity:BENZENE IS LISTED AS CARCINOGEN OR
POTENTIAL CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:LEUKEMIA, SKIN IRRITATION, EYE IRRITATION,
WEAKNESS, HEADACHE, NAUSEA, CONFUSION, BLURRED VISION, DROWSINESS,
DIZZINESS, SLURRED SPEECH, FLUSHED FACE, UNCONSCIOUSNESS,
CONVULSIONS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
CALL A PHYSICIAN. SKIN: IMMEDIATELY WASH SKIN WITH SOAP AND WATER.
IF IRRITATION DEVELOPS, CALL A PHYSICIAN. INHALATION: REMOVE TO
FRESH AIR . IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. INGESTION:
DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-50F,-46C
Lower Limits:< 1 %
Upper Limits:8 %
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE TO EXTINGUISH, BUT
WATER SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE. DO NOT ENTER ENCLOSED
OR CONFINED SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT INCLUDING
RESPIRATORY PROTECTION.
================== Accidental Release Measures ==================
Spill Release Procedures:MATERIAL IS FLAMMABLE. CONTAIN SPILL
IMMEDIATELY IN SMALLEST POSSIBLE AREA. RECOVER AS MUCH AS POSSIBLE
BY VACUUMING, FOLLOWED BY RECOVERING RESIDUAL BY USE OF ABSORBENT
MATERIALS. AVOID WASHING, DRAI NING OR DIRECTING MATERIAL TO STORM
OR SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN OR
CLOTHING.
Other Precautions:NOTE TO PHYSICIAN: GASTRIC LAVAGE BY QUALIFIED
MEDICAL PERSONNEL MAY BE CONSIDERED, DEPENDING ON QUANTITY OF
MATERIAL INGESTED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT APPROPRIATE NIOSH-APPROVED RESPIRATORY
PROTECTION WHERE NECESSARY TO MAINTAIN EXPOSURES BELOW ACCEPTABLE
LIMITS. PROPER RESPIRATOR SELECTION SHOULD BE DETERMINED BY
ADEQUATELY TRAINED PERSONNEL AND BASED ON THE CONTAMINANTS.
Ventilation:USE SUFFICIENT VENTILATION TO MAINTAIN ATMOSPHERIC
CONCENTRATIONS BELOW PERMISSIBLE EXPOSURE LIMITS. AVOID SPARKING.
Protective Gloves:NBR OR NEOPRENE FOR PROLONGED EXPOSURE
Eye Protection:CHEMICAL SPLASH GOGGLES/FACE SHIELD
Other Protective Equipment:SUFFICIENT PROTECTIVE CLOTHING TO MINIMIZE
SKIN EXPOSURE. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING, DRINKING OR SMOKING.
Supplemental Safety and Health
THIS PRODUCT CONTAINS PETROLEUM HYDROCARBONS WHICH ARE CONSIDERED
HAZARDOUS IF SPILLED IN NAVIGABLE WATERS. REPORTABLE QUANTITY IS
ANY SMOUNT THAT PRODUCES A FILM OR SHEEN UPON OR DISCOLORATION OF
THE WATER SURFACE OR ADJOINING SHORELINE.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:=29.3C, 84.9F
Melt/Freeze Pt:M.P/F.P Text:NONE GIVEN
Vapor Pres:275-475
Vapor Density:> 1
Spec Gravity:0.70-0.77
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:RED DYED, PINK OR COLORLESS LIQUID, GASOLINE ODOR
Percent Volatiles by Volume:100 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID HEAT, FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE MAY BE FORMED FROM
INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE AS MUCH OF THE RECOVERABLE PRODUCT AS
POSSIBLE. TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL MUST BE
IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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