===================== Product Identification =====================
MSDS NAME:SUPER UNLEADED GASOLINE
NIIN:00-148-7104
MSDS Number: BKPGD
=== Responsible Party ===
Company:COASTAL CORP
Address:9 GREENWAY PLAZA
City:HOUSTON
State:TX
ZIP:77046
Country:US
Info Phone Num:713-877-1400
Emergency Phone Num:713-877-1400
Preparer's Name:DELNO D. MALZAHN, CIH
CAGE:46684
=== Contractor Identification ===
Company:COASTAL CORP
Address:9 GREENWAY PLAZA
Box:City:HOUSTON
State:TX
ZIP:77046
Country:US
Phone:713-877-6732
CAGE:46684
============= Composition/Information on Ingredients =============
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0-5.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 0-25.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 0-25.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 0-5.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: <3.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:HEXANE (ISOMERS OTHER THAN N-HEXANE)
Fraction by Wt: < 6.5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:500 PPM
Name:1,2,4-TRIMETHYLBENZENE (SARA III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 0 - 5.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9192
Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: < 9.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9192
Name:PENTANE
CAS:109-66-0
RTECS #:RZ9450000
Fraction by Wt: < 2.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM/750 STEL
ACGIH TLV:600 PPM/750STEL;9293
Name:TERT-BUTYL ALCOHOL (SARA III)
CAS:75-65-0
RTECS #:EO1925000
Fraction by Wt: 0 - 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM
ACGIH TLV:100PPM 9394
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 0 - 15%
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SLIGHT TO MODERATE EYE IRRITATION,
MODERATE SKIN IRRITATION, MUCUOUS MEMBRANE IRRITATION, RESPIRATORY
TRACT IRRITATION, ASPHYXIANT, CENTRAL NERVOUS SYSTEM DAMAGE.BENZENE
IS A CARCINOGEN.IT CAUSES DAMA GE TO THE BLOOD FORMING ORGANS,
WHICH LEADS TO ANEMIA AND LEUKEMIA.
Explanation of Carcinogenicity:BENZENE, A COMPONENT OF THIS PRODUCT, IS
LISTED AS CARCINOGENIC BY NTP, IARC AND OSHA.
Effects of Overexposure:HEADACHE, NAUSEA, DROWSINESS, FATIGUE,
PNEUMONITIS, PULMONARY EDEMA, CENTRAL NERVOUS SYSTEM DEPRESSION.
GASTRITIS, LOSS OF CONSCIOUSNESS, CONVULSIONS, CYANOSIS, CAPILLARY
HEMORRHAGING OF LUNG AND INTE RNAL ORGANS.
Medical Cond Aggravated by Exposure:OVEREXPOSURE MAY AGGRAVATE
PRE-EXISTING DERMATITIS OR RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
Eyes: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES.
SPEED AND THOROUGHNESS IN RINSING EYES ARE IMPORTANT TO AVOID
PERMANENT INJURY. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED
AREAS WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. IF
BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. INGESTION: DO
NOT INDUCE VOMITING. GET MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=-42.8C, -45.F
Autoignition Temp:=257.2C, 495.F
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE
Fire Fighting Procedures:USE A SMOTHERING TECHNIQUE FOR EXTINGUISHING
FIRE OF THIS PRODUCT. DO NOT USE A FORCED WATER STREAM DIRECTLY ON
GASOLINE FIRES AS THIS WILL SCATTER FIRE.
Unusual Fire/Explosion Hazard:FLOWING GASOLINE CAN BE IGNITED BY SELF-
GENERATED STATIC ELECTRICITY. RUNOFF TO SEWER MAY CREATE FIRE OR
EXPLOSION HAZARD DOWNSTREAM FROM THE SOURCE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF HEAT OR IGNITION INCLUDING
INTERNAL COMBUSTION ENGINES AND POWER TOOLS. CLEAN-UP SPILL, BUT DO
NOT FLUSH TO SEWER OR SURFACE WATER. VENTILATE AREA AND AVOID
BREATHING VAPORS OR MISTS .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
A DRY COOL PLACE, AWAY FROM INCOMPATIBLE MATERIALS OR SOURCES OF
HEAT OR IGNITION.
Other Precautions:GROUND AND BOND ALL TRANSFER AND STORAGE EQUIPMENT TO
PREVENT STATIC SPARKS AND EQUIP WITH SELF CLOSING VALVES, PRESSURE
VACUUM BUNGS AND FLAME ARRESTORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPROVED RESPIRATORY PROTECTIVE EQUIPMENT IN
SITUATIONS WHERE AIRBORNE CONCENTRATIONS MAY EXCEED OCCUPATIONAL
EXPOSURE LEVELS.
Ventilation:PROVIDE ADEQUATE VENTILATION TO KEEP MISTS OR VAPORS BELOW
PERMISSIBLE LEVELS AND TO PREVENT EXPLOSIVE ATMOSPHERES.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:REMOVE CONTACT LENSES;CHEMICAL GOGGLES
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO AVOID SKIN
CONTACT. EYEWASH AND SHOWER SHOULD BE AVAILABLE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CLOTHES AFTER USE.
Supplemental Safety and Health
EMPTY CONTAINERS MAY CONTAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE
DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOU
RCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:=26.7C, 80.F
Vapor Pres:325-525
Vapor Density:3-4
Spec Gravity:0.7-0.77
Viscosity:1.4CST@104F
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE FLUID, AROMATIC ODOR
Percent Volatiles by Volume:100 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS, HALOGENS, STRONG ACIDS AND ALKALIES.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES AND
BUILD-UP OF STATIC ELECTRICITY.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
HYDROCARBONS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE THROUGH A LICENSED WASTE DISPOSAL
COMPANY. FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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