===================== Product Identification =====================
MSDS NAME:LPGAS PROPANE W/ODORANT
NIIN:00-269-4299
MSDS Number: BKYKC
=== Responsible Party ===
Company:EXXON COMPANY USA
Box:2180
City:HOUSTON
State:TX
ZIP:77252-2180
Info Phone Num:(713) 656-5949 656-2443
Emergency Phone Num:(713) 656-5949 656-2443
CAGE:DO849
=== Contractor Identification ===
Company:EXXON COMPANY U.S.A.
Box:2180
City:HOUSTON
State:TX
ZIP:77252-2180
Country:US
Phone:713-656-5949 / 713-656-3424
CAGE:29700
Company:EXXON COMPANY USA
Box:2180
City:HOUSTON
State:TX
ZIP:77252-2180
Country:US
Phone:713-656-5949; 800-298-4007
CAGE:DO849
============= Composition/Information on Ingredients =============
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 100%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
Name:ODORANT
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): >5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: ASPHYXIATION. SKIN:
FROSTBITE, REMOVE OILS, IRRITATION, & DERMATITIS. EYES: IRRITATION.
INGESTION: HARMFUL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: ASPHYXIATION. SKIN: FROSTBITE,
REMOVE OILS, IRRITATION, & DERMATITIS. EYES: IRRITATION. INGESTION:
HARMFUL.
======================= First Aid Measures =======================
First Aid:SKIN: TREAT FOR FROSTBITE. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR OR OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING.
EYES: OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:<0F
Lower Limits:2.1%
Upper Limits:9.5%
Extinguishing Media:FOLLOW THE NFPA, FIRE PROTECTION GUIDE ON HAZARDOUS
MATERIALS.
Fire Fighting Procedures:STOP FLOW OF GAS. USE WATER TO KEEP
FIRE-EXPOSED CONTAINERS COOL/PROTECT PERSONNEL. USE WATER SPRAY TO
DISPERSE GAS/VAPOR. USE SCBA IN ENCLOSED/CONFINED AREAS.
Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 842F. FLAMMABLE
LIQUID.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF & ELIMINATE IGNITION SOURCES.
EVACUATE AREA. VENTILATE CONFINED SPACES. OPEN ALL WINDOWS & DOORS.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/PILOT
LIGHTS/STATIC ELECTRICITY/OPEN FLAME/KEEP CLOSED WHEN NOT IN USE.
AVOID BREATHING GASESVAPORS/FUMES & CONTACT W/SKIN.
Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE/BE DANGEROUS. DON'T
PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND, MAY EXPLODE/CAUSE
INJURY/DEATH. WORK ON TANKS REFER TO OSHA/GOVT/INDUSTRIAL
REFERENCES FOR CLEANING/RE PAIRING/WELDING/CONTEMPLATED OPERATIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE SUPPLIED-AIR RESPIRATOR IN CONFINED OR
ENCLOSED AREAS.
Ventilation:USE SUFFICIENT VENTILATION TO KEEP
EXPLOSIVE CONCENTRATIONS OF VAPOR IN AIR. EXPLOSION-PROOF EQUIP.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GLASSES
Other Protective Equipment:CHEMICAL RESISTANT APRON OR OTHER CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES
BEFORE REUSE. WASH AFTER CONTACT/BEFORE BREAKS/MEALS/END OF DAY. NO
SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text: -49 TO 32F
Vapor Pres: 208 PSIG
Vapor Density:1.5
Spec Gravity:0.50
pH: 7
Solubility in Water:NEGLIGIBLE
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS SUCH AS LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM OR
CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:HEAT, FLAME, SPARKS, PILOT LIGHTS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:FUMES, SMOKE, CO, ALDEHYDES, & OTHER
PRODUCTS OF INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:HIGH VOLATILITY OF MATERIAL WILL CAUSE EXTREMELY
RAPID EVAPORATION, NO DISPOSAL METHOD IS NEEDED OR SHOULD BE
ATTEMPTED. CONTAINERS SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY
MANNER IN ACCORDANCE W/L OCAL/STATE/FED REGS. FLAMMABLE LIQUID.
UN1075.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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