5: disassociate from it over intermittent periods, 6: periods of weeping until clearance is achieved. 7: together w/lachrymatory eft, & it is important to 8: will normally occur w/in a matter of hours, even 9: stuck together apply lots of warm h*2o to lips & 10: mouth. peel/roll lips apart. do not try & pull 11: impossible to swallow cyanoacrylate. adhesive 12: adhesive in 1/2 to 2 days. in case a lump forms 13: lump when it detaches. burns: cyanoacrylates ing 14: drop will incr temp enough to cause burn. burns shd 15: is rels from tissue as described above. surgery: 16: to separate accidentally bonded skin. efts of ethyl cyanoacrylate hydroquinone (sara iii) sulfur dioxide (sara iii) acrylic polymer supp data: adhesion on eyeball: cyanoacrylate introduced
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CYANOACRYLATE ADHESIVE IS A VERY FAST
SETTING AND STRONG ADHESIVE. IT BONDS HUMAN TISSUE INCLUDING SKIN
IN SECONDS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EXPERIENCE HAS SHOWN THAT ACCIDENTS DUE TO CYANOACRYLATES ARE
HANDLED BEST BY PASSIVE, NON-SURGICAL FIRST AID. TREATMENT OF
SPECIFIC TYPES OF ACCIDENTS ARE GIVEN BELOW. SKIN ADHESION: FIRST
IMMERSE BO NDED SURFS IN WARM SOAPY H2O. PEEL/ROLLSURFS APART W/AID
OF BLUNT EDGE: SPATULA, OR TEASPOON HNDL; THEN REMOVE ADHESIVE FROM
SKIN W/ SOAP & H2O. DO NOT TRY & PULL SURFS APART W/DIRECT (SUPP
DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>200F,>93C
Extinguishing Media:CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
Spill Release Procedures:FLOOD WITH WATER TO POLYMERIZE COMPLETELY.
SOLID POLYMER IS NON HAZARDOUS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AT 75 F OR BELOW TO MAXIMIZE
SHELF LIFE. AVOID CONTACT WITH SKIN OR EYES. AVOID BREATHING VAPOR.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: OPPOSING ACTION. EYELID TO EYELID/EYEBALL ADHESION: IN
EVENT THAT EYELIDS ARE STUCK TOGETHER/BONDED TO EYEBALL, WASH THORO
W/WARM H2O & APPLY GAUZE PATCH. EYE WILL OPEN W/OUT FURTHER A
CTION, TYPICALLY IN 1-4 DAYS. THERE WILL BE NO RESIDUAL DAMAGE. DO
NOT TRY TO OPEN EYES BY MANIPULATION. (SEE ING 5)
HCC:N1
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:<0.2 MM
Vapor Density:3
Spec Gravity:1.1
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK LIQUID, SHARP ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES OR ALKALIES.
Stability Condition to Avoid:HIGH HUMIDITY, HIGH TEMPERATURE AND ULTRA
VIOLET LIGHT.
Hazardous Decomposition Products:NONE.
Waste Disposal Methods:AFTER POLYMERIZATION AS ABOVE, LANDFILL OR
INCINERATE FOLLOWING FEDERAL, STATE, AND LOCAL REGULATIONS.
PHTHALIC ANHYDRIDE IS LISTED BY EPA AS HAZARDOUS WASTE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.