===================== Product Identification =====================
MSDS NAME:MERCURIC OXIDE
NIIN:00-247-0599
MSDS Number: BMTWY
=== Responsible Party ===
Company:MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION
Address:PARIS BYPASS
Box:M
City:PARIS
State:KY
ZIP:40361
Country:US
Info Phone Num:800-354-2050(PRESS 3)/314-982-5000
Emergency Phone Num:800-354-2050/314-539-1600
CAGE:62910
=== Contractor Identification ===
Company:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910
============= Composition/Information on Ingredients =============
Name:MERCURIC OXIDE (SARA III)
CAS:21908-53-2
RTECS #:OW8750000
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1 MG HG/M3;SKIN;C
ACGIH TLV:0.1 MG HG/M3; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS 18 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALE:IRRITATION,SORE
THROAT,COUGHING,LABORED BREATHING & HEADACHE.EYE:MAY CAUSE
IRRITATION/ULCERATION OF CORNEA.SKIN:MAY CAUSE
IRRITATION,DERMATITIS/SENSITIVITY.MAY BE ABSORBED THROUGH SKIN.OR
AL:MAY CAUSE BURNS,ABDOMINAL PAIN,VOMITING,BLOODY DIARRHEA,COLLAPSE
& EVEN DEATH.CHRONIC-CAN PRODUCE CNS & KIDNEY DAMAGE
Effects of Overexposure:INHALATION MAY CAUSE IRRITATION OF THE
RESPIRATORY TRACT, SORE THROAT, COUGHING, LABORED BREATHING &
HEADACHE. MAY CAUSE EYE IRRITATION/ULCERATION. MAY CAUSE SKIN
IRRITATION, DERMATITIS/SENSITIVITY. M AY BE ABSORBED THROUGH SKIN.
ORALLY MAYCAUSE BURNS, ABDOMINAL PAIN, VOMITING, BLOODY DIARRHEA,
COLLAPSE & EVEN DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING NERVOUS
DISORDERS OR ALLERGIES OR IMPAIRED KIDNEY OR RESPIRATORY FUNCTION
OR A KNOWN SENSITIZATION TO MERCURY MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IMMEDIATELY.EYE/SKIN:IMMEDIATELY FLUSH
WITH WATER FOR AT LEAST 15 MINUTES.HOLD EYELIDS OPEN.INHALED:REMOVE
TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:INDUCE VOMITING BY
GIV ING TWO GLASSES WATER/MILK & STICKING FINGER DOWN THROAT.CALL A
PHYSICIAN IMMEDIATELY.NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:EMITS OXYGEN AND TOXIC FUMES OF MERCURY
WHEN HEATED TO DECOMPOSITION. AT 400 C BECOMES ALMOST BLACK BUT RED
AGAIN ON COOLING.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE CLOTHING &
RESPIRATORY PROTECTION FROM DUST. PICK UP SPILLS AND PLACE IN A
SUITABLE CONTAINER FOR RECLAMATION/DISPOSAL IN A METHOD THAT DOES
NOT GENERATE DUST. SPRINKLE AREA WITH SULFUR TO SUPPRESS MERCURY.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN TIGHTLY CLOSED
CONTAINER IN COOL,DRY,VENTILATED AREA AWAY FROM INCOMPATIBLE
MATERIALS.
Other Precautions:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. AVOID
BREATHING DUST. KEEP OUT OF REACH OF CHILDREN. WASH THOROUGHLY
AFTER HANDLING AND BEFORE EATING OR DRINKING. AVOID
CROSS-CONTAMINATION OF STREET CLOTHE S. DO NOT GENERATE DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A
NIOSH-APPROVED DUST/MIST RESPIRATOR IS RECOMMENDED. IF
CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR, USE SELF-CONTAINED
BREATHING APPARATUS.
Ventilation:PROVIDE SUFFICIENT LOCAL EXHAUST VENTILATION TO CONTROL
INHALATION EXPOSURES BELOW OSHA'S PEL.
Protective Gloves:RECOMMENDED
Eye Protection:DUST-RESIST SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T3
Decomp Temp:Decomp Text:932F,500C
Spec Gravity:11.14
Solubility in Water:INSOLUBLE
Appearance and Odor:BRIGHT, ORANGE-RED OR ORANGE-YELLOW POWDER -
ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CL, HYDRAZINE HYDRATE, H2O2, IODINE+METHANOL+ETHANOL, MG, P, NA K
ALLOY, S, ACETYL NITRATE, BUTADIENE,HYDROCARBONS, SCL2
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE &
STORAGE. DECOMPOSES WITH EXPOSURE TO LIGHT TO OXYGEN AND MERCURY.
Hazardous Decomposition Products:EMITS OXYGEN AND TOXIC FUMES OF
MERCURY WHEN HEATED TO DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. DO NOT FLUSH TO SEWER.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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