===================== Product Identification =====================
MSDS NAME:PARA-DICHLOROBENZENE
NIIN:00-174-1824
MSDS Number: BNRMY
=== Responsible Party ===
Company:PPG INDUSTRIES, INC
Address:ONE PPG PLACE
City:PITTSBURGH
State:PA
ZIP:15272
Country:US
Info Phone Num:304-843-1300
Emergency Phone Num:304-843-1300
Preparer's Name:R KENNETH LEE
CAGE:DO894
=== Contractor Identification ===
Company:PPG INDUSTRIES, INC.
Address:4325 ROSANNA DR
Box:9
City:ALLISON PARK
State:PA
ZIP:15101
Country:US
Phone:412-592-5555
CAGE:DO894
============= Composition/Information on Ingredients =============
Name:PARA-DICHLOROBENZENE (SARA III)
(IPEL: 75 PPM, 8 HR TWA; 100 PPM, 15 MIN STEL)
CAS:106-46-7
RTECS #:CZ4550000
Fraction by Wt: 99.9%
Other REC Limits: SEE ABOVE W/INGRED
OSHA PEL:75 PPM
ACGIH TLV:10 PPM,A3 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 DERMAL: >6000 MG/KG;
Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE OVEREXPOSURE: INHAL: CENTRAL
NERVOUS SYSTEM DEPRESSION, CARDIAC SENSITIZATION, VENTRICULAR
FIBRILLATION. EYE/ SKIN: SLIGHTLY IRRITATING W/EXCESSIVE CONTACT.
INGESTION: DEATH OR ILLNESS SIMILAR T O LISTED FOR INHAL. CHRONIC:
ANIMAL: LIVER KIDNEY DAMAGE.
Explanation of Carcinogenicity:DICHLOROBENZENE CONSIDERED ANIMAL
CARCINOGEN BASED ON NTP SUDY. RELEVANCE TO HUMAN HEALTH AREN'T
KNOWN AT PRESENT.
Effects of Overexposure:CENTRAL NERVOUS SYSTEM DEPRESSION: HEADACHE,
DIZZINESS, EYE, NOSE, & THROAT IRRITATION, NAUSEA, FEELING OF
DRUNKENNESS, UNCONSCIOUSNESS AND EVEN DEATH. LC50 INHAL: NO EFFECT
LEVEL 158 PPM; LD50 INGEST : 3827 MG/KG; LC50 (FISH):
TLM96:10-<1PPM.
Medical Cond Aggravated by Exposure:NONE KNOWN. NOTE TO PHYSICIAN
(INCLUDING ANTIDOTES): ADMINISTRATION OF ADRENALINE MAY BE
CONTRAINDICATED FOR OVEREXPOSURE TO PARA-DICHLOROBENZENE.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. NOT BREATHING, GIVE ARTIF
RESPIRATION (MOUTH TO MOUTH). DIFFICULT BREATHING, GIVE OXYGEN.
CALL DR. EYE: FLUSH W/PLENTY WATER, CALL DR. SKIN: FLUSH W/SOAP &
WATER. IF IRRIT/ DISCOMFORT OCCURS, CONSULT DR. INGEST: CONSCIOUS,
DRINK LRG QTY WATER. DON'T INDUCE VOMIT. TAKE IMMED TO HOSPTL/DR.
UNCONSCIOUS/CONVULSING TAKE IMMED TO HOSPTL. NOTHING BY MOUTH TO
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:148F,64C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:FIRE FIGHTERS MUST WEAR NIOSH/MSHA APPROVED,
SELF-CONTAINED PRESSURE DEMAND BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:BURNS TO FORM TOXIC, CORROSIVE HYDROGEN
CHLORIDE AND POSSIBLE TRACES OF PHOSGENE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE UNPROTECTED PERSONNEL. VENT AREA.
REMOVE IGNITION SOURCES. WORKERS WEAR SCBA OR FULL FACEPIECE
AIRLINE RSPRTRS W/AUX SCBA'S OPERATED IN PRESS DEMAND MODE &
SKIN/EYE PROTECTION. W/CARE SHOVEL/SW EEP UP. PUT IN CLSD CNTNRS.
Neutralizing Agent:N/K MAINTAIN VENT UNTIL ALL VAPORS ELIMINATED. FLUSH
AREA OR SPILL WITH WATER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL(NOT BELOW 32F) AREA, IN
CLSD, LABELED CNTNRS. KEEP CNTNRS CLSD WHEN NOT IN USE. USE IN
VENTED AREAS. DON'T EAT, DRINK, SMOKE IN WK AREA.
Other Precautions:VAPOR HEAVIER THAN AIR, COLLECTS IN LOW AREAS. MAT'L/
VAPOR W/HEAT CAN DECOMPOSE TO FORM HYDROGEN CHLORIDE GAS, PHOSGENE.
DON'T CONTAM WATER, FOOD, FEED. TOXIC TO FISH. KEEP OUT OF LAKES,
PONDS, STREA MS. DON'T CONTAM WATER BY CLEANING OF
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA ORGANIC VAPOR CARTRIDGE/CANISTER
RSPRTR WHEN ABOVE TLV. DUST PRESENT, USE PARTIACULATE PREFILTER.
RESP PROTECT DURING SPILLS SEE SPILL PROCEDURES. OBSERVE RSPRTR
LIMITATIONS. RSPRTR PRO TECT PROGRAMS IN ACCORD 29CFR 18A0.134.
Ventilation:LOCAL EXHAUST VENT SUFF TO MAINTAIN WORKPLACE CONCENTRATION
BELOW PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:VITON/NITRILE(LMTD USE)/POLYVINYL
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:IMPERVIOUS BOOTS, APRONS, OR CHEMICAL SUITS
SHOULD BE USED WHEN NECESSARY. ALCOHOL (DEGRADES IN WTR)
Work Hygienic Practices:N/K EQUIPMENT OR DISPOSAL OF WASTES. AVOID
CONTAM OF WATER SUPPLIES: HANDLING, STORAGE, USE PROCEDURES
Supplemental Safety and Health
BE CAREFULLY MONITORED TO AVOID SPILLS/ LEAKS. ANY SPILL MAY CONTAM
UNDERGRND WATER. DON'T BREATHE/INGEST. AVOID EYE/SKIN CONTACT--CAN
CAUSE THERMAL BURNS. EMPTY DRUM BY SHAKING/TAPPING SIDES/BOTTOM.
REFILL ACCORDING TO GOVRNMNTL REGS OR DISPOSE BY
INCINERATION/LANDFILL. CONTAM CANNOT BE EASILY CORRECTED.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:345F,174C
Melt/Freeze Pt:M.P/F.P Text:127F,53C
Vapor Pres:1.027
Vapor Density:5.07
Spec Gravity:1.248@55C/WTR=1
pH:NEUTRL
Solubility in Water:77 PPM @ 30C
Appearance and Odor:WHITE CRYSTALLINE SOLID OR CLEAR LIQUID WITH
PENETRATING AROMATIC ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:OPEN FLAMES, HOT GLOWING SURFACES, OR
ELECTRIC ARCS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE AND POSSIBLE TRACES
OF PHOSGENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE, OR DISPOSE OF PRODUCT BY BURNING IN
APPRVD INCINERATOR OR DISPOSAL IN APPRVD HAZARDOUS WASTE MANAGMNT
FACILITY. PESTICIDE WASTES TOXIC (RINSATE INCLUDED). IMPROPER
DISPOSAL VIOLATES FED LAW. CONTACT STATE PESTICIDE/EPA IF UNABLE
TO COMPLY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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