| MSDS | : | F-053, MONDUR O | | CAS | : | 112-96-9 | | NAME | : | ing 20:can dev symp as a result of cont w/sm amts of
vent: reference sources regarding industrial ventilation
ing 6:(3-8%), detergent (2%) & water (90%).during spill
other prec:isocyanate expos levels must be monitored by
ing 8:exceeded.medical surveillance of all employees who
ing 9:incl preemployment & periodic med exams w/resp func
ing 10:cndtns, chronic bronch, other chronic resp
ing 11:working w/isocyanates.once a person is diagnosed as
supp data:can result in irrit & corr action in mouth, stom
ing 13:abdom pain, naus, vomit & diarr.chronic: inhal:as
ing 14:indiv will develop isocyanate sensit which will
ing 15:well below tlv.these symp, which incl:chest
ing 16:attack,could be immed/delayed,once sensit,an indiv
ing 17:other irritants.this incr lung sensit can persist
ing 18:isocyanates has been rptd to cause lung dmg.lung dmg
ing 19:reddening, swell, rash, scaling, blistering & in
isocyanic acid, octadecyl ester; (octadecyl isocyanate).
first aid proc:these symp may develop immed/be delayed up
ing 2:ml of milk or water to drink.do not give anything by
ing 3:for evidence of corneal injury.if cornea is
ing 4:vaps can produce corneal dmg.skin:treat as cont
spill proc:loosely,allow to stand for 24 to 48 hrs.wash
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===================== Product Identification =====================
MSDS NAME:F-053, MONDUR O
NIIN:00N023279
MSDS Number: BPCKF
=== Responsible Party ===
Company:MOBAY CORP, A BAYER USA INC COMPANY,DYES & ORG DIV
Address:MOBAY RD
City:PITTSBURG
State:PA
ZIP:15205-9741
Country:US
Info Phone Num:800-662-2927
Emergency Phone Num:412-923-1800/800-424-9300(CHEMTREC)
Preparer's Name:J. J. CONKLIN
CAGE:19511
=== Contractor Identification ===
Company:BAYER CORPORATION
Address:100 BAYER ROAD
Box:City:PITTSBURGH
State:PA
ZIP:15205-9741
Country:US
Phone:800-662-2927; 202-483-7616
CAGE:19511
============= Composition/Information on Ingredients =============
Name:ING 20:CAN DEV SYMP AS A RESULT OF CONT W/SM AMTS OF
LIQ/EXPOS TO VAPOR.
RTECS #:9999999ZZ
Name:VENT: REFERENCE SOURCES REGARDING INDUSTRIAL VENTILATION
SHOULD BE REGARDED.
RTECS #:9999999ZZ
Name:ING 6:(3-8%), DETERGENT (2%) & WATER (90%).DURING SPILL
CLEAN-UP, A NIOSH/MSHA APPRVD SCBA/AIR-LINE RESP/PROT CLTHG REQ.
RTECS #:9999999ZZ
Name:OTHER PREC:ISOCYANATE EXPOS LEVELS MUST BE MONITORED BY
ACCEPTED MONITORING TECHNIQUES TO ENSURE TLV IS NOT (ING 9)
RTECS #:9999999ZZ
Name:ING 8:EXCEEDED.MEDICAL SURVEILLANCE OF ALL EMPLOYEES WHO
HANDLE/COME IN CONT W/ISOCYANATES IS REC.THIS SHOULD (ING 10)
RTECS #:9999999ZZ
Name:ING 9:INCL PREEMPLOYMENT & PERIODIC MED EXAMS W/RESP FUNC
TESTS (FEV,FVC AS MINIMUM).PERSONS W/ASTHMATIC-TYPE (ING 11)
RTECS #:9999999ZZ
Name:ING 10:CNDTNS, CHRONIC BRONCH, OTHER CHRONIC RESP
DISEASES/RECURRENT SKIN ECZEMA/SENSIT SHOULD BE EXCLUDED FROM (ING
12)
RTECS #:9999999ZZ
Name:ING 11:WORKING W/ISOCYANATES.ONCE A PERSON IS DIAGNOSED AS
SENSIT TO ISOCYANATES NO FURTHER EXPOS CAN BE PERMITTED.
RTECS #:9999999ZZ
Name:SUPP DATA:CAN RESULT IN IRRIT & CORR ACTION IN MOUTH, STOM
TISS & DIGESTIVE TRACT.SYMP CAN INCL SORE THROAT, (ING 14)
RTECS #:9999999ZZ
Name:ING 13:ABDOM PAIN, NAUS, VOMIT & DIARR.CHRONIC: INHAL:AS
RESULT OF PREVIOUS RPTD OVEREXP/SINGLE LRG DOSE,CERTAIN(ING 15)
RTECS #:9999999ZZ
Name:ING 14:INDIV WILL DEVELOP ISOCYANATE SENSIT WHICH WILL
CAUSE THEM TO REACT TO LATER EXPOS TO ISOCYANATE AT LEVS(ING 16)
RTECS #:9999999ZZ
Name:ING 15:WELL BELOW TLV.THESE SYMP, WHICH INCL:CHEST
TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF BREATH/ASTHMATIC (ING 17)
RTECS #:9999999ZZ
Name:ING 16:ATTACK,COULD BE IMMED/DELAYED,ONCE SENSIT,AN INDIV
CAN EXPERIENCE THESE SYMP UPON EXPOS TO DUST,COLD AIR/(ING 18)
RTECS #:9999999ZZ
Name:ING 17:OTHER IRRITANTS.THIS INCR LUNG SENSIT CAN PERSIST
FOR WEEKS & IN SEVERE CASES FOR SEV YRS.OVEREXP TO (ING 19)
RTECS #:9999999ZZ
Name:ING 18:ISOCYANATES HAS BEEN RPTD TO CAUSE LUNG DMG.LUNG DMG
& SENSIT MAY BE PERM.SKIN:PRLNGD CONT CAN CAUSE (ING 20)
RTECS #:9999999ZZ
Name:ING 19:REDDENING, SWELL, RASH, SCALING, BLISTERING & IN
SOME CASES, SKIN SENSIT.INDIV WHO HAVE DEV SKIN SENSIT (ING 21)
RTECS #:9999999ZZ
Name:ISOCYANIC ACID, OCTADECYL ESTER; (OCTADECYL ISOCYANATE).
ACGIH TLV: 0.005 PPM;0.02 STEL (MFR)
CAS:112-96-9
RTECS #:NR0140000
Fraction by Wt: 100%
ACGIH TLV:SEE INGREDIENT NAME
Name:FIRST AID PROC:THESE SYMP MAY DEVELOP IMMED/BE DELAYED UP
TO SEV HRS.CALL MD.INGEST:DO NOT INDUCE VOMIT.GIVE 250(ING 3)
RTECS #:9999999ZZ
Name:ING 2:ML OF MILK OR WATER TO DRINK.DO NOT GIVE ANYTHING BY
MOUTH TO UNCON PERSON.CALL MD.NOTE TO MD:EYES:STAIN (ING 4)
RTECS #:9999999ZZ
Name:ING 3:FOR EVIDENCE OF CORNEAL INJURY.IF CORNEA IS
BURNED,INSTILL ANTIBIOTIC STEROID PREPARATION FREQ.WORKPLACE (ING
5)
RTECS #:9999999ZZ
Name:ING 4:VAPS CAN PRODUCE CORNEAL DMG.SKIN:TREAT AS CONT
DERMAT.IF BURNED,TREAT AS THERM BURN.RESP:TREATMENT IS ESSEN SYMP.
RTECS #:9999999ZZ
Name:SPILL PROC:LOOSELY,ALLOW TO STAND FOR 24 TO 48 HRS.WASH
DOWN SPILL AREA W/DECONTAM SOLN.DECONTAM SOLNS:AMMONIA (ING 7)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 30 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL: VAPS/MISTS CAN IRRIT MUC
MEMB IN RESP TRACT CAUSING:RUNNY NOSE, SORE THROAT, COUGHING, CHEST
DISCOMFORT, SHORTNESS OF BRTH & REDUCED LUNG FUNC.EXPOS WELL ABOVE
TLV MAY LEAD TO BRONCH, BRO NCHIAL SPASM & FATAL PULM EDEMA.CHEM
PNEUM, W/FLU-LIKE SYMP THAT CAN BE DELAYED, HAS BEEN RPTD.PERSONS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:W/PREEXISTING, NONSPECIFIC BRONCHIAL
HYPERREACTIVITY CAN RESPOND TO CONC WELL BELOW TLV W/IMMED/DELAYED
SYMP/ASTHMATIC ATTACK. SKIN:BASED ON ANIMAL EXPERIMENTS, OCTADECYL
ISOCYANATE IS CONSID ERED TO BE SLIGHTLY IRRIT TO SKIN.ISOCYANATES
MAY REACT W/SKIN PROTEIN & MOISTURE & CAN CAUSE SKIN BURNS, (SUPP
DATA)
Medical Cond Aggravated by Exposure:ASTHMA, OTHER RESPIRATORY DISORDERS
(BRONCHITIS, EMPHYSEMA, BRONCHIAL HYPERREACTIVITY), SKIN ALLERGIES,
ECZEMA.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH IMMED W/CLEAN, LUKEWARM WATER FOR AT LEAST 15 MIN,
OCCASNLY LIFTING LIDS & CALL MD IMMED.SKIN:GET UNDER SAFETY SHOWER
& IMMED FLUSH W/WATER WHILE REMOVING CLTHG & SHOES.GET MD.WASH
CONTAM CL THG THORO BEFORE REUSE.DISCARD CONTAM SHOES.INHAL:MOVE TO
FRESH AIR.ADMIN OXYGEN/ARTF RESP AS NEEDED.CALL MD.FATAL PULM
EDEMA/ASTHMATIC-TYPE SYMP INCL BRONCH, BRONCHOSPASM MAY DEVELOP;
(ING 2)
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:365F,185C
Extinguishing Media:WATER FOG, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DURING A FIRE, IRRIT AND/OR TOXIC GAS FROM
COMBUST MAY BE GENERATED.
Unusual Fire/Explosion Hazard:CAUTION: REACTION BETWEEN WATER AND FOAM
AND HOT ISOCYANATE CAN BE VIGOROUS.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER SPILL W/SAWDUST, VERMICULITE, FULLER'S
EARTH/OTHER ABSORB MATL.POUR DECONTAM SOLN OVER SPILL AREA & ALLOW
TO REACT FOR AT LEAST 10 MIN.COLLECT MATL IN OPEN TOP CNTNRS & ADD
ADDTNL AMTS OF DECONT AM SOLN.REMOVE CNTNRS TO SAFE PLACE,
COVER(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLSD CNTNRS TO PVNT
MOISTURE CONTAM. DO NOT RESEAL IF CONTAM IS SUSPECTED. AVOID
CONTACT WITH SKIN & EYES. DO NOT BREATHE VAPORS.
Other Precautions:IF CNTNR EXPOSED TO HIGH HEAT, 375F, IT CAN BECOME
PRESSURIZED & POSSIBLY RUPTURE. ISOCYANATES REACT SLOWLY WITH WATER
TO FORM POLYUREAS AND LIBERATE CO*2 GAS. THIS GAS CAN CAUSE SEALED
CNTNRS TO EXPA ND AND POSSIBLY RUPTURE. (ING 8)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF IRRITATING VAPORS ARE DETECTED, A NIOSH/MSHA
APPROVED POSITIVE PRESSURE AIR-LINE RESPIRATOR MUST BE USED. PROPER
FIT & TIMELY REPLACEMENT OF FILTER ELEMENTS MUST BE ENSURED.
OBSERVE OSHA REGS FOR R ESP USE (29 CFR 1910.134).
Ventilation:LOC EXHST SHOULD BE USED TO MAINTAIN LEVELS
ISOCYANATES ARE HANDLED, PROCESSED/SPRAY-APPLIED. STD (ING 22)
Protective Gloves:NATL RUBBER, POLYVINYL ALCOHOL.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING. CONTACT LENSES
SHOULD NOT BE WORN. SAFETY SHOWERS & EYEWASH STATIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:IRRIT & DISCOLORATION.CURED MATL CAN BE DFCLT TO
REMOVE.IN SOME INDIV,CONT CAUSES SKIN SENSIT RESULT IN DERMAT.
EYE:LIQ, AEROSOLS & VAPS ARE IRRIT & CAN CAUSE TEARING, REDDENING &
SWEL LING.IF LEFT UNTREATED, CORNEAL DMG CANOCCUR & INJ IS SLOW TO
HEAL.HOWEVER, DMG IS USUALLY REVERSIBLE.INGEST: (ING 13)
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:475F,246C
Vapor Pres:1 @ 154C
Spec Gravity:0.86
Solubility in Water:REACTS, DECOMPOSES
Appearance and Odor:PALE YELLOW LIQUID WITH SHARP, PUNGENT ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS. WILL CAUSE SOME CORROSION TO
COPPER ALLOYS & ALUMINUM.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY HIGH HEAT AND FLAME: CO, OXIDES OF
NITROGEN, TRACES OF HCN.
Conditions to Avoid Polymerization:MOISTURE/OTHER MATLS WHICH REACT
W/ISOCYANATES.SELF-RXN MAY OCCUR AT TEMPS >350F/AT LOWER TEMPS IF
SUFF TIME INVOLVED.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATION IS THE PREFERRED METHOD. EMPTY
CNTNRS MUST BE HANDLED WITH CARE DUE TO PRODUCT RESIDUE.
DECONTAMINATE CNTNRS PRIOR TO DISPOSAL. DO NOT HEAT OR CUT EMPTY
CNTNR W/ELECTRIC OR GAS TORCH.DISP MUST BE I/A/W FEDERAL, ST &
LOCAL REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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