===================== Product Identification =====================
MSDS NAME:SULFURIC ACID
NIIN:00N019698
MSDS Number: BPCJN
=== Responsible Party ===
Company:GEORGIA-PACIFIC CORP; BELLINGHAM DIV
Address:300 LAUREL STREET
Box:1236
City:BELLINGHAM
State:WA
ZIP:98227
Country:US
Info Phone Num:206-733-4410
Emergency Phone Num:206-733-4410
CAGE:95732
=== Contractor Identification ===
Company:GEORGIA-PACIFIC CORP; BELLINGHAM DIV
Address:300 LAUREL STREET (9822S)
Box:1236
City:BELLINGHAM
State:WA
ZIP:98227
Country:US
Phone:206-733-4410
CAGE:95732
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 93-98%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3;3 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:OTHER PREC:CARBIDES, OXIDIZABLES, ETC. SODA ASH, SAND OR
LIME SHOULD BE KEPT IN GENERAL STORAGE/WORK AREAS FOR (ING 3)
RTECS #:9999999ZZ
Name:ING 2:EMERGENCY USE. PROTECT CNTNRS AGAINST PHYSICAL
DAMAGE. GLASS BOTTLES NEED EXTRA PROTECTION. SULFURIC ACID (ING 4)
RTECS #:9999999ZZ
Name:ING 3:IS HIGHLY CORROSIVE TO MOST METALS, ESPECIALLY BELOW
77% H*2SO*4. DO NOT ADD WATER TO CONC ACID. MAY BE (ING 5)
RTECS #:9999999ZZ
Name:ING 4:FATAL OR CAUSE PERMANENT DAMAGE IF SWALLOWED. CAUSES
SEVERE BURNS. VAPOR HARMFUL.
RTECS #:9999999ZZ
Name:SUPP DATA:CONTINUE TO ADMINISTER FLUID. CALL MD
IMMEDIATELY.
RTECS #:9999999ZZ
Name:PH: EXTREMELY ACIDIC
RTECS #:9999999ZZ
Name:SPEC GRAV: 1.835-1.84 (WATER = 1).
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HIGH CORROSIVE TO SKIN & EYES.
BREATHING OF VAPOR OR MIST MAY CAUSE EROSION OF TEETH, SORE MOUTH,
OR DIFFICULTY IN BREATHING. CONC SULFURIC ACID IS A STRONG MINERAL
ACID, AN OXIDIZING AGENT, AND A DEH YDRATING AGENT THAT IS RAPIDLY
DAMAGINGTO ALL HUMAN TISSUE WITH WHICH IT COME IN CONTACT. INGEST
MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CAUSE SEVERE INJURY OR DEATH.
INHALATION OF MISTS CAN DAMAGE BOTH THE UPPER RESPIRATORY TRACT AND
THE LUNGS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/PLENTY OF RUNNING WATER FOR AT LEAST 15 MIN
(INCL UNDER LIDS).SPEED IN DILUTING & RINSING OUT ACID IS EXTREMELY
IMPORTANT IF PERMANENT EYE DMG IS TO BE AVOIDED.CALL MD
IMMED.SKIN:IMM ED FLUSH AFFECTED AREAS W/WATER, REMOVING CONTAM
CLTHG UNDER SAFETY SHOWER. CONTINUE WASHING W/WATER & GET MD.
INHAL:REMOVE TO FRESH AIR. RESTORE BRTHG. CALL MD IMMED. MAINTAIN
OBSERVATION (SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DO NOT ADD WATER OR OTHER LIQUID TO THE
ACID.
Unusual Fire/Explosion Hazard:SULFURIC ACID MISTS & VAPS FROM FIRE AREA
ARE CORR.WATER APPLIED DIRECTLY TO H*2SO*4 CAUSES EVOL OF HEAT &
SPATTERING.H*2SO*4 IS CAPABLE OF IGNITING (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:RESTRICT PERSONS W/O PROT EQUIP & CLTHG FROM
ENTERING AREA.VENT AREA & COLLECT MATL ON VERMICULITE, DRY SAND,
EARTH/SIMILAR, NON-COMBUST MATL FOR DISP.ALTERNATIVELY,SPILLED ACID
MAY BE VERY CAREFULLY DILUTED W/WATER & NEUT W/LIME,
LIMESTONE/SODA ASH.
Neutralizing Agent:LIME, LIMESTONE, OR SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BRTHG MIST/VAPS.AVOID CONT
W/SKIN/EYES.DO NOT SMOKE.USE NON-SPARKING TOOLS & VAPOR-PROOF TYPE
ELEC FIXTURES.KEEP OUT OF DIRECT SUNLIGHT.
Other Precautions:H*2SO*4 IN CARBOYS/DRUMS SHOULD BE STORED IN CLEAN
VENT STORAGE AREAS HAVING ACID RESIST FLOORS W/GOOD DRAINAGE.DO NOT
STORE ABOVE 32C.STORAGE FACILITIES SHOULD BE SEPARATE FROM METALLIC
POWDERS, CHRO MATES, CHLORATES, NITRATES, (ING 2)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED HIGH EFFICIENCY PARTICULATE
RESPIRATOR WITH FULL FACEPIECE WHERE THE POTENTIAL EXISTS FOR
INHALATION OF MISTS OR VAPORS UP TO 50 MG/M3.
Ventilation:LOCAL EXHAUST: IF REQUIRED TO MAINTAIN PEL. MECHANICAL
(GENERAL): IF REQUIRED TO MAINTAIN PEL.
Protective Gloves:RUBBER.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD
Other Protective Equipment:IMPERVIOUS RUB APRONS, BOOTS & SUITS ARE REC
IF POTENTIAL EXISTS FOR BODY CONT W/PROD. EMER EYEWASH, DELUGE
SHOWER
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:FINELY DIVIDED COMBUSTIBLE MATLS ON CONTACT. ABOVE 644F,
CORROSIVE SULFUR OXIDE GASES ARE FORMED. FIRST AID PROC:OF PATIENT
FOR POSSIBLE DELAYED ONSET OF PULM EDEMA. INGEST:DILUTE ACID IMMED
W/LRG AMTS OF MILK/WATER, THEN GIVE MILK OF MAGNESIA TO NEUT. DO
NOT INDUCE VOMIT; IF IT OCCURS SPONTANEOUSLY,(ING 6)
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>538F,>281C
Melt/Freeze Pt:M.P/F.P Text:>-29F,>-34C
Vapor Pres:0.001
Vapor Density:3.4
Spec Gravity:ING 8
pH:ING 7
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:REACTS VIOLENTLY
Appearance and Odor:CLEAR, COLORLESS, HYGROSCOPIC OILY LIQUID WITH NO
ODOR.
Percent Volatiles by Volume:2-7%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FINELY DIVIDED COMBUSTIBLE MATERIALS AND METALS.
Stability Condition to Avoid:DO NOT ADD WATER TO ACID (ACID SHOULD
ALWAYS BE ADDED SLOWLY TO WATER.
Hazardous Decomposition Products:EXPLOSIVE HYDROGEN GAS IN AIR MIXTURES
MAY BE FORMED ON CONTACT OF DILUTED ACID WITH METALS.
Conditions to Avoid Polymerization:AVOID STORAGE WITH FINELY DIVIDED
COMBUSTIBLE MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:H*2SO*4 MAY BE PLACED IN SEALED CNTNRS OR
ABSORBED IN VERMICULITE, DRY SAND, EARTH, OR A SIMILAR MATERIAL AND
DISPOSED OF IN A SECURED SANITARY LANDFILL. IT MAY ALSO BE DILUTED
AND NEUTRALIZED. DISPOS AL MUST BE I/A/W FEDERAL, ST & LOCAL REGS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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