| MSDS | : | CONATHANE EN-1556 PART A | | CAS | : | 584-84-9 | | NAME | : | ing 23:non-ionic surfactant union carbide's tergitol
ing 24:(2%),& h*2o (90%). during spill clean-up, a
spill proc:cover loosely,& allow to stand for 24-48 hours.
other prec:observe osha regulations for respirator use.
resp prot:vent is used.for non-spray,short-term (<1 hr)
ing 11:full face,air-purifying resp equipped with org
vent:at normal room temps (70f) tdi levels quickly exceed
supp data:chronic: inhal:can produce irrit of muc memb in
ing 14:productive cough & reduction in lung func,
ing 15:chest tightness, wheezing, cough, shortness of
ing 16:also been rptd to cause lung dmg (incl decrease in
ing 17:to eyes & can cause tears.prlngd vap cont may cause
ing 18:heal. skin:localized irrit, discoloration.prlngd
ing 19:some indiv,skin sensit resulting in dermat.once
ing 20:of expos to vapor. ingest:irrit & some corr action
ing 21:sore throat, abdominal pain, nausea, vomiting and
ing 8:to this matl should be removed from exposure to any
benzene, 2,4-diisocyanate-1-methyl-;
first aid proc:oxygen/artf resp as needed.call
ing 2:hrs.call md.ingest:do not induce vomit.give 12 fl oz
ing 3:to uncon person.call md.note to md:eyes:stain for
ing 4:antibiotic steroid preparation freq.workplace vaps
ing 5:impairing vision.this cmpd is known skin sensit.treat
ing 6:specific antidote for ingest treat symptom.inducing
ing 7:this cmpd.tdi is known pulm sensit.treatment is
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===================== Product Identification =====================
MSDS NAME:CONATHANE EN-1556 PART A
NIIN:00N022343
Kit Part:Y
MSDS Number: BPCKB
=== Responsible Party ===
Company:CONAP INC.
Address:1405 BUFFALO STREET
City:OLEAN
State:NY
ZIP:14760-1139
Country:US
Info Phone Num:716-372-9650
Emergency Phone Num:716-372-9650
Preparer's Name:GEORGE C. KARPIN
CAGE:16245
=== Contractor Identification ===
Company:CONAP INC.,WHOLLY OWNED SUBSIDIARY OF CYTEC INDUSTRIES
INC.
Address:1405 BUFFALO STREET
Box:City:OLEAN
State:NY
ZIP:14760
Country:US
Phone:716-372-9650
CAGE:16245
============= Composition/Information on Ingredients =============
Name:ING 23:NON-IONIC SURFACTANT UNION CARBIDE'S TERGITOL
TMN-10(20%) & H*2O (80%); OR CONC AMMONIA (3-8%), DETERGENT(ING 25)
RTECS #:9999999ZZ
Name:ING 24:(2%),& H*2O (90%). DURING SPILL CLEAN-UP, A
NIOSH/MSHA APPRVD SCBA OR AIR LINE RESP & PROT CLTHG MUST BE WORN.
RTECS #:9999999ZZ
Name:SPILL PROC:COVER LOOSELY,& ALLOW TO STAND FOR 24-48 HOURS.
WASH DOWN SPILL AREA W/DECONTAM SOLNS.DECONTAM SOLNS:(ING 24)
RTECS #:9999999ZZ
Name:OTHER PREC:OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE.
(29CFR 1910.134).
RTECS #:9999999ZZ
Name:RESP PROT:VENT IS USED.FOR NON-SPRAY,SHORT-TERM (<1 HR)
SITUATIONS WHERE CONC ARE NEAR TLV,A NIOSH/MSHA APPRVD (ING 12)
RTECS #:9999999ZZ
Name:ING 11:FULL FACE,AIR-PURIFYING RESP EQUIPPED WITH ORG
CARTRIDGES/CANISTERS CAN BE USED.
RTECS #:9999999ZZ
Name:VENT:AT NORMAL ROOM TEMPS (70F) TDI LEVELS QUICKLY EXCEED
THE TLV UNLESS PROPERLY VENTILATED.
RTECS #:9999999ZZ
Name:SUPP DATA:CHRONIC: INHAL:CAN PRODUCE IRRIT OF MUC MEMB IN
RESP TRACT RESULTING IN RUNNING NOSE, SORE THROAT, (ING 15)
RTECS #:9999999ZZ
Name:ING 14:PRODUCTIVE COUGH & REDUCTION IN LUNG FUNC,
ISOCYANATE SENSIT (CHEM ASTHMA), HYPERREACTIVITY/HYPERSENSIT, (ING
16)
RTECS #:9999999ZZ
Name:ING 15:CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF
BREATH/ASTHMATIC ATTACK. CHRONIC OVEREXP TO ISOCYANATE HAS(ING 17)
RTECS #:9999999ZZ
Name:ING 16:ALSO BEEN RPTD TO CAUSE LUNG DMG (INCL DECREASE IN
LUNG FUNC) WHICH MAY BE PERMANENT. EYES:SEVERELY IRRIT(ING 18)
RTECS #:9999999ZZ
Name:ING 17:TO EYES & CAN CAUSE TEARS.PRLNGD VAP CONT MAY CAUSE
CONJ.CORNEAL INJURY CAN OCCUR WHICH CAN BE SLOW TO (ING 19)
RTECS #:9999999ZZ
Name:ING 18:HEAL. SKIN:LOCALIZED IRRIT, DISCOLORATION.PRLNGD
CONT COULD PRODUCE REDDENING, SWELL/BLISTERING AND, IN (ING 20)
RTECS #:9999999ZZ
Name:ING 19:SOME INDIV,SKIN SENSIT RESULTING IN DERMAT.ONCE
SENSITIZED A INDIV CAN DEVELOP RECURRING SYMP AS A RESULT(ING 21)
RTECS #:9999999ZZ
Name:ING 20:OF EXPOS TO VAPOR. INGEST:IRRIT & SOME CORR ACTION
IN MOUTH, STOM TISS & DIGESTIVE TRACT. SYMP CAN INCL (ING 22)
RTECS #:9999999ZZ
Name:ING 21:SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND
DIARRHEA.
RTECS #:9999999ZZ
Name:ING 8:TO THIS MATL SHOULD BE REMOVED FROM EXPOSURE TO ANY
ISOCYANATE.
RTECS #:9999999ZZ
Name:BENZENE, 2,4-DIISOCYANATE-1-METHYL-;
(TOLUENE-2,4-DIISOCYANATE)
CAS:584-84-9
RTECS #:CZ6300000
Fraction by Wt: <8%
OSHA PEL:C,0.02 PPM/0.02 STEL
ACGIH TLV:0.005PPM/0.02STEL;93
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:FIRST AID PROC:OXYGEN/ARTF RESP AS NEEDED.CALL
MD.ASTHMATIC-TYPE SYMP MAY DEV & MAY BE IMMED/DELAYED UP TO SEV
(ING 3)
RTECS #:9999999ZZ
Name:ING 2:HRS.CALL MD.INGEST:DO NOT INDUCE VOMIT.GIVE 12 FL OZ
OF MILK/WATER TO DRINK.DO NOT GIVE ANYTHING BY MOUTH (ING 4)
RTECS #:9999999ZZ
Name:ING 3:TO UNCON PERSON.CALL MD.NOTE TO MD:EYES:STAIN FOR
EVIDENCE OF CORNEAL INJURY.IF CORNEA IS BURNED,INSTILL (ING 5)
RTECS #:9999999ZZ
Name:ING 4:ANTIBIOTIC STEROID PREPARATION FREQ.WORKPLACE VAPS
HAVE PRODUCED REVERSIBLE CORNEAL EPITHELIAL EDEMA (ING 6)
RTECS #:9999999ZZ
Name:ING 5:IMPAIRING VISION.THIS CMPD IS KNOWN SKIN SENSIT.TREAT
SYMPTOM AS FOR CONT DERMAT/THERMAL BURNS.THERE IS NO(ING 7)
RTECS #:9999999ZZ
Name:ING 6:SPECIFIC ANTIDOTE FOR INGEST TREAT SYMPTOM.INDUCING
VOMIT IS CONTRAINDICATED BECAUSE OF IRRIT NATURE OF (ING 8)
RTECS #:9999999ZZ
Name:ING 7:THIS CMPD.TDI IS KNOWN PULM SENSIT.TREATMENT IS
ESSENTIALLY SYMPTOM.AN INDIV HAVING SKIN/PULM SENSIT RXN (ING 9)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) >5800 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:TDI VAPS/MISTS AT CONC
>TLV CAN IRRIT (BURNING SENSATION) THE MUC MEMB IN RESP TRACT
(NOSE, THROAT, LUNGS) CAUSING RUNNY NOSE, SORE THROAT, COUGHING,
CHEST DISCOMFORT, SHORTNESS OF BREATH & REDUCED LUNG FUNCTION
(BRTHG OBSTRUCTION). EXPOS WELL ABOVE TLV MAY LEAD TO BRONCHITIS,
BRONCHIAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:TOLUENE DIISOCYANATE: ANTICIPATED TO BE
A CARCINOGEN (NTP); GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:SPASM & PULM EDEMA (FLUID IN LUNGS).
THESE EFTS ARE USUALLY REVERSIBLE. CHEM/HYPERSENSIT PNEUM,
W/FLU-LIKE SYMP (E.G. FEVER, CHILLS). INGEST:IRRIT & CORR ACTION IN
MOUTH, STOM TISS & DIGESTIV E TRACT. SYMP CAN INCL SORE THROAT,
ABDOM PAIN, NAUS, VOMIT & DIARR. EYE:SEVERELY IRRIT & CAN CAUSE
PAIN, (SUPP DATA)
Medical Cond Aggravated by Exposure:PERSONS WITH A PREEXISTING,
NONSPECIFIC BRONCHIAL HYPERACTIVITY. ASTHMA, OTHER RESPIRATORY
DISORDERS (BRONCHITIS, EMPHYSEMA, BRONCHIAL HYPERREACTIVITY), SKIN
ALLERGIES, ECZEMA.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/CLEAN, LUKEWARM WATER (LOW PRESS) FOR AT LEAST 15
MIN, OCCASNLY LIFTING LIDS. CALL MD. REFER INDIV TO OPHTHALMOLOGIST
FOR IMMED FOLLOW-UP. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREAS
THO RO W/SOAP/TINCTURE OF GREEN SOAP & WATER. WASH CONTAM CLTHG
THORO BEFORE REUSE. FOR SEVERE EXPOS, GET UNDER SAFETY SHOWER,
REMOVE CLTHG UNDER SHOWER, GET MD. INHAL:REMOVE TO FRESH AIR. ADMIN
(ING 2)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>260F,>127C
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . NO SKIN SURFACE SHOULD BE EXPOSED.
Unusual Fire/Explosion Hazard:DURING FIRE TDI VAPS & OTHER IRRIT,HIGHLY
TOX GASES MAY BE GEN BY THERMAL DECOMP/COMBUST.AT TEMPS >350F TDI
FORMS CARBODIIMIDES W/RELS OF CO*2 WHICH (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:COVER SPILL W/SAWDUST, VERMICULITE, FULLER'S
EARTH/OTHER ABSORB MATL.POUR DECONTAM SOLN OVER SPILL AREA & ALLOW
TO REACT FOR AT LEAST 10 MIN.COLLECT MATL IN OPEN TOP CNTNRS & ADD
ADDTNL AMTS OF DECONT AM SOLN. REMOVE CNTNRS TO SAFE PLACE, (ING
23)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:MATL MAY PRESENT DUST HAZ IF
CUT/GROUND/MACHINED AFTER CURING.STORE IN TIGHTLY CLSD CNTNRS TO
PVNT MOISTURE CONTAM.DO NOT RESEAL IF CONTAM IS SUSPECT.
Other Precautions:AVOID CONT W/EYES & SKIN.DO NOT BREATHE VAPS.TDI HAS
POOR WARNING PROPERTIES SINCE ODOR AT WHICH TDI CAN BE SMELLED IS
SUBSTANTIALLY HIGHER THAN 0.02 PPM.THEREFORE,PROPER FIT & TIMELY
REPLACEMENT OF F ILTER ELEMENTS MUST BE ENSURED.(ING 10)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA APPRVD POSITIVE PRESS AIR-SUPPLIED
RESP IS REQ WHENEVER TDI CONC EXCEED SHORT-TERM EXPOS/CEILING
LIMIT/EXCEED TLV. A NIOSH/MSHA APPRVD AIR SUPPLIED RESP MUST ALSO
BE WORN DURING SPRAY APP LICATN, EVEN IF EXHST (ING 11)
Ventilation:LOC EXHST SHOULD BE USED TO MAINTAIN LEVS
CONTAINING MATL IS HNDLD,PROCESSED,SPRAY APPLIED. (ING 13)
Protective Gloves:BUTYL RUB/NITRILE RUB/POLYVINYL ALCOHOL.
Eye Protection:CHEM WORK GOGG & FULL LGTH FSHLD .
Other Protective Equipment:SAFETY SHOWERS & EYEWASH STATIONS. COVER AS
MUCH EXPSD SKIN AS POSS W/APPROP CLTHG.
Work Hygienic Practices:CONT LENSES SHOULD NOT BE WORN. EDUCATE & TRAIN
EMPLOYEES IN SAFE USE OF PRODUCT. FOLLOW ALL LABEL INSTRUCTIONS.
Supplemental Safety and Health
EXPLO HAZ:CAN CAUSE PRESS BUILD-UP IN CLSD CNTNRS.EXPLO RUPT IS
POSS.USE COLD WATER TO COOL FIRE-EXPSD CNTNRS. EFTS OF
OVEREXP:TEARING, REDDENING/SWELL.IF LEFT UNTREATED, CORNEAL DMG CAN
OCCUR. SKIN:I RRIT WHICH MAY INCL FOLLOWING SYMP:REDDENING, SWELL,
RASH, SCALING OR BLISTERING. CURED MATL IS DFCLT TO REMOVE.(ING 14)
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.06 (H*2O=1)
Solubility in Water:REACTS
Appearance and Odor:LIQUID WITH A SHARP PUNGENT ODOR.
Percent Volatiles by Volume:NEGLIG
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, SHORT CHAIN ALCOHOLS, AMINES.
Stability Condition to Avoid:TEMPERATURES HIGHER THAN RECOMMENDED.
Hazardous Decomposition Products:BY HEAT & FIRE: CO*2, CO, OXIDES OF
NITROGEN & TRACES OF HYDROGEN CYANIDE, TDI.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE ACCORDING TO ANY LOCAL, STATE AND
FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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