===================== Product Identification =====================
MSDS NAME:TETRAHYDROFURAN
NIIN:00N022710
MSDS Number: BPPTK
=== Responsible Party ===
Company:SPECTRUM CHEMICAL MANUFACTURING CORP
Address:14422 S SAN PEDRO ST
City:GARDENA
State:CA
ZIP:90248-9985
Country:US
Info Phone Num:213-516-8000
Emergency Phone Num:213-516-8000;800-424-9300(CHEMTREC)
CAGE:63415
=== Contractor Identification ===
Company:SPECTRUM LABORATORY PRODUCTS INC
Address:14422 S SAN PEDRO ST
Box:City:GARDENA
State:CA
ZIP:90248-2027
Country:US
Phone:310-516-8000/FAX: 310-516-9843
CAGE:63415
============= Composition/Information on Ingredients =============
Name:FURAN, TETRAHYDRO-; (TETRAHYDROFURAN) (SARA III)
CAS:109-99-9
RTECS #:LU5950000
Fraction by Wt: >99%
OSHA PEL:200 PPM;250 STEL
ACGIH TLV:200 PPM;250 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:OXIDATION INHIBITOR; (PEROXIDATION INHIBITOR)
Fraction by Wt: TRACE
Name:SUPDAT:INFO ) ATTACKS SOME PLASTICS, RUBBER.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXPOS:CHRONIC:INHAL:ANIMAL EXPOS TO OVER 3000
PPM FOR 20 DAYS EXHIBITED IRRIT OF UPPER RESP TRACT. (ING 5)
RTECS #:9999999ZZ
Name:ING 4:LIVER & KIDNEY DMG WAS OBSERVED BUT MAY HAVE BEEN DUE
TO IMPURITIES. SKIN:MAY CAUSE IRRIT, DEHYDRATION (ING 6)
RTECS #:9999999ZZ
Name:ING 5:& DEFATTING, & SUBSEQUENT DERM. EYE:MAY CAUSE CONJ.
INGEST:REPORTED TO CAUSE LIVER & KIDNEY DMG.
RTECS #:9999999ZZ
Name:FIRST AID PROC:LIFTING LIDS, UNTIL NO EVIDENCE OF CHEM
REMAINS (AT LEAST 15-20 MIN). GET MD ATTN IMMED. (ING 8)
RTECS #:9999999ZZ
Name:ING 7:INGEST:IF CONSCIOUS & NOT CONVULSING, INDUCE VOMIT BY
GIVING SYRUP OF IPECAC FOLLOWED BY WATER. (IF VOMIT (ING 9)
RTECS #:9999999ZZ
Name:ING 8:OCCURS KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION).
GASTRIC LAVAGE SHOULD BE PERFORMED BY QUALIFIED MED (ING 10)
RTECS #:9999999ZZ
Name:ING 9:PERSONNEL. GET MD ATTN IMMED. NO SPECIFIC ANTIDOTE.
TREAT SYMPTOMATICALLY & SUPPORTIVELY.
RTECS #:9999999ZZ
Name:SPILL PROC:OR FLARE IN HAZ AREA. EVACUATE AREA. REPORTABLE
QTY:1000 LBS.
RTECS #:9999999ZZ
Name:OTHER PREC:ADDING INHIBITOR. AVOID CONT W/HEAT, SPARKS,
FLAMES/OTHER SOURCES OF IGNIT. VAP MAY BE EXPLOSIVE & (ING 13)
RTECS #:9999999ZZ
Name:ING 12:POISONOUS; DO NOT ALLOW UNNEC PERSONNEL IN AREA. DO
NOT OVERHEAT CONTRS; CONTRS MAY VIOLENTLY RUPTURE & (ING 14)
RTECS #:9999999ZZ
Name:ING 13:TRAVEL CONSIDERABLE DISTANCE IN HEAT OR FIRE. STORE
IN ACCORDANCE WITH 29 CFR 1910.106.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT):2816 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT/NARCOTIC. HIGH VAP
CONC MAY CAUSE SEV OCCIPITAL HDCH & DULLNESS, MUCOUS MEMBRANE
IRRIT, SORE THROAT, COUGHING, NAUS, CNS DEPRESS, FATIGUE,
UNCONSCIOUSNESS & POSS ASPHY. IN LAB ANIMAL S CONC ABOVE 25,000 PPM
PRODUCED ANESTHESIA, VOMIT, MARKED FALL IN BLOOD PRESS & STRONG
RESP (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:STIMULATION. SKIN:ESSENTIALLY
NONIRRIT. SKIN ABSORP MAY OCCUR. EYE:VAP MAY CAUSE IRRIT, REDNESS,
TEARING & BLURRED VISION. LIQ MAY CAUSE SEV IRRIT/POSS BURNS.
INGEST:MAY CAUSE GI IRRIT, SORE THROAT, ABDOMINAL PAIN, NAUS,
VOMIT, DIARR & DULLNESS. ASPIR MAY CAUSE SEV LUNG IRRIT & POSS
DELAYED CHEM PNEUM.(ING 4)
Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED LIVER, KIDNEY
OR PULMONARY FUNCTION; EYE/SKIN DISORDERS. ALCOHOL MAY ENHANCE
TOXIC EFFECTS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, PERFORM ARTIF RESP. KEEP WARM & AT REST. TREAT
SYMPTOMATICALLY & SUPPORTIVELY. GET MD ATTN IMMED. SKIN:REMOVE
CONTAM CLTHG & SHOES IMM ED. WASH AFFECTED AREA W/SOAP/MILD
DETERGENT & LRG AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS
(APPROX 15-20 MIN). GET MD ATTN IMMED. EYES:WASH IMMED W/LRG AMTS
OF WATER/NORMAL SALINE,(ING 7)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:6F,-14C
Lower Limits:2%
Upper Limits:11.8%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY,
FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
MOVE CONTRS FROM FIRE AREA IF POSS. COOL FIRE EXPOS CONTRS W/ WATER
FOG. WITHDRAW IMMED IN CASE OF (SUPDAT)
Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPOSED TO HEAT/FLAME.
VAP- AIR MIX ARE EXPLOS. VAP ARE HVR/AIR & MAY TRAVEL A
CONSIDERABLE DISTANCE TO SOURCE OF IGNIT & FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF W/OUT
RISK. USE WATER SPRAY TO REDUCE VAP. FOR SMALL SPILLS, TAKE UP
W/SAND/OTHER ABSORB MATL & PLACE INTO CONTRS FOR LATER DISP. FOR
LRG SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMOKING,
FLAME,(ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:MEET BONDING & GROUNDING GUIDELINES
SPECIFIED IN NFPA 77-1983, REC PRACTICE ON STATIC ELECT. PROT
AGAINST PHYSICAL DMG. SEPERATE FROM OXIDIZING MATL.
Other Precautions:STORE IN COOL, DARK & WELL VENT AREA, AWAY FROM
SOURCES OF HEAT. OUTSIDE/DETACHED STOR IS PREFERABLE. INSIDE STOR
SHOULD BE IN STANDARD FLAMM LIQ STOR ROOM/CABINET. PERIODICALLY
CHECK FOR PEROXIDE CON TANT & MAINTAIN BELOW 1% BY (ING 12)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM
LEV FOUND IN WORK PLACE, MUST NOT EXCEED WORKING LIM OF RESP & BE
NIOSH/MSHA APPROVED. FOR MORE INFORMATION CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL VENTILATION TO MEET
EXPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH FOUNTAIN WITHIN IMMEDIATE WORK AREA
FOR EMERGENCY USE. IMPERVIOUS CLOTHING AND EQUIPMENT TO PREVENT
CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:RISING SOUND FROM VENT SAFETY DEVICE/ANY DISCOLORATION
OF STOR TANK DUE TO FIRE. EXTING ONLY IF FLOW CAN BE STOPPED.
EVACUATE TO A RADIUS OF 1500 FT FOR UNCONTROLLABLE FIRES. CONDTNS T
O AVOID:TO DRYNESS, AN EXPLOS MAY OCCUR. MATL TO AVOID:
TETRAHYDROALYMINATE & OTHERS. CONTACT NEHC FOR MORE (ING 3)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:153F,67C
Melt/Freeze Pt:M.P/F.P Text:-162F,-108C
Vapor Pres:145 @ 20C
Vapor Density:2.5
Spec Gravity:0.8892
Evaporation Rate & Reference:14.5 (BUTYL ACETATE = 1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, VOLATILE, MOBILE LIQUID WITH AN
ETHER-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS VIOLENTLY/EXPLOS W/LITHIUM ALUMINUM ALLOYS, STRONG OXIDIZERS,
POTASSIUM DIOXIDE, SODIUM (SUPDAT)
Stability Condition to Avoid:IF PEROXIDATION IS UNINHIBITED, MAY FORM
EXPLOS ORGANIC PEROXIDES WHEN EXPOS TO AIR. IF DISTILLED/EVAPORATED
(SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC COX.
Conditions to Avoid Polymerization:MAY POLYMERIZE EXOTHERMICALLY IN
CONTACT WITH SOME ACIDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE,
CONTACT DISTRICT DIRECTOR OF ENVIRONMENTAL PROTECTION AGENCY, 40
CFR 262. HAZ WASTE #U213
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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