===================== Product Identification =====================
MSDS NAME:SO-A-94, NITRIC ACID SOLUTIONS
NIIN:00N015823
MSDS Number: BPPRX
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:ING 10:OCCSNLY LIFTING LIDS UNTIL NO EVID OF CHEM REMAINS
(AT LEAST 15-20 MIN). CONTINUE IRRIGATING W/NORMAL (ING 12)
RTECS #:9999999ZZ
Name:ING 11:SALINE UNTIL PH RETURNED TO NORM (30-60 MIN). COVER
W/STERILE BANDAGES. GET MD IMMED. INGEST:DO NOT USE (ING 13)
RTECS #:9999999ZZ
Name:ING 12:GASTRIC LAVAGE OR INDUCE VOMIT. DILUTE SUBSTANCE
IMMED W/LG AMTS OF MILK/WATER. INGESTED ACIDS SHOULD BE (ING 14)
RTECS #:9999999ZZ
Name:ING 13:DILUTED APPROX 100X TO RENDER IT HARMLESS TO TISS.
TREAT ASPHYXIA FROM GLOTTAL EDEMA BY MAINTAINING (ING 15)
RTECS #:9999999ZZ
Name:ING 14:AIRWAY. TREAT SHOCK. GET MD IMMED. ANTIDOTE:NO
SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
RTECS #:9999999ZZ
Name:NITRIC ACID (SARA III)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 0.4-4%
OSHA PEL:2 PPM; 4 PPM STEL
ACGIH TLV:2 PPM; 4 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 96-99.6%
Name:EFTS OF OVEREXP:INGEST:IMMED PAIN IN MOUTH, THROAT & STOM
MAY BE FOLLOWED BY NAUSEA, VOMIT, DIARRHEA, & POSSIBLY (ING 4)
RTECS #:9999999ZZ
Name:ING 3:CIRCULATORY COLLAPSE. ASPHYXIA IS POSS. BURNS OF GI
TRACT MAY BE SEVERE ENOUGH TO CAUSE PERFORATION OF (ING 5)
RTECS #:9999999ZZ
Name:ING 4:ESOPHAGUS & STOM WHICH MAY BE FOLLOWED BY
MEDIASTINITIS OR PERITONITIS, INDICATED BY FEVER. (ING 6)
RTECS #:9999999ZZ
Name:ING 5:CHRONIC:INHAL:RPTD/PRLNGD EXPOS MAY CAUSE DENTAL
EROSION FOLLOWED BY JAW NECROSIS, CHRONIC COUGH & BRONCH (ING 7)
RTECS #:9999999ZZ
Name:ING 6:OR CHEMICAL PNEUMONITIS & GI DISTURBANCES.
SKIN:DEPENDING ON CONC & DURATION OF EXPOS, RPTD/PRLNGD EXPOS (ING
8)
RTECS #:9999999ZZ
Name:ING 7:MAY CAUSE SYMPS AS THOSE OF ACUTE EXPOS.
EYE:DEPENDING ON CONC & DURATION OF CNTCT, RPTD/PRLNGD EXPOS MAY
(ING 9)
Name:ING 8:CAUSE SYMPTOMS AS THOSE OF ACUTE EXPOSURE. INGEST:NO
DATA AVAILABLE.
RTECS #:9999999ZZ
Name:FIRST AID PROC:DRESSING. BANDAGE SECURELY BUT NOT TOO
TIGHTLY. GET MD IMMED. EYE:WASH IMMED W/LG AMTS OF WATER, (ING 11)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE COUGHING,HDCH,
DIZZ & WEAKNESS. DELAYED SYMPS MAY INCLUDE DRYNESS OF THROAT &
NOSE, CHEST PAIN/TIGHTNESS, DYSPNEA, FROTHY SPUTUM, HYPOTENSION &
CYANOSIS FOLLOWED BY PNEUMONITIS & PULM EDEMA WHICH MAY BE FATAL.
SCAR TISSUE MAY CAUSE STRICTURE OF PYLORUS/ESOPHAGUS. SKIN:DIRECT
CNTCT(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:W/LIQ/VAP CAUSES IMMED SEVERE &
PENETRATING BURNS, STAINING SKIN YELLOW/ YELLOWISH-BROWN. DILUTE
SOLNS PRDCE MILD IRRIT & HARDEN SKIN W/OUT DESTROYING IT.
EYE:DIRECT CNTCT W/LIQ MAY CAUSE PAI N, PHOTOPHOBIA, TEARING,
EDEMA, CORNEALULCERATION, SEVERE BURNS & NECROSIS OF DEEPER TISSUES
W/PERMANENT DAMAGE.(ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF
RESP. MAINTAIN AIRWAY & BLOOD PRESS & GIVE O*2 IF AVAIL. KEEP
WARM/AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MD IMMED.
SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECTED AREA
W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM
REMAINS (AT LEAST 15-20 MIN). IN CASE OF CHEM BURNS, COVER AREA
W/STERILE, DRY (ING 10)
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER
SPRAY/STANDARD FOAM. LARGER FIRES, USE WATER SPRAY, FOG OR STANDARD
FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
MOVE CNTNRS FROM FIRE AREA IF POSS. COOL CNTNRS EXPSD TO FLAMES
W/WATER FROM SIDE UNTIL WELL (SUPP DATA)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER W/SODA ASH. SCOOP UP & PLACE IN SUITABLE
CNTNR. RQ:1000 LBS. SARA 304 REQ THAT RELEASE =/> RQ FOR THIS
SUBSTANCE BE IMMED REPORTED TO LOCAL EMER PLANNING COMMITTEE &
STATE EMER RESPONSE COMMISSI ON.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONSULT NFPA PUBLICATION 43A, STORAGE
OF LIQUID AND SOLID OXIDIZING MATERIALS, FOR STORAGE REQUIREMENTS.
Other Precautions:MAY IGNITE OTHER COMBUSTIBLE MATERIALS (WOOD, PAPER,
OIL, ETC.). REACTS VIOLENTLY W/WATER & FUELS. FLAMMABLE, POISONOUS
GASES MAY ACCUMULATE IN TANKS & HOPPER CARS. RUNOFF TO SEWER MAY
CREATE FIRE/EXP LOSION HAZARD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAMINATION LEVELS FOUND IN WORK PLACE & BE NIOSH/MSHA APPROVED.
FOR MORE SPECIFIC INFORMATION CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:APPROP PROT (IMPERVIOUS) CLTHG & EQUIP.
PROVIDE EYE WASH FOUNTAIN & QUICK DRENCH SHOWER W/IN IMMED WORK
AREA FOR EMER.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
FIRE FIGHT PROC:AFTER FIRE OUT. STAY AWAY FROM STOR TANK ENDS. DO NOT
USE WATER DIRECTLY ON MATL. IF LG AMTS OF COMBUST MATLS INVOLVED,
USE WATER SPRAY/FOG IN FLOODING AMTS. USE WATER SPRAY TO ABSORB
CORR VAPS. COOL CNTNRS W/FLOODING AMTS OF WATER FROM AS FAR A
DISTANCE AS POSS. AVOID BRTHG CORR VAPS; KEEP UPWIND.
================== Physical/Chemical Properties ==================
HCC:D4
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32F,0C
Vapor Pres:14 @ 20C
Vapor Density:0.7(WATER)
Spec Gravity:1
pH:ACIDIC
Evaporation Rate & Reference:>1 (ETHER = 1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACETIC ACID, CYANATES, ETHANOL, METALS, REDUCING AGENTS. FOR A COMPLETE
LISTING OF MATERIALS TO AVOID CNTCT NEHC .
Stability Condition to Avoid:REACTS VIOLENTLY W/WATER & FUELS.
Hazardous Decomposition Products:THERMAL DECOMP MAY INCLUDE HIGHLY
TOXIC NO*X, INCLUDING NITRIC OXIDE & NITROGEN DIOXIDE & HYDROGEN
NITRATE.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE CONTACT DISTRICT
DIRECTOR OF THE EPA.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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