| MSDS | : | A4074, ETHYL ALCOHOL DENATURED | | CAS | : | 64-17-5
67-56-1
141-78-6
108-10-1
7732-18-5 | | NAME | : | ing 11: w/flooding water from as far as poss. avoid brthg
hlth haz:allergic cont derm.ing 2:irrit.absorb causes
ing 13:acidosis & death.eye:ing 1:temp irrit, lacrimation,
ing 14:injury of corneal epithelium & hyperemia of
ing 15:pain, atrophy, concentric visual fields &
ing 16:ingest:ing 1:confusion, disorientation, loss of
ing 17:& urination, drow, stupor, coma, convulsions &
ing 18:weakness, fatigue, restlessness, insomnia & leg
ing 19:back, abdomen & extremities, muscular
ing 20:narcosis, apathy, delirium, coma, excitement, mania
ing 21:dizz, nervousness, tremors, fatg, naus, narcosis,
ing 22:blindness. skin:ing 1:defat & dry fissured derm. ing
ing 23:impairment & optic neuritis.eye:ing 2:conjunctivitis
ing 24:liver, kidneys & brain efts, gastroenteritis,
ethyl alcohol; (ethanol). vap dens: 1.6. ld50: (oral, rat)
methanol; (methyl alcohol). ld50: (oral, rat) 5628 mg/kg.
acetic acid, ethyl ester; (ethyl acetate) (sara iii)
2-pentanone, 4-methyl-; (methyl isobutyl ketone) (sara
aviation gasoline; (aviation gas)
water
supp data:h*2o/3-5% sodium bicarbonate soln unless 2
ing 7:following ingest. antidote:naloxone, 0.01 mg/kg, by
fire fight proc:stor tank ends.for massive fire in stor
ing 9:area & let burn.w/draw immed if rising sound from
ing 10:fire.exting only if flow can be stopped.use flooding
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===================== Product Identification =====================
MSDS NAME:A4074, ETHYL ALCOHOL DENATURED
NIIN:00N023404
MSDS Number: BPPTL
=== Responsible Party ===
Company:FISHER SCIENTIFIC, CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100 OR 201-796-7523
Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:ING 11: W/FLOODING WATER FROM AS FAR AS POSS. AVOID BRTHG
VAPS, KEEP UPWIND.
RTECS #:9999999ZZ
Name:HLTH HAZ:ALLERGIC CONT DERM.ING 2:IRRIT.ABSORB CAUSES
SYSTEMIC EFTS, CNS DEPRESS, NARCOSIS, OPTIC NEURITIS, (ING 14)
RTECS #:9999999ZZ
Name:ING 13:ACIDOSIS & DEATH.EYE:ING 1:TEMP IRRIT, LACRIMATION,
BURNING & STINGING, W/REFLEX CLOSURE OF LIDS.TEMP (ING 15)
RTECS #:9999999ZZ
Name:ING 14:INJURY OF CORNEAL EPITHELIUM & HYPEREMIA OF
CONJUNCTIVA.ING 2:BLURRED/DIMMED VISION W/OPTIC NEURITIS, (ING 16)
RTECS #:9999999ZZ
Name:ING 15:PAIN, ATROPHY, CONCENTRIC VISUAL FIELDS &
PHOTOPHOBIA, TRANSIENT/PERM, COMPLETE/BILATERAL BLINDNESS. (ING 17)
RTECS #:9999999ZZ
Name:ING 16:INGEST:ING 1:CONFUSION, DISORIENTATION, LOSS OF
MOTOR NERVE CONTROL, SHALLOW RESP, INVOLUNTARY DEFECATION(ING 18)
RTECS #:9999999ZZ
Name:ING 17:& URINATION, DROW, STUPOR, COMA, CONVULSIONS &
DEATH. ING 2:COUGHING, HDCH, DULLNESS, VERTIGO, ANOREXIA, (ING 19)
RTECS #:9999999ZZ
Name:ING 18:WEAKNESS, FATIGUE, RESTLESSNESS, INSOMNIA & LEG
CRAMPS, NAUS, OCCASIONAL VOMIT & DIARR, VIOLENT PAIN IN (ING 20)
RTECS #:9999999ZZ
Name:ING 19:BACK, ABDOMEN & EXTREMITIES, MUSCULAR
INCOORDINATION, SWEATING, COLD & CLAMMY EXTREMITIES, DYSPNEA, (ING
21)
RTECS #:9999999ZZ
Name:ING 20:NARCOSIS, APATHY, DELIRIUM, COMA, EXCITEMENT, MANIA
& CONVULSIONS. CHRONIC:ING 1:IRRIT OF MUC MEMB, HDCH,(ING 22)
RTECS #:9999999ZZ
Name:ING 21:DIZZ, NERVOUSNESS, TREMORS, FATG, NAUS, NARCOSIS,
LACK OF CONC & SOMNOLENCE. ING 2:VISUAL IMPAIRMENT, (ING 23)
RTECS #:9999999ZZ
Name:ING 22:BLINDNESS. SKIN:ING 1:DEFAT & DRY FISSURED DERM. ING
2:DEFAT, ERYTHEMA, SCALING & ECZEMATOID DERM, VISUAL(ING 24)
RTECS #:9999999ZZ
Name:ING 23:IMPAIRMENT & OPTIC NEURITIS.EYE:ING 2:CONJUNCTIVITIS
& VISUAL IMPAIRMENT.INGEST:ING 1:WT LOSS, (ING 23)
RTECS #:9999999ZZ
Name:ING 24:LIVER, KIDNEYS & BRAIN EFTS, GASTROENTERITIS,
CIRRHOSIS, POLYNEURITIS, BLINDNESS, LIVER, KIDNEY & BRAIN DAMAGE.
RTECS #:9999999ZZ
Name:ETHYL ALCOHOL; (ETHANOL). VAP DENS: 1.6. LD50: (ORAL, RAT)
7060 MG/KG.
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 88%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Name:METHANOL; (METHYL ALCOHOL). LD50: (ORAL, RAT) 5628 MG/KG.
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 4.6%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (SARA III)
CAS:141-78-6
RTECS #:AH5425000
Fraction by Wt: 0.9%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA
III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 0.9%
OSHA PEL:100 PPM/75 STEL
ACGIH TLV:50 PPM/75 STEL; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AVIATION GASOLINE; (AVIATION GAS)
Fraction by Wt: 0.9%
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 4.6%
Name:SUPP DATA:H*2O/3-5% SODIUM BICARBONATE SOLN UNLESS 2
HRS/MORE SINCE INGEST.SYRUP OF IPECAC MAY BE GIVEN PROMPTLY (ING 8)
RTECS #:9999999ZZ
Name:ING 7:FOLLOWING INGEST. ANTIDOTE:NALOXONE, 0.01 MG/KG, BY
IV, HAS AROUSAL EFT IN ACUTE ALCOHOLIC COMA.
RTECS #:9999999ZZ
Name:FIRE FIGHT PROC:STOR TANK ENDS.FOR MASSIVE FIRE IN STOR
AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZ, W/DRAW FROM(ING 10)
RTECS #:9999999ZZ
Name:ING 9:AREA & LET BURN.W/DRAW IMMED IF RISING SOUND FROM
VENTING SAFETY DEVICE/ANY TANK DISCOLORATION DUE TO (ING 11)
RTECS #:9999999ZZ
Name:ING 10:FIRE.EXTING ONLY IF FLOW CAN BE STOPPED.USE FLOODING
WATER AS FOG; SOLID STREAMS INEFTIVE. COOL CNTNRS (ING 12)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:ING 1:TEMP IRRIT OF UPPER
RESP TRACT & COUGHING, HDCH, STUPOR, FATG, LASSITUDE & LOSE
APPETITE LOSS.CNS DEPRESS W/HDCH, DIZZ, DULLNESS & DROW.ING
2:INEBRIATION, COUGHING, HDCH, TINNITUS, D ULLNESS, ANOREXIA,
WEAKNESS, VERTIGO, FATG, RESTLESSNESS, INSOMNIA, LEG CRAMPS, NAUS,
VOMIT, COLIC, (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CONSTIP, VIOLENT PAIN IN BACK, ABDOMEN
& EXTREMITIES, MUSCULAR INCOORDINATION, COLD, CLAMMY EXTREMITIES,
DYSPNEA & NARCOSIS, DELIRIUM, COMA, BLURRED/DIMMED VISION,
BLINDNESS, CYANOSIS, COMA, LIVER/KIDNEY DAM, CEREBRAL & PULM
EDEMA, DEATH, CNS EFTS.SKIN: ING 1:MILD REDNESS & BURNING. SENSIT
IN SOME/ (ING 13)
Medical Cond Aggravated by Exposure:ING 1: PERSONS WITH LIVER DISEASE.
ALLERGIC REACTIONS TO ALCOHOLS HAVE BEEN REPORTED. ING 2: PERSONS
WITH CHRONIC RESPIRATORY, LIVER, KIDNEY, EYE OR SKIN DISEASES.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE TO FRESH AIR IMMED.IF BRTHG HAS STOPPED, PERFORM
ARTF RESP.KEEP WARM & @ REST.TREAT SYMPTOMATICALLY &
SUPPORTIVELY.GET MD. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED.WASH
AREA W/SOAP/MILD DETE RGENT & LG AMTS OF WATER UNTIL NO EVID OF
CHEM REMAINS (APPROX 15-20 MIN).GET MD. EYE:WASH IMMED W/LG AMTS OF
WATER/NORM SALINE, OCCASIONALLY LIFTING LIDS, UNTIL NO EVID OF CHEM
REMAINS (SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:>56F,>13C
Lower Limits:3.3% (ING 1)
Upper Limits:19% (ING 1)
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR
ALCOHOL FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG/ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.MOVE CNTNR FROM FIRE AREA & COOL W/WATER FROM SIDE UNTIL WELL
AFTER FIRE IS OUT.STAY AWAY FROM (ING 9)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPSD TO
HEAT/FLAME.VAPS ARE HVR THAN AIR & MAY TRAVEL TO IGNIT SOURCE &
FLASH BACK.VAP-AIR MIX EXPLO ABOVE FL PT.CNTNR (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGNIT SOURCES.DO NOT TOUCH SPILL.STOP
LEAK IF W/OUT RISK.REDUCE VAPS W/H*2O SPRAY.SM SPILLS:TAKE UP
W/SAND/OTHER ABSORB & PLACE IN CNTNRS FOR DISP. LG SPILLS:DIKE
AHEAD OF SPILL FOR DISP.NO S MOKING, FLAMES/FLARES IN HAZ AREA!
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.106. OBSERVE
ALL FED, STATE & LOCAL REGS WHEN STORING SUBSTANCE. FOR ASSISTANCE
CONT DISTRICT DIRECTOR OF EPA.
Other Precautions:SUBSTANCES W/LOW ELECTROCONDUCTIVITY, WHICH MAY BE
IGNITED BY ELECTROSTATIC SPKS, SHLD BE STORED IN CNTNRS WHICH MEET
BONDING & GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983, RECD
PRACT ON STATIC ELE C. STORE AWAY FROM INCOMP SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
THE CONTAMINATION LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED
WORKING LIMITS OF RESPIRATOR AND BE JOINTLY APPROVED BY NIOSH/MSHA.
FOR MORE SPECIFIC INFO C ONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION
VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:APPROPRIATE PROTECTIVE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING
AND EQUIPMENT TO PREVENT REPEATED OR PROLONGED SKIN CONTACT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
EXPLO HAZ:EXPLODES IN HEAT OF FIRE.VAP EXPLO & POIS HAZ
INDOORS/OUTDOORS/IN SEWERS.RUNOFF TO SEWER MAY CREATE FIRE/EXPLO
HAZ. SPILL PROC:KEEP UNNEC PEOPLE AWAY; ISOLATE HAZ AREA & DENY
ENTRY. FIRST AI D PROC:(APPROX 15-20 MIN).GET MD.INGEST:REMOVE BY
GASTRIC LAVAGE W/TAP WATER/EMESIS/BY GASTRIC LAVAGE W/WARM (ING 7)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:>173F,>78C
Vapor Density:SEE ING 1
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. FOR A MORE COMPLETE LISTING OF MATERIALS TO AVOID
CONTACT NEHC .
Stability Condition to Avoid:MAY BE IGNITED BY HEAT, SPARKS OR FLAMES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC OXIDES OF CARBON AND FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGS WHEN
DISPOSING OF SUBSTANCE. FOR ASSISTANCE, CONT DISTRICT DIRECTOR OF
EPA. DISPOSAL MUST BE I/A/W STANDARDS APPLIC TO GENERATORS OF
HAZARDOUS WASTE, 40 CFR 2 62. EPA HAZ WASTE NUMBER D001.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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