===================== Product Identification =====================
MSDS NAME:CALCO PREMIUM UNLEADED GASOLINE
NIIN:00-264-4538
MSDS Number: BPXDD
=== Responsible Party ===
Company:CHEVRON ENVIRONMENTAL HEALTH CENTER INC.
Address:15299 SAN PABLO AVE.
Box:4054
City:RICHMOND
State:CA
ZIP:94804-0054
Country:US
Info Phone Num:415-233-3737
Emergency Phone Num:415-233-3737
CAGE:0AHD1
=== Contractor Identification ===
Company:CHEVRON ENVIRONMENTAL HEALTH CENTER INC
Address:15299 SAN PABLO AVE
Box:4054
City:RICHMOND
State:CA
ZIP:94804
Country:US
Phone:800-582-3835
CAGE:0AHD1
Company:NEW WEST PETROLEUM INC
Address:1831 16TH STREET
Box:188410
City:SACRAMENTO
State:CA
ZIP:95818-8410
Country:US
Phone:916-443-0890
CAGE:0VGM1
============= Composition/Information on Ingredients =============
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <4%.O
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:P-XYLENE (P-DIMETHYLBENZENE) (SARA III)
CAS:106-42-3
RTECS #:ZE2625000
Fraction by Wt: <4.3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:M-XYLENE (M-DIMETHYLBENZENE) (SARA III)
CAS:108-38-3
RTECS #:ZE2275000
Fraction by Wt: <8.8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/15OSTEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:O-XYLENE (O-DIMETHYLBENZENE) (SARA III)
CAS:95-47-6
RTECS #:ZE2450000
Fraction by Wt: <4.3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <14.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CYCLOHEXANE (SARA III)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: <2.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: <15.0%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <4.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (RAT) ORAL >5 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE CONTACT: SLIGHTLY IRRITATING. MAY
CAUSE PROLONGED IMPAIRMENT OF VISION. SYMPTOMS INCLUDE TEARS,
SWELLING, REDNESS, BLURRED VISION. SKIN: PROLONGED OR FREQUENTLY
CONTACT MAY CAUSE CRACKED, DRY, DEF ATTING OF THE SKIN. INHALATION:
SLIGHTLY TOXIC TO INTERNAL ORGANS. INGESTION: SLIGHTLY TOXIC TO
INTERNAL ORGANS.
Explanation of Carcinogenicity:BENZENE, A COMPONENT OF THIS PRODUCT, IS
CLASSIFIED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:EARLY TO MODERATE CNS DEPRESSION MAY BE
EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA. THE DEGREE
OF TOXICITY DEPEND ON THE AMOUNT OF EXPOSURE. ASPIRATION
PNEUMONITIS MAY BE EVIDENCED BY COU GHING, LABORED BREATHING AND
CYANOSIS. KIDNEY DAMAGE MAY BE EVIDENCED BY CHANGE IN URINE OUTPUT
URINE APPEARANCE.
Medical Cond Aggravated by Exposure:PREEXISITING EYE, SKIN, AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED. IMPAIRED LIVER AND KIDNEY
FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
Eyes: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN CONTACT: FLUSH WITH WATER WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. FOLLOW BY WASHING WITH
SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION
INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED,
RESUSCITATE. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. GET MEDICAL AID.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:FIRE FIGHTING FOAMS; ALCOHOL RESISTANT TYPE (AR)
AFFF, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE
SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS MAY INCLUDE
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:LIQUID VERY QUICKLY EVAPORATES AND FORMS
VAPORS (FUMES) WHICH CAN CATCH FIRE AND BURN WITH EXPLOSIVE
VIOLENCE. INVISIBLE VAPOR SPREADS EASILY.
================== Accidental Release Measures ==================
Spill Release Procedures:DANGER. EXTREMELY FLAMMABLE. ELIMINATE ALL
IGNITION SOURCES. CLEAN UP SPILLS IMMEDIATELY. ISOLATE THE HAZARD
AREA. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. PREVENT
FROM ENTERING DRAINAGE A ND SEWER SYSTEMS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:NEVER SIPHON GASOLINE BY MOUTH. DO NOT
USE FOR CLEANING, PRESSURE APPLIANCE FUEL, OR OTHER SUCH USE. USE
ONLY IN WELL VENTILATED AREA.
Other Precautions:KEEP CONTAINER CLOSED. DO NOT TRANSFER LIQUID TO AN
UNLABELED CONTAINER. USE ONLY AS A MOTOR FUEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER CONDITIONS OF POTENTIAL HIGH EXPOSURE, THE
USE OF A NIOSH-APPROVED RESPIRATOR IS RECOMMENDED. REFER TO THE
OSHA BENZENE STANDARD TO DETERMINE THE TYPE OF RESPIRATOR IS
REQUIRED BASED ON EXPOSURE LEVELS.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Protective Gloves:NITRILE RUBBER OR VITON/NEOPRENE
Eye Protection:FACE SHIELD OR GOGGLES
Other Protective Equipment:STANDARD WORK CLOTHING. SHOES CONTAMINATED
WITH THIS PRODUCT THAT CAN NOT BE DECONTAMINATED SHOULD BE
DISCARDED.
Work Hygienic Practices:WEAR IMPERVIOUS GLOVES WHEN "DIP-STICKING
STORAGE TANKS". WORK UPWIND OF SMALL SPILLS.
Supplemental Safety and Health
DO NOT USE THIS PRODUCT AS A SOLVENT FOR CLEANING EQUIPMENT OR SKIN.
STORE SMALL QUANTITIES ONLY IN SAFETY CANS. ALLOW CONTAMINATED RAGS
TO DRY IN WELL-VENTILATED AREA BEFORE STORAGE. PRODUCT SPREADS
EASILY AND MAY FLASH BACK ALONG VAPOR TRAILS. THIS PRODUCT IS
ENTERED AS PN IND B; PN IND A LACK INFORMATION.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:VARIABLE
Vapor Pres:5-15
Vapor Density:3-4
Spec Gravity:0.7-0.8
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED LIQUID
Percent Volatiles by Volume:99+
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES. PREVENT VAPOR
ACCUMULATION.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
AND WATER VAPORS; INCOMPLETE COMBUSTION CAN PRODUCE CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT LOCAL ENVIRONMENTAL OR HEALTH
AUTHORITIES FOR APPROVED DISPOSAL OF THIS MATERIAL.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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