===================== Product Identification =====================
MSDS NAME:SOLVENT 111, GENERAL PURPOSE GRADE, INDUSTR
NIIN:00-476-5612
MSDS Number: BPXDS
=== Responsible Party ===
Company:VULCAN MATERIALS CO
Address:NO 1 METROPLEX DR
Box:7689
City:BIRMINGHAM
State:AL
ZIP:35253
Country:US
Emergency Phone Num:316-524-5751
CAGE:1B637
=== Contractor Identification ===
Company:CHEMICAL SPECIALISTS AND DEVELOPMENT INC
Address:2210 HACKBERRY LN
Box:687
City:CONROE
State:TX
ZIP:77305
Country:US
Phone:409-756-1065
CAGE:4N760
Company:VULCAN MATERIALS CO
Address:NO 1 METROPLEX DR
Box:530390
City:BIRMINGHAM
State:AL
ZIP:35253
Country:US
Phone:316-524-5751
CAGE:1B637
============= Composition/Information on Ingredients =============
Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 95.5% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:350 PPM/450 STEL
ACGIH TLV:350 PPM/450STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Name:1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)
CAS:123-91-1
RTECS #:JG8225000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 100 PPM
ACGIH TLV:S, 25 PPM; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) = 10300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE EYE & SKIN
IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CENTRAL NERVOUS
SYSTEM DEPRESSANT. LOSS OF CONSCIOUSNESS AND EVEN DEATH CAN OCCUR
AT HIGH LEVELS OF EXPOSURE.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:ABOVE 1000 PPM: DIZZINESS, DROWSINESS, THROAT
IRRITATION. UNCONSCIOUSNESS AND DEATH ABOVE 10000PPM. PROLONGED OR
REPEATED SKIN CONTACT CAN CAUSE IRRITATION, DEFATTING OF SKIN AND
DERMATITIS. SLIGHT TE MPORARY EYE IRRITATION AND/OR CORNEAL INJURY.
ASPIRATION HAZARD; CAN CAUSE CHEMICAL PNEUMONIA.
Medical Cond Aggravated by Exposure:ACUTE AND CHRONIC LIVER DISEASE AND
RHYTHM DISORDERS OF THE HEART.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CALL A PHYSICIAN. EYE: FLUSH IMMEDIATELY
WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER
PROMPTLY. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL
ATTENTION. NOTE: ADRENALIN SHOULD NEVER BE GIVEN TO PERSONS
OVEREXPOSED TO PRODUCT.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:NONFLAMMABLE
Lower Limits:7.5 %
Upper Limits:15.0 %
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE THE AREA, VENTILATE AND AVOID
BREAATHING VAPORS. DIKE AREA TO CONTAIN SPILL. CLEAN UP AREA BY
MOPPING OR WITH ABSORBENT MATERIAL AND PLACE IN CLOSED CONTAINERS.
AVOID CONTAMINATION OF GROUND AND SURFACE WATERS. DO NOT FLUSH TO
SEWEER.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:PREVENT WATER OR MOIST AIR FROM ENTERING STORAGE
TANKS OR CONTAINERS. DO NOT CUT OR WELD ON EMPTY OR FULL DRUMS. DO
NOT USE WITH ALUMINUM. READ AND FOLLOW DIRECTIONS ON LABEL. DO NOT
REUSE CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE VAPOR CONCENTRATION IS LIKELY TO EXCEED
350 PPM, AN APPROVED ORGANIC VAPOR TYPE RESPIRATOR IS ACCEPTABLE.
APPROVED SELF-CONTAINED BREATHING APPARATUS OR AIR LINE RESPIRATOR,
WITH FULL FACE PIECE , IS REQUIRED ABOVE 1000 PPM.
Ventilation:DO NOT USE IN CLOSED OR CONFINED SPACE. OPEN DOORS AND/OR
WINDOWS. USE VENTILATION TO MAINTAIN EXPOSURE LEVELS < 350 PPM
Protective Gloves:VITON, POLYVINYL ALCOHOL
Eye Protection:USE CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
CHRONIC OVEREXPOSURE TO 1,1,1 TRICHLOROETHANE HAS CAUSED LIVER TOXIC
EFFECTS IN EXPERIMENTAL ANIMALS. VAPORS ARE HEAVIER THAN AIR AND
WILL COLLECT IN LOW AREAS. DO NOT REMOVE OR DEFACE LABEL. DO NOT F
LUSH TO SEWER.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:165F,74C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:100 @20C
Vapor Density:4.6
Spec Gravity:1.32
Evaporation Rate & Reference:0.4 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILDLY SWEET ODOR
Percent Volatiles by Volume:100 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, OXIDIZERS AND REACTIVE METALS
Stability Condition to Avoid:AVOID CONTACT WITH OPEN FLAME, ELECTRIC
ARCS OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION
Hazardous Decomposition Products:WHEN INVOLVED IN FIRE,
1,1,1-TRICHLOROETHANE EMITS HIGHLY TOXIC AND IRRITATING HYDROGEN
CHLORIDE, CHLORINE AND PHOSGENE
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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