===================== Product Identification =====================
MSDS NAME:COMPRESSED ASBESTOS RUBBER GASKET MATERIAL
NIIN:00-110-3601
MSDS Number: BQDYG
=== Responsible Party ===
Company:KLINGER RICHARD INC
Address:2350 CAMPBELL RD
City:SIDNEY
State:OH
ZIP:45365-9501
Country:US
Info Phone Num:513-498-1181
Emergency Phone Num:513-498-1181
Preparer's Name:PHIL CORNOCK
CAGE:9U500
=== Contractor Identification ===
Company:KLINGER RICHARD INC
Address:2350 CAMPBELL RD
Box:City:SIDNEY
State:OH
ZIP:45365-9501
Country:US
Phone:937-498-1181
CAGE:9U500
============= Composition/Information on Ingredients =============
Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
Fraction by Wt: 70 - 90%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9293
Name:POLYCHLOROPRENE/CHLOROPRENE RUBBER
CAS:9010-98-4
Fraction by Wt: 6 - 11%
Other REC Limits:NONE RECOMMENDED
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9293
Name:1,3 BUTADIENE POLYMER
CAS:9003-17-2
Fraction by Wt: 2 - 6%
Other REC Limits:NONE RECOMMENDED
Name:ETHYLENE THIOUREA (SARA III)
CAS:96-45-7
RTECS #:NI9625000
Fraction by Wt: <0.3%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV (ASBESTOS) 2 & PEL 0.2 FBS/CC.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE-NONE UNDER NORMAL CONDITIONS OF
USE.IF ASBESTOS FIBERS ARE RELEASED FROM RUBBER MATRIX,CAN CAUSE
EYE,SKIN,GI & RESPIRATORY TRACT IRRITATION.CHRONIC-ASBESTOS CAN
CAUSE IRREVERSIBLE ASBESTOSIS,LUN G DISEASE & LUNG CANCER.SMOKING
GREATLYINCREASES THE RISKS.SYMPTOMS SUCH AS LABORED BREATHING MAY
SHOW 15-20 YR LATER.
Explanation of Carcinogenicity:ASBESTOS IS REGULATED BY OSHA AS A
CARCINOGEN.
Effects of Overexposure:NONE UNDER NORMAL CONDITIONS OF USE.IF ASBESTOS
FIBERS ARE RELEASED FROM RUBBER MATRIX,CAN CAUSE EYE,SKIN,GI &
RESPIRATORY TRACT IRRITATION.CHRONIC EXPOSURE CAN CAUSE
IRREVERSIBLE ASBESTOSIS,LUNG DISE ASE & LUNG CANCER.SMOKING GREATLY
INCREASES THE RISKS.SYMPTOMS SUCH AS LABORED BREATHING MAY SHOW
15-20 YR LATER.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS SUCH AS DERMATITIS, RESPIRATORY PROBLEMS, LUNG DISEASE,
BRONCHIAL HYPER-REACTIVITY OR ANY CONDITION THAT MAY BE AGGRAVATED
BY NUISANCE DUST OR FIBERS.
======================= First Aid Measures =======================
First Aid:SEEK MEDICAL ATTENTION IF SYMPTOMS DEVELOP. IN CASE OF EYE
IRRITATION GENTLY RINSE WITH WATER FOR 15 MINUTES WHILE KEEPING
EYELIDS OPEN. DO NOT RUB EYES. SKIN: WASH FREQUENTLY WITH SOAP AND
WATER. INH ALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE
VOMITING. SEE A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NON FLAMMABLE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:AVOID BREATHING FUMES. WEAR PROTECTIVE
CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS
OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:ASBESTOS FIBERS MAY BE RELEASED. FINE
RUBBER PARTICLES MAY PRODUCE A WEAK EXPLOSION HAZARD. WHEN THE
RUBBER IS EXTINGUISHED, COOL FURTHER TO PREVENT REIGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:TREAT DUST AS FREE ASBESTOS. DO NOT DRY SWEEP
OR USE COMPRESSED AIR. WET METHOD SHOULD BE USED FOR EXTRACTION OF
DUST AND DEBRIS. HIGH EFFICIENCY PARTICULATE APPARATUS (HEPA)
VACUUMS SHOULD BE USED. A VOID WATER-POLLUTION.
Neutralizing Agent:NOT APPLICABLE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE- AVOID CREATING DUST BY
SANDING OR GRINDING THE PRODUCT.
Other Precautions:USE IN WELL VENTILATED AREA. AVOID BREATHING DUST OR
FIBERS. MINIMIZE CONTACT WITH SKIN. AVOID CONTACT WITH EYES. DO NOT
RAISE DUST. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
DRINKING. KEEP AWAY FROM REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED HIGH EFFICIENCY FIBERS/FUMES
RESPIRATOR WHEN AIRBORNE FIBER CONCENTRATIONS EXCEED THE PEL.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. NONE NORMALLY REQUIRED.
Protective Gloves:LEATHER, COTTON OR RUBBER IF FRIABLE
Eye Protection:DUST-RESISTANT SAFETY GOGGLES IF FRIABLE
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER, WORK
CLOTHING AND APRON AS REQUIRED. DO NOT WEAR CONTACT LENSES
Work Hygienic Practices:DON'T TAKE PROTECTIVE GEAR/CLOTHING HOME IF
EXPOSED TO DUST. DON'T SHAKE. DON'T EAT IN AREA WHERE ASBESTOS/DUST
PRESENT.
Supplemental Safety and Health
AS MANUFACTURED, GASKET CONTAINING ASBESTOS DOES NOT PRESENT A HAZARD.
ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS, THEN ASBESTOS
FIBERS MAY BE RELEASED AND BECOME AIRBORNE.
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:1.65 - 1.85
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK SHEET MATERIAL - FAINT SOLVENT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES
Stability Condition to Avoid:AVOID INHALATION OR INGESTION OF DUST.
AVOID GENERATING DUST OR FIBERS.
Hazardous Decomposition Products:CO, CO2, HCL. PYROLYTIC PRODUCTS FROM
CHLOROPRENE RUBBER MUST BE CONSIDERED TOXIC.
==================== Disposal Considerations ====================
Waste Disposal Methods:APPROVED LANDFILL. WASTE SHOULD BE CONTAINED IN
IMPERMEABLE BAGS, LABELED AND DISPOSED IN ACCORDANCE WITH ALL
LOCAL, STATE AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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