===================== Product Identification =====================
MSDS NAME:METCO 443, 443NS
NIIN:00-629-8275
MSDS Number: BQDZT
=== Responsible Party ===
Company:METCO INCORPORATED
Address:1101 PROSPECT AVENUE
City:WESTBURY
State:NY
ZIP:11590-2799
Country:US
Info Phone Num:516-334-1300
Emergency Phone Num:516-334-1300
CAGE:HO565
=== Contractor Identification ===
Company:METCO INC, SUB OF THE PERKIN-ELMER CORP
Address:1101 PROSPECT AVENUE
Box:City:WESTBURY
State:NY
ZIP:11590-2724
Country:US
Phone:516-334-1300
CAGE:39918
Company:METCO INCORPORATED
Address:1101 PROSPECT AVENUE
Box:1006
City:WESTBURY
State:NY
ZIP:11590-2799
Country:US
Phone:516-334-1300
CAGE:HO565
============= Composition/Information on Ingredients =============
Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9293
Name:MANGANESE (SARA III)
CAS:7439-96-5
RTECS #:OO9275000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9293
Name:ORGANIC BINDERS
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV(MG/M3): NITRIC OXIDE=30; OZONE=0.2
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:NICKEL: SENSITIVE DERMATITIS; ASTHMA
ALLERGIC, NASAL CAVITIES. ALIUMINUM: POSSIBLE CONTRIBUTOR TO
SHAVERS DISEASE. MAY BE IMPLICATED BY ALZHIMERS DISEASE. MANGANESE:
PARKINSON'S, ASTHENIA, INSOMNIA, M ENTAL, METAL FUME FEVER. IRON:
BENIGN PNEUMONOCONIOSIS.
Explanation of Carcinogenicity:NICKEL IS A LISTED CARCINOGEN TO MAN BY
NIOSH. CHROMIUM IS A SUSPECTED CARCINOGEN IN ANIMALS BY IARC.
Effects of Overexposure:MANGANESE: DRY THROAT, COUGH, TIGHT CHEST,
DYSPNEA, RALES, LOW-BACK PAIN, VOMIT, MALAISE, FATIGUE. POSSIBLE
EYE, SKIN & RESPIRATORY IRRITATION.
======================= First Aid Measures =======================
Eyes: FLOOD EYES WITH WATER. IF IRRITATION PERSISTS, CONSULT
A PHYSICIAN. SKIN: IF SKIN IRRITATION OCCURS, WASH WITH SOAP AND
WATER TO REMOVE POWDER. INHALATION: EXPOSE TO FRESH AIR. INGESTION:
CONSUL T A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE CLASS D FIRE EXTINGUISHER.
Fire Fighting Procedures:TREAT AS A METALLIC FIRE.
Unusual Fire/Explosion Hazard:MODERATE FIRE HAZARD IN THE FORM OF DUST
WHEN EXPOSED TO FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:MATERIAL THAT IS SPILLED ONTO THE FLOOR MAY
BECOME AIRBORNE BY NORMAL PLANT ACTIVITY. SWEEP UP ANY SPILLS IN
THE AREA. KEEP THESE MATERIALS FROM BECOMING A SOURCE OF AIR
CONTAMINATION.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID EXCESSIVE SKIN CONTACT AND ORAL
INGESTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATOR APPROVED BY NIOSH FOR
DUST/FUMES/MISTS SHOULD BE WORN AT ALL TIMES DURING THE THERMAL
SPRAY PROCESS TO PROTECT OPERATOR FROM DUST AND FUMES.
Ventilation:LOCAL EQUIPMENT DESIGNED TO CREATE AN AIR VELOCITY OF
200FPM
Protective Gloves:ALUMINIZED GLOVES DURING SPRAY PROCESS.
Eye Protection:"SEE SUPPLEMENTAL DATA"
Other Protective Equipment:ALUMINIZED APRON DURING PLASMA SPRAYING.
WEAR EAR PROTECTION IF THE OPERATOR IS SUBJECTED TO EXCESSIVE
LEVELS OF NOISE.
Work Hygienic Practices:MINIMIZE BREATHING DUST. CLEANSE SKIN
THOROUGHLY AFTER CONTACT, BEFORE BREAKS AND MEALS, AND AT THE END
OF WORK PERIODS.
Supplemental Safety and Health
THE FOLLOWING LENS SHADES ARE RECOMMENDED FOR THE PROCESS INDICATED.
COMBUSTION SPRAYING SHADE #5, PLASMS SPRAYING UP TO 40 KW SHADE #9,
40 TO 60 KW SHADE #10 AND GREATER THAN 60 KW SHADE #11.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:1300-2600F
Solubility in Water:NEGLIGIBLE
Appearance and Odor:POWDER; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:CHLORINATED HYDROCARBON VAPORS PRESENT
NEAR PLASMA FLAME MAY BE DECOMPOSED TO PHOSGENE.
Hazardous Decomposition Products:OZONE AND NITRIC OXIDE ARE FORMED BY
PLASMA FLAME (INDEPENDENT OF POWDER; SIMILIAR TO WELDING FUMES).
Conditions to Avoid Polymerization:AVOID EXCEEDING THE TLV LIMIT OF 30
MG/M3 & 0.2 MG/M3 FOR NITRIC OXIDE & OZONE RESPECTIVELY; 5MG/M3 FOR
MANGANESE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT LOCAL & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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