===================== Product Identification =====================
MSDS NAME:AEROSOL PAINT,GREY
NIIN:00N012274
MSDS Number: BQPDJ
=== Responsible Party ===
Company:GILMAN CO,INC
Address:801 RIVERFRONT PKWY
Box:1257
City:CHATTANOOGA
State:TN
ZIP:37401
Country:US
Info Phone Num:615-752-3040
Emergency Phone Num:615-752-3040
Preparer's Name:JAMES H FASSE
CAGE:HO755
=== Contractor Identification ===
Company:FASSE PAINT CO,INC
Address:215 PINE STREET
Box:City:SHEBOYGAN FALLS
State:WI
ZIP:53085
Phone:615-752-3040
CAGE:DO269
Company:GILMAN CO
Box:City:CHATTANOOGA
State:TN
ZIP:37401
Country:US
Phone:615-756-5185
CAGE:11348
Company:GILMAN CO,INC
Address:801 RIVERFRONT PKWY
Box:1257
City:CHATTANOOGA
State:TN
ZIP:37401
Country:US
Phone:615-752-3040
CAGE:HO755
============= Composition/Information on Ingredients =============
Name:METHYL ETHYL KETONE
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 11-30%
Other REC Limits:N/K
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:LIQUIFIED PETROLEUM GAS,SWEETENED
CAS:68476-86-8
Fraction by Wt: 11-30%
Other REC Limits:1000 PPM (MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Name:N-BUTYL ALCOHOL
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 1-5%
Other REC Limits:N/K
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE)
CAS:111-15-9
RTECS #:KK8225000
Fraction by Wt: 1-5%
Other REC Limits:N/K
OSHA PEL:100 PPM SKIN
ACGIH TLV:5 PPM SKIN
Name:XYLOL (XYLENE)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 11-30%
Other REC Limits:N/K
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:VM&P NAPHTHA (COAL TAR NAPHTHA)
CAS:8030-30-6
RTECS #:DE3030000
Fraction by Wt: 1-5%
Other REC Limits:N/K
OSHA PEL:100 PPM
ACGIH TLV:N/K
Name:MINERAL SPIRITS (COAL TAR NAPHTHA)
CAS:8030-30-6
RTECS #:DE3030000
Fraction by Wt: 1-10%
Other REC Limits:N/K
OSHA PEL:100 PPM
ACGIH TLV:N/K
Name:METHYLENE CHLORIDE
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 11-30%
Other REC Limits:N/K
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ABSORPTION OF MATL ASPIRATED INTO
LUNGS MAY RESULT IN INJURY TO OTHER BODY SYS.NIOSH STUDIES INDICATE
2-ETHOXYETHYL ACETATE HAS CAUSED REPRO DISORDERS IN LAB ANIMALS
(RATS/MICE) AND MAY HAVE THE POTEN TL FOR CAUSING SIMILAR DISORDERS
IN HUMANS .RPTD/PRLNG OVEREXPOS TO SOLV ASSOCIATED W/ PERM BRAIN &
NERVS SYS DMG.
Explanation of Carcinogenicity:METHYLENE CHLORIDE:POSSIBLY CARCINOGENIC
TO HUMANS (IARC,GROUP 2B,1987). ANTICIPATED TO BE CARCINOGEN (SUPP
DATA)
Effects of Overexposure:EYES:IRRITATION. POSSIBLE SLIGHT TRANSIENT
CORNEAL INJURY. SKIN:IRRITATION. PROLONGED OR REPEATED CONTACT MAY
CAUSE DEFATTING. INGESTION:. INHALATION:VAPORS MAY CAUSE NOSE,
THROAT AND RESPIRATOR Y TRACT IRRITATION. HIGH VAPOR CONCENTRATIONS
MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE AND SKIN DISORDERS
MAY BE AGGRAVATED BY EXPOSURE TO SOLVENT SYSTEM.
======================= First Aid Measures =======================
Eyes:FLUSH IMMED W/ LG AMTS OF H2O FOR AT LEAST 15 MIN.CALL
MD.SKIN:WASH W/ SOAP & H2O.REMOVE CONTAM CLTHG.INGEST: CALL MD
IMMED.INHAL:REMOVE FROM EXPOS.RESTORE BRTHG.CALL MD.MD NOTE:
METHYLENE CHLORI DE MATL HAS PRDCED SENSIT OF THE MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR EFT IN HUMANS.USE
ADRENERGICS (EPINEPHRINE) ONLY FOR LIFE-SUSTAINING USES IN HUMANS
EXPOS TO (SEE SUP
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:<0F,-18.4C
Lower Limits:SEE SUPP
Upper Limits:SEE SUPP
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE,DRY
CHEMICAL OR FOAM)
Fire Fighting Procedures:WEAR PRESSURE DEMAND SELF-CONTAINED BREATHING
APPRARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT/SUNLIGHT MAY CAUSE
BURSTING.TREAT AEROSOLS AS CYLINDERS OF COMPRESSED GAS UNDER
PRESS.HAZ DECOMP PROD:THERMAL DECOMP YIELDS HYDROGEN (SEE SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION,VENTILATE
AREA,AND REMOVE WITH INERT ABSORBENT AND NONSPARKING TOOLS.
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT SPRAY AROUND OPEN FLAMES/SPARK.
EXPOSURE TO HEAT,SUNLIGHT OR TEMPERATURES ABOVE 120F,48.89C MAY
CAUSE BURSTING.AVOID CONTACT WITH SKIN.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES,OR HOT SURFACES.HEAT MAY CAUSE
THE FORMATION OF HCL AND/OR PHOSGENE .DELIBERATELY CONCENTRATING
AND INHALI NG CONTENTS CAN BE HARMFUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .RESPIRATORY PROTECTION SHOULD BE IN ACCORDANCE
WITH 29 CFR 1910.134.
Ventilation:LOCAL EXHAUST IS ADEQUATE.
Protective Gloves:N/K
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CLOTHING TO MINIMIZE PHYSICAL CONTACT.
PROTECTIVE CLOTHING & EQUIPMENT IN ACCORDANCE WITH 29 CFR 1910.132
& CFR 1910.133
Work Hygienic Practices:ENSURE STRICT SANITARY CONDITIONS ARE CONFORMED
TO WHEN WORKING AROUND CHEMICALS.
Supplemental Safety and Health
LEL:1.8 (PROPELLANT).UEL:9.5 (PROPELLANT). EXPLO HAZ:CHLORIDE,VERY
SMALL AMT OF PHOSGENE,CO,CO2,& OTHER TOX CHEMS IN TRACE AMTS.ENTRY
RTE:INHAL/SKIN/INGEST .EXPLAN OF CARCIN:(NTP,GROUP 2,1989).A CGIH
A2=SUSP HUMAN CARC (1991).KNOWN TOCAUSE CANCER (CAL PROP 65,
1988).FIRST AID PROC:METHYLENE CHLORIDE .
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:<0F,-18.4C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Density:>1,AIR=1
Evaporation Rate & Reference:<1,ETHER=1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:PETROLEUM NAPHTHA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT,FLAME,SPARKS.
Hazardous Decomposition Products:THERMAL DECOMP WILL RESULT IN
FORMATION OF HCL,VERY SMALL AMT OF PHOSGENE,CO,CO2 & OTHER TOXIC
CHEMICALS IN TRACE AMTS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .ACTUATE BUTTON UNTIL ALL
PRODUCT AND PROPELLENT IS EXPELLED.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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