===================== Product Identification =====================
MSDS NAME:RUBIGAN EC FUNGICIDE 20143
NIIN:00N012251
MSDS Number: BQPCJ
=== Responsible Party ===
Company:DOWELANCO
Box:68511
City:INDIANAPOLIS
State:IN
ZIP:46268
Country:US
Info Phone Num:517-636-4400
Emergency Phone Num:517-636-4400
CAGE:2158X
=== Contractor Identification ===
Company:DOWELANCO
Address:3901 W 86TH ST
Box:68511
City:INDIANAPOLIS
State:IN
ZIP:46268-1189
Country:US
Phone:517-636-4400
CAGE:2158X
Company:ELANCO PRODUCTS CO DIV LILLY ELI AND CO
Address:3901 W 86TH ST
Box:City:INDIANAPOLIS
State:IN
ZIP:46268-1702
Country:US
Phone:317-276-2000
CAGE:21626
============= Composition/Information on Ingredients =============
Name:NAPHTHALENE
CAS:91-20-3
RTECS #:QJ0525000
Fraction by Wt: 6.6%
Other REC Limits:N/K
OSHA PEL:10 PPM
ACGIH TLV:10 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:PROPYLENE GLYCOL MONOMETHYL ETHER.TOTAL PERCENT OF
INGREDIENTS2 AND 3 IS 81.4.
CAS:107-98-2
RTECS #:UB7700000
Other REC Limits:N/K
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Name:AROMATIC 200.TOTAL PERCENT OF INGREDIENTS 2 AND 3 IS 81.4.
CAS:64742-94-5
RTECS #:WF3100000
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred
Name:ALPHA-(2-CHLOROPHENYL)-ALPHA-(4-CHLOROPHENYL)-5-PYRIMIDINE-MET
HANOL (FENARIMOL).
CAS:60168-88-9
RTECS #:UV9279400
Fraction by Wt: 12%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPP DATA: CHARCOAL WITH WATER. TREATMENT IS OTHERWISE
SYMPTOMATIC AND SUPPORTIVE. ROUTE OF ENTRY:INGESTION .
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 RAT ORAL 0.6-2.0 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:NAPHTHALENE MAY CAUSE CHANGES IN LENS
OF EYE INCLUDING DEVELOPMENT OF CATARACTS,INCREASED LIVER WEIGHT &
LIVER ENZYME ACTIVITY.PROPYLENE GLYCOL MONOMETHYL ETHER MAY CAUSE
LIVER & KIDNEY DAMAGE/ CENTRA L NERVOUS SYSTEM
DEPRESSION.ASPIRATION MAY CAUSE SEVERE PNEUMONITIS. HARMFUL IF
SWALLOWED,INHALED,ABSORBED THROUGH SKIN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:CAUSES SUBSTANTIAL BUT TEMPORARY
INJURY.SKIN:IRRITATION,POSSIBLE RASH.CAN BE ABSORBED.INGESTION:MAY
CAUSE GASTROINTESTINAL UPSET.HARMFUL IF SWALLOWED.INHALATION:MAY
CAUSE NAUSEA, VOMITING,TINGLIN G OF THE TONGUE,AND
HEADACHE.NAPHTHALENE MAY CAUSE RESPIRATORY TRACT
IRRITATION,CONFUSION,EXCITEMENT,COMA AND HEMOLYSIS.
Medical Cond Aggravated by Exposure:PERSONS WITH GLUCOSE-6-PHOSPHATE
DEHYROGENASE DEFICIENCY MAY BE MORE SUSCEPTIBLE TO HEMOLYSIS.
======================= First Aid Measures =======================
Eyes:HOLD LIDS OPEN,FLUSH W/ STEADY,GENTLE STREAM OF H2O FOR
AT LEAST 15 MIN.SEE AN OPHTHALMOLOGIST IMMED.SKIN:WASH ALL EXPOS
AREAS W/ PLENTY OF SOAP & H2O.CALL MD IF IRRIT DEVELOPS.INGEST: DO
NOT IND UCE VOMITING.CALL MD/POIS CTL CTR.GIVE 6-8 HEAPING
TEASPOONS ACTIVATED CHARCOAL W/ LRG QTY OF H2O.DO NOT GIVE ANYTHING
BY MOUTH TO UNCON PERSON.TAKE TO HOSPITAL IMMED.INH:REMOVE TO FRESH
(SEE SUPP)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:104F,40C
Lower Limits:SEE SUPP
Extinguishing Media:USE WATER,CARBON DIOXIDE,OR DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
PRESSURE BUILDUP IN EXCESSIVE HEAT/INTENSE FIRE.HAZ DECOMP
PROD:WILL EMIT TOXIC FUMES AS IT BURNS.AUTOIGNIT TEMP:738F,392C.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT MATERIALS TO CONTAIN AND CLEAN
UP SMALL SPILLS AND DISPOSE OF WASTE. REPORT LARGE SPILLS TO
CHEMTREC, DOWELANCO FOR ASSISTANCE. PROHIBIT USE OF HOT OR SPARKING
EQUIPMENT IN IMMEDIATE ARE A. PREVENT RUNOFF.
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID FREEZING. DO NOT GET IN EYES, ON
SKIN OR CLOTHING. AVOID BREATHING VAPOR/SPRAY MIST. DO NOT STORE
NEAR HEAT OR FLAME.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. TOXIC TO FISH AND
AQUATIC ORGANISMS. DO NOT APPLY WHEN WEATHER CONDITIONS FAVOR
RUNOFF OR DRIFT FROM THE TARGET AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN ENCLOSED SPACES, WEAR NIOSH/MSHA APPROVED
RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves:USE IMPERMEABLE GLOVES.
Eye Protection:CHEM WORK GOGGL.MAY ADD FULL(PROT EQUIP)
Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS COVERALL & LONG
SLEEVED SHIRT WHEN HANDLING PROD. EYE PROT:LENGTH FACESHIELD TO
GOGGLE
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
VP:7.1 MMHG @ 25C,77F.PH:4.8-5.3 (AQUEOUS 50/50).LEL:1-1.2 BY VOL @
80C,176F.FIRST AID PROC:AIR.IF BREATHING DIFCLT, GIVE
CARDIOPULMONARY RESUSCITATION.GET MED ATTN.MD NOTE:CONTAINS
AROMATIC HYDROCARB ON.CONSIDER STOMACH LAVAGE W/ CUFFED
ENDOTRACHEAL TUBE IN PLACE & IMMEDIATE ADMIN OF 6-8 TEASPOONS
ACTIVATED (SEE ING 5)
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:239F,115C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Vapor Density:1.02,AIR=1
Spec Gravity:0.998,WATER=1
pH:SUP DA
Evaporation Rate & Reference:N/K
Solubility in Water:EMULSIFIES
Appearance and Odor:CLEAR AMBER LIQUID WITH AROMATIC ODOR.
================= Stability and Reactivity Data =================
N/K
Stability Condition to Avoid:HEAT,FLAME AND FREEZING.
Hazardous Decomposition Products:WILL EMIT TOXIC FUMES AS IT BURNS.
Conditions to Avoid Polymerization:DOES NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE IAW FED,STATE & LOCAL REGS .DO NOT
CONTAMINATE H2O,WETLANDS,FOOD/FEED BY STOR/DISP.WASTES MAY BE
DISPOSED OF ON SITE/AT APPRVD WASTE DISP FACILITY.REPORTABLE
QTY:1515 LB (NAPHTHALEN E).NAPHTHALENE:SARA TITLE III SECTION 313
LISTED.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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