| MSDS | : | ALL CARBIDE GRADES & BRAZED TOOLS & SLUDGES | | CAS | : | 7440-43-9
7440-50-8
7440-66-6
12070-12-1
7440-33-7
7440-48-4
12070-06-3
7440-25-7
12070-08-5
13463-67-7
12070-10-9
1314-62-1
7440-02-0
1344-28-1
25583-20-4
7440-22-4 | | NAME | : | cadmium, cadmium pigment (suspected human carcinogen by
copper (dust & mist), bronze powder
zinc (as zinc oxide)
tungsten carbide
tungsten (insoluble), wolfram
cobalt
tantalum carbide *93-3*
tantalum
titanium carbide *93-3*
titanium dioxide, tio2
vanadium carbide *93-3*
vanadium
nickel (soluble) (suspected human carcinogen by ntp, iarc,
aluminum oxide, bauxite, alumina, dialuminum trioxide
titanium nitride *93-3*
silver
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===================== Product Identification =====================
MSDS NAME:ALL CARBIDE GRADES & BRAZED TOOLS & SLUDGES
NIIN:00F030802
MSDS Number: BSLWQ
=== Responsible Party ===
Company:GREENFIELD INDUSTRIES INC
Box:2587
City:AUGUSTA
State:GA
ZIP:30913-6899
Country:US
Info Phone Num:404-863-7708
Emergency Phone Num:404-863-7708
CAGE:GO259
=== Contractor Identification ===
Company:GREENFIELD INDUSTRIES INC
Box:2587
City:AUGUSTA
State:GA
ZIP:30913-6899
Country:US
Phone:404-863-7708
CAGE:GO259
============= Composition/Information on Ingredients =============
Name:CADMIUM, CADMIUM PIGMENT (SUSPECTED HUMAN CARCINOGEN BY
ACGIH, IARC & NTP) INTENDED CHANGE (IC)
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: 16%
Other REC Limits:A2 CARCINOGEN
OSHA PEL:0.05 MG/CUM (CD)
ACGIH TLV:0.01 MG/CUM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:COPPER (DUST & MIST), BRONZE POWDER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 15.5%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ZINC (AS ZINC OXIDE)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 15.5%
ACGIH TLV:10 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TUNGSTEN CARBIDE
CAS:12070-12-1
RTECS #:YO7250000
Fraction by Wt: 41-97%
Other REC Limits:5 MG(W)/M3
ACGIH TLV:5 MG(W)/M3
Name:TUNGSTEN (INSOLUBLE), WOLFRAM
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: 41-97%
ACGIH TLV:5 MG/CUM
Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: 3-30%
Other REC Limits:0.05 PPM
OSHA PEL:0.1 MG/CUM
ACGIH TLV:0.05 MG/CUM
Name:TANTALUM CARBIDE *93-3*
CAS:12070-06-3
Fraction by Wt: 0-52%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Name:TANTALUM
CAS:7440-25-7
RTECS #:WW5505000
Fraction by Wt: 0-52%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Name:TITANIUM CARBIDE *93-3*
CAS:12070-08-5
Fraction by Wt: 0-15%
Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 0-15%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Name:VANADIUM CARBIDE *93-3*
CAS:12070-10-9
Fraction by Wt: 0-0.5%
Name:VANADIUM
CAS:1314-62-1
RTECS #:YW1355000
Fraction by Wt: 0-0.5%
OSHA PEL:0.5 MG/CUM
ACGIH TLV:0.05 MG/CUM (DUST)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC,
ACGIH) INTENDED CHANGE (IC)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 18.5%
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:0.05 MG/CUM IC
Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: 0-0.5%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM
Name:TITANIUM NITRIDE *93-3*
CAS:25583-20-4
Fraction by Wt: 0-0.5%
Name:SILVER
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: 50%
OSHA PEL:0.01 MG/CUM
ACGIH TLV:0.1 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITANT/SENSITIZER; HARD
METAL DISEASE; COBALT: BLOOD/HEART/NON-RESPIRATORY ORGANS PROBLEMS;
CADMIUM: RENAL PERITUBULAR DAMAGE/BEHAVIORAL DISORDERS; NICKEL:
SENSITIZER. SKIN: IRRITANT/SEN SITIZER/DERMATITIS/ECZEMA. EYES:
IRRITANT. INGESTION: GI IRRITANT; DAMAGE TO PANCREAS/THYROID
GLAND/HEART/BONE MARROW.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INHALATION: SHORTNESS OF
BREATH/DYSPNEA/ASTHMA/WHEEZING/COUGHING/CHEST
SORENESS/BRONCHITIS/WEIGHT
LOSS/HEMOPTYSIS/INTERSTITIAL/RADIOLOGICAL CHANGES/CADMIUM:
RESPIRATORY INFLAMATION/SLEEPLESSNESS/LOSS OF APPETITE. SKIN:
RASH/ITCHING. EYES: REDNESS/PAIN/ITCHING/CONJUNCTIVITIS.INGESTION:
DIARRHEA/CONVULSIONS/HYPOTENSION.
Medical Cond Aggravated by Exposure:WILSON'S DISEASE & EXISTING
SKIN/EYE/PHYSIOLOGICAL PROBLEMS
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. KEEP WARM/AT REST. PERFORM
CPR IF NECESSARY. SKIN: REMOVE CONTAMINATED CLOTHING, WASH W/SOAP &
WATER. EYES: FLUSH W/WATER. INGESTION: IF CONSCIOUS, GIVE WATER &
INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:ABC TYPE, WATER, SODIUM CHLORIDE, SODA ASH, DRY
SAND, DRY DOLOMITE
Fire Fighting Procedures:POWDER: COOL CONTAINERS EXPOSED TO FLAME
W/WATER. USE APPROPRIATE RESPIRATOR. LARGE: USE SCBA, UNMANNED HOSE
HOLDER/MONITOR NOZZLES, OR LET FIRE BURN & CONTROL.
Unusual Fire/Explosion Hazard:POWDER/DUST MAY PRESENT A FIRE/EXPLOSION
HAZARD. TUNGSTEN CARBIDE POWDER/DUST GENERATED IN HARD METAL
GRINDING OPERATIONS IS EXPECTED TO IGNITE/EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. CLEAN USING METHODS TO AVOID
DUST GENERATION SUCH AS VACUUM W/APPROPRIATE FILTER, MOP, WET
CLEAN-UP. USE AN APPROPRIATE RESPIRATOR.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID DISPERSION OF POWDER & DUST IN
AIR, DUST ACCUMULATION. AVOID DUST INHALATION & DIRECT CONTACT
W/SKIN & EYES.
Other Precautions:DON'T SHAKE CLOTHING/RAGS/OTHER ITEMS TO REMOVE DUST;
VACUUM OR WASH ITEMS. PERIODIC MEDICAL EXAMINATIONS ARE RECOMMENDED
FOR INDIVIDUALS REGULARLY EXPOSED TO POWDER/DUST/GINDER MIST.
CUTTING TOOLS MA Y SHATTER WHEN BROKEN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR
IF AIRBORNE DUST CONCENTRATIONS EXCEED THE APPROPRIATE PEL/TLV.
Ventilation:LOCAL EXHAUST: ADEQUATE TO LIMIT EXPOSURE LEVELS BELOW
TLV'S
Protective Gloves:REQUIRED
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS/GOGGLES
Other Protective Equipment:BARRIER CREAMS
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING/BEFORE
EATING/SMOKING. REMOVE (AVOID GENERATING DUST)/LAUNDER CLOTHING
BEFORE REUSE.
Supplemental Safety and Health
DURING OPERATION AND USE, PRODUCT DOESN'T PRESENT A HEALTH HAZARD.
GRINDING/CUTTING/BURNING/BRAISING/WELDING OF PRODUCT MAY RELEASE
DUSTS/FUMES WHICH MAY PRESENT A HEALTH HAZARD. ITEM NAMES: CEMENTED
CARBIDE PRODUCT W/NICKEL BINDER(GRADE N1-14, UC-6)/CEMENTED
CARBIDE PRODUCT BRAZED TOOLS USING BRAZING FILLER METAL.
================== Physical/Chemical Properties ==================
Spec Gravity:11-15.5
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK GRAY METAL/POWDER W/NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS & ACIDS
Stability Condition to Avoid:IGNITION SOURCES
==================== Disposal Considerations ====================
Waste Disposal Methods:TUNGSTEN CARBIDE PRODUCT MAY BE SOLD AS SCRAP
FOR RECLAMATION. IF RECLAMATION ISN'T FEASIBLE, IT'S THE
RESPONSIBILITY OF CONSUMER TO DISPOSE PRODUCT IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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