LD50 LC50 Mixture:LC50:>10 TO<100MG/L),SEE HEALTH HAZARDS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:LC50 8HR (MIST):18MG/M3 FOR 1-2 MNTH
GPIG/50MG/M3 FOR 18 MO. OLD G/PIG. (ALL LC50 DATA NOTED IS FOR MIST
INHALATION).
Explanation of Carcinogenicity:N/A
Effects of Overexposure:ACUTE OVEREXPOSURE:TISSUE DESTRUCTION UPON
EXPOSURE & DEHYDRATION. MAY CAUSE THIRD DEGREE BURNS. CHRONIC
OVEXPSR:INHALATION OF MIST CAN CAUSE BRONCHITIS HYPEREMIA;
EPITHELIAL DEGENERATION OF THE LARYN X; TRACHEA; & BRONCHI W/
LARYNGEAL OR BRONCHIAL SPASMS.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/LGE AMTS OF WTR FOR AT LEAST 15 MIN.HOLD
EYELD APART DURING IRRIGATION.CALL PHYS.CONTIN WASHG EYE DUR
TRANSIT IF NEED.SKIN:WASH W/LGE AMT OF WTR & RMV CLTHNG & SHOES UND
SHWER-SEEK M ED ATTN. INHAL:RMV TO FRESH AIR. SUPPORT BRTH(GIVE
O*2/ART RESP). SEEK MED AID. INGESTION:DRNK LGE QTY OF WTR IMMED TO
REDUCE CONCEN.SEEK MED AID IMMED. DO NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:ACID MAY CAUSE IGN BY CONT W/COMBU LIQ & SOL.IN
FIRE WHERE ACID PRSNT;USE DRY CHEM;CO*2/WTR FOG
Fire Fighting Procedures:USE NIOSH/MSHA APPRO SCBA & FULL PROT EQPTDO
NOT ALLOW WTR TO ENT STOR CNTNR AS VIOL RCTN CAN OCCUR.ALSO HYDRO
GAS CAN ACCUM IN CNTNR&CARE MST BE(SUP DATA
Unusual Fire/Explosion Hazard:ACID WILL NOT BRN BUT CAN STRT FIRE
W/ORGAN MATL;NTRATE;CARBID;CHLORAT;&METALLIC POWD.HYD; HGHLY
FLAMM&EXPLO GAS IS GEN BY ACID ACTN ON MOST METAL.HYDR (SUP DAT
Spill Release Procedures:CONTAM AREA SHLD BE THORO FLUSH DWN W/LGE AMTS
OF WTR & SODA ASH/LIME SPREAD OVER AREA TO NEUTRA RESIDUAL ACID.IF
SPILL IS SUFFIC TO CONTAM SEWER SYS; NEUTRALIZE WASHINGS W/SODA
ASH/OTHER ALKALINE MAT ERIAL
Neutralizing Agent:SODA ASH; LIME;/OTHER ALKALINE MATERIAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:HYDR CAN BE GEN INSID DRUMS &
TANKS.THEREFORE OPN LIGHTS;SMK/SPARKS SHLD NOT BE PERM NEAR OPEN
DRUM/TANK.WHN DILUT W/WTR ADD ACID TO WTR-NVR ADD(SUPDA
Other Precautions:CNTNR & CARRIER CONT CORR LIQ MST BE PROP
LABL;PLACAR;SHIP PAPR;& TRANSPOR;IAW FED REGUL CONT IN 49CFR PART
171-177;& OTH APPLI FED;STATE & LOCAL REGUL.
Respiratory Protection:FOR ACID GAS & MST CONCEN LID TIMES TLV;CHEM
CARTRI RESP APPROV BY NIOSH FOR ACID GAS & MST MAY BE USED.USE FULL
FCEPIEC IF EYE IRRI IS NOTED.FOR EMER USE SCBA IN PRESSURE DEMAND
MODE W/FULL FACEPIECE .
Ventilation:LCL EXHAU VENT TO LMT EXPSR IN PROC LIBER ACID MST.VENT IS
NECES TO CLEA STOR TANK PRIO TO ENT.FOL OSHA REGU FOR INK ENT
Protective Gloves:RUBBER GLOVES
Eye Protection:CHEM WORK GOGG & FACESHIELD
Other Protective Equipment:RUBBER SAFETY SHOES;/RUBBER WORN OVER
LEATHER SAFETY SHOES.WEAR RUBBER APRON IF BODY CNTCT IS POSS.EYWASH
& DELUGE SHWR.
Work Hygienic Practices:N/K
Supplemental Safety and Health
PCT VOLT-VOL:N.PH:STRNG ACID.SP FF PROC:TAKN NOT TO IGN.UNUS FR EXP
HAZ:GAS CAN ACCUM IN CNTNR&CARE MST BE TAKN NOT TO IGN IT.HAZ DECO
PROD:FRE.OPEN LGT SHLD NOT BE PERM NEAR THS CNTNR.OTH PROD INCL S
UL DIO&SUL TRIOX.HND/STR PREC:WTR TO A CID. DO NOT ALLW WTRTO ENT
STOR TANK AS VIOLENT REACTION CAN OCCUR.
HCC:C1
Boiling Pt:B.P. Text:560F/293.3C
Melt/Freeze Pt:M.P/F.P Text:-10F/-23.3C
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Spec Gravity:1.8407
pH:SP DAT
Evaporation Rate & Reference:N/APPLICABLE
Solubility in Water:COMPLETELY
Appearance and Odor:CLEAR, COLORLESS LIQUID; NO ODOR
Percent Volatiles by Volume:N/K-FP
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DO NOT POUR WTR INTO ACID.DO NOT STR NEAR
NITRAT;CARBID;CHLORAT;CYANID;/OTH COMBUS ORG SUBST.DO NOT MIX
W/METAL(SUP DAT)
Stability Condition to Avoid:CONTACT W/METAL POWDERS MAY RELEASE
HYDROGEN, A HIGHLY FLAMMABLE GAS. CONTACT WITH COMBUS MATL MAY
CAUSE THM TO IGNITE.
Hazardous Decomposition Products:HYD GAS CAN BE GEN INSD STEEL
DRUM;TANK CARS;TNK TRCK;/MET STOR TNK.EXPL MIX W/AIR UND CERT COND
MAY RESULT.SMK(SUP DAT)
Waste Disposal Methods:STORE IN AREA WHERE SPILLS OR LEAKS CAN BE
CONTAINED & DISPOSE OF PROPERLY.PREFERABLY NEUTRALIZE W/LIME/SODA
ASH.RESULT SULFATE SALTS MAY BE DILUTED; LANDFILLED;OR WASHED TO
SEWAGE PLANTS IF LOCAL ORD INANCES PERMIT.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.