===================== Product Identification =====================
MSDS NAME:ALLOY GRADE
NIIN:00N049085
MSDS Number: BTZCD
=== Responsible Party ===
Company:FALCONBRIDGE LIMITED
Address:COMMERCE COURT WEST
Box:40
City:TORONTO, ONTARIO CANADA
Info Phone Num:705-693-2761
Emergency Phone Num:705-693-2761
CAGE:IO743
=== Contractor Identification ===
Company:FALCONBRIDGE LIMITED
Address:COMMERCE COURT WEST
Box:40
City:TORONTO, ONTARIO CANADA
Phone:705-693-2761
CAGE:IO743
Company:INDUSMIN DIVISION FALCONBRIDGE LTD.
Address:365 BLOOR ST. EAST
Box:City:TORONTO
State:ON
Country:CA
Phone:(705) 877-2210
CAGE:38385
============= Composition/Information on Ingredients =============
Name:ING 4:ANIMALS. FINALLY, ACGIH STATES THAT ONLY DUST & FUMES
FROM ROASTING OF NICKEL SULPHIDE ORES ARE CARCIN (ING 6)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 5:TO HUMANS. IMPORTANT NOTE:ONLY RELIABLE, SCIENTIFIC
STUDIES SHOWING AN EXCESS OF CANCER OF RESP TRACT HAVE (ING 7)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 6:BEEN DEMONSTRATED TO RSLT FROM CERTAIN STEPS IN
PROCESS OF NICKEL PRODUCTION.ON OTHER HAND, SEVERAL STUDIES(ING 8)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 7:OF WORKERS EXPOSED TO VARIOUS FORMS OF NICKEL & ITS
COMPOUNDS HAVE NOT SHOWN ANY INCREASED RISK OF CANCER.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:RESP PROT:OSHA CFR 1910.134 ARE RECOMMENDED.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:VENT:BY USE OF APPROPRIATE VENTILATION.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:EYE PROT:AVOID SOLUTION CONTACT BY USE OF ANSI APPROVED
PROTECTIVE GOGGLES .
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:EXPLAN OF CARCIN:CARCINOGENS, 1991:ANTICPATED TO BE
CARCINOGEN.ANIMAL LUNG, ANIMAL SARCOMAS .
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:NICKEL (SARA III); (99.9% NI METAL)
CAS:7440-02-0
RTECS #:QR5950000
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Name:SUPDAT:I.A.R.C.(JUNE 1989) HAS RECLASSIFIED NICKEL AS
FOLLOWS:METALLIC NICKEL & ITS ALLOYS:GROUP 2B CARCIN. (ING 3)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 2:ALL NICKEL CMPDS:GROUP 1 CARCIN. GROUP 1 CARCIN -
CARCIN TO HUMANS. GR 2B CARCIN - POSSIBLY CARCINOGENIC (ING 4)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 3:TO HUMANS. THIS CLASSIFICATION IS USED WHEN THERE IS
ADEQ EVIDENCE IN HUMANS & LIMITED/NO EVIDENCE IN (ING 5)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)>5000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:UNDER NORMAL HNDLG & USE, EXPOS TO
MASSIVE FORMS OF NICKEL PRESENTS FEW HLTH HAZ. IF, HOWEVER, MASSIVE
FORMS ARE CONVERTED TO PARTICULATES THEN BOTH ACUTE & CHRONIC HLTH
HAZ ARE POSS. ACUTE:EYE:PARTIC ULATES MAY CAUSE SLIGHT EYE IRRIT.
SKIN:BOTH MASSIVE FORMS & PARTICULATES MAY CAUSE EITHER CONT DERM
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL:IARC MONO ON EVAL OF CARCIN RISK
OF CHEMS TO MAN, VOL 49, PG 257, 1990:GRP 2B. NTP 6TH ANNUAL REPORT
ON (ING 12)
Effects of Overexposure:HLTH HAZ:OR SKIN SENSIT IN SENSITIVE
INDIVIDUALS W/RPTD SKIN EXPOS. INGEST:NOT A NORMAL ROUTE OF ENTRY.
INHAL:RARE CASES OF ASTHMA HAVE BEEN REPORTED TO HAVE OCCURRED IN
INDIVIDUALS EXPOSED TO SOME FO RMS OF PARTICULATES CONTAINING
NICKEL, PARTICULARLY NICKEL SULPHATE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:IRRIGATE WITH WATER FOR AT LEAST 15 MINS. SKIN:WASH OFF
CONT AREAS W/WATER/REMOVE CONTAMD CLTHG & SHOWER. CONTAMD CLTHG
SHOULD BE WASHED BEFORE REUSE. AVOID PRLNGD/RPTD CONT W/SKIN.
INGEST:INDUCE VOMIT IF LG AMTS INGESTED. CONSULT PHYS.
INHAL:REMOVE TO FRESH AIR IF ACUTE RESP EFFECT. CONSULT PHYS.
===================== Fire Fighting Measures =====================
Extinguishing Media:MASSIVE FORMS OF NICKEL DO NOT PRESENT A FIRE OR
EXPLOSIVE HAZARD.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
================== Accidental Release Measures ==================
Spill Release Procedures:UNDER NORMAL HNDLG AND USE MATL IS NOT DUSTY
AND DOES NOT PRESENT SPILLAGE & LEAKAGE PROBLEMS. NO PROT REQD,
EXCEPT AVOID PRLNGD/RPTD DIRECT SKIN CONTACT IF SENSITIVE TO
NICKEL. IN SUCH CIRCUMSTANCES, GLOVES ARE RECOMMENDED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEAR MINERAL ACIDS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF SOLID NICKEL FORMS ARE CONVERTED IN MFR
PROCESSES TO PARTICUALTES & VENT IS NOT ADEQ TO MAINTAIN NICKEL
CONCS BELOW RECOMMENDED EXPOS LIMS, THEN RESP PROT SHOULD BE USED.
NIOSH/MSHA APPRVD RESPS W/ H.E.P.A. FILTER ACCORDING TO (ING 9)
Ventilation:IF SOLID FORMS OF NICKEL ARE CONVERTED TO PARTICULATES
MAINTAIN WORKING ENVIRONMENT BELOW RECOMMENDED EXPOS LIMS(ING 10)
Protective Gloves:LEATHER OR RUBBER GLOVES.
Eye Protection:IF NICKEL METAL IS DISSOLVED, (ING 11)
Other Protective Equipment:PROT COVERALLS AND SAFETY FOOTWEAR ARE
RECOMMENDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CNDTNS (STAB):WILL PRODUCE NICKEL CARBONYL-A HIGHLY TOXIC GAS. EFTS OF
OVEREXPOS:FORM. ACUTE INHAL DOSE L.C. 50 IN RATES IS >10 MG/L.
CHRONIC:ACCORDING TO OSHA CFR 1910.1200(D)(4)(1), NICKEL METAL IS
CONSIDERED A POSS CANCER HAZ BECAUSE NTP HAS CONCLUDED IT MAY BE
REASONABLY ANTICIPATED TO BE A HUMAN CARCIN.(ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:4946F,2730C
Melt/Freeze Pt:M.P/F.P Text:2647F,1453C
Spec Gravity:8.9 (H*20=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID, METALLIC - NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:CONT W/MINERAL ACIDS WILL RELEASE
HYDROGEN-A DANGEROUS GAS. UNDER SPECIFIC CNDTNS, EXPOS TO CARBON
MONOXIDE (SUPDAT)
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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