===================== Product Identification =====================
MSDS NAME:ZINIC IZ-268-S IRIDESCENT CHROMATE
NIIN:00F037199
MSDS Number: BVTHN
=== Responsible Party ===
Company:FREDERICK GUMM CHEMICAL CO
Address:538 FOREST ST
City:KEARNEY
State:NJ
ZIP:07032-5000
Country:US
Info Phone Num:201-991-4174
Emergency Phone Num:201-991-4174
Preparer's Name:KEITH FREY
CAGE:0A7F7
=== Contractor Identification ===
Company:FREDERICK GUMM CHEMICAL CO
Address:538 FOREST ST
Box:City:KEARNEY
State:NJ
ZIP:07032-5000
Country:US
Phone:201-991-4174
CAGE:0A7F7
============= Composition/Information on Ingredients =============
Name:CHROMIC ACID (SOLID OR SOLUTION), CRO3, CHROMIUM (VI)
OXIDE,CR-O3 (GROUP 1 HUMAN CARCINOGEN BY IARC, ACGIH & NTP)*94-3*
CAS:1333-82-0
RTECS #:GB6650000
Fraction by Wt: 5.2%
OSHA PEL:0.1 MG/CUM (CRO3)
ACGIH TLV:0.05 MG/CUM (CR)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF NASAL
SEPTUM/RESPIRATORY TRACT, ULCERATION/PERFORATION OF NASAL SEPTUM,
ALLERGIC ASTHMA. SKIN: BURNS, DEEP/PENETRATING ULCERS. MAY BE
ABSORBED THROUGH BROKEN SKIN. CONTACT W/ HEXAVALENT CHROMIUM
COMPOUNDS MAY CAUSEALLERGIC DERMATITIS. (SEE SUPP)
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:IRRITATION, ULCERATION, BURNS, TISSUE DAMAGE,
CONJUNCTIVITIS.
Medical Cond Aggravated by Exposure:CUTS, BRUISES, DERMATITIS
======================= First Aid Measures =======================
Eyes: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH
W/PLENTY OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR/OXYGEN IF NEEDED. INGESTION: NEVER GIVE ANYTHING BY MOUTH
TO AN UN CONSCIOUS PERSON. HAVE PERSON DRINK SEVERAL GLASSES OF
WATER & THEN INDUCE VOMITING. KEEP AIRWAY CLEAR. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SOILED MATERIAL MAY BE SHOVELED UP & STORED IN
CLOSED CONTAINERS FOR POSSIBLE NORMAL USE/PROPER DISPOSAL. TREAT
AREA W/REDUCING AGENT TO CONVERT HEXAVALENT CHROMIUM TO TRIVALENT
FORM & NETURALIZE. SOA K UP W/AN INERT ABSORBENT. (SEE SUPP)
Neutralizing Agent:CAUSTIC SODA, SODA ASH, LIME
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
A COOL DRY AREA AWAY FROM SOURCES OF HEAT. AVOID CONTACT W/ORGANIC
& COMBUSTIBLE MATERIALS.
Other Precautions:DON'T GET IN EYES/ON SKIN/CLOTHING. KEEP CONTAINER
TIGHTLY CLOSED WHEN NOT IN USED. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE/VAPORS. ALWAYS OBEY HAZARD WARNINGS & HANDLE EMPTY
CONTAINERS AS IF THEY WER E FULL. DON'T REUSE EMPTY CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WHERE
MIST/SPRAY MAY BE GENERATED ABOVE TLV LIMIT.
Ventilation:ADEQUATE LOCAL EXHAUST WHERE MIST/SPRAY MAY BE GENERATED TO
MAINTAIN LEVEL BELOW TLV LIMIT.
Protective Gloves:RUBBER, NEOPRENE
Eye Protection:CHEMICAL SAFETY GOGGLES, FACE SHIELD
Other Protective Equipment:CHEMICALLY RESISTANT SHOES & APRON, SAFETY
SHOWERS, EYE WASH FACILITY.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DISCARD CLOTHING THAT CAN'T BE DECONTAMINATED. WASH AFTER
HANDLING.
Supplemental Safety and Health
HEALTH HAZARDS CONT'D: EYES: EXTREME BURNS/PERMANENT DAMAGE/MODERATE
IRRITATION/CONJUNCTIVITIS/BLINDNESS. INGESTION: EXTREME TISSUE
DESTRUCTION/KIDNEY FAILURE/DEATH. SPILLS CONT'D: STORE IN CLOSED
CON TAINERS FOR PROPER DISPOSAL. NEVER FLUSH INTO SEWERS/STREAMS.
MAY BE HAZARDOUS TO AQUATIC LIFE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F
Spec Gravity: 1.23
Evaporation Rate & Reference:(WATER =1): <1
Solubility in Water:COMPLETE
Appearance and Odor:DARK RED LIQUID
Percent Volatiles by Volume:70
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, ORGANIC/COMBUSTIBLE MATERIALS
Stability Condition to Avoid:HEAT
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF SOLID MATERIAL IAW/FEDERAL, STATE &
LOCAL REGULATIONS. REDUCE HEXAVALENT CHROMIUM TO TRIVALENT CHROMIUM
W/SODIUM BISULFITE/SODIUM SULFITE, NEUTRALIZE TO PH OF 7.5 W/SODA
ASH/CAUSTIC SODA/LI ME.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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