===================== Product Identification =====================
MSDS NAME:UPC01641C ORTHO MALATHION 50 PLUS INSECT SPRAY
NIIN:00F039962
MSDS Number: BXKSZ
=== Responsible Party ===
Company:SOLARIS GROUP DIV OF AGRICULTURAL GRP OF MONSANTO
Box:5008
City:SAN RAMON
State:CA
ZIP:94583-0808
Country:US
Info Phone Num:800-225-2883/800-454-2333
Emergency Phone Num:800-454-2333/800-225-2883
CAGE:SOLAR
=== Contractor Identification ===
Company:SOLARIS GROUP DIV OF AGRICULTURAL GRP OF
Box:5008
City:SAN RAMON
State:CA
ZIP:94583-0808
Phone:800-225-2883/800-454-2333
CAGE:SOLAR
============= Composition/Information on Ingredients =============
Name:MALATHION, O,O-DIMETHYL DITHIOPHOSPHATE OF DIETHYL
MERCAPTOSUCCINATE
CAS:121-75-5
RTECS #:WM8400000
Fraction by Wt: 50%
OSHA PEL:15 MG/CUM (SKIN)
ACGIH TLV:10 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *95-1*
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <1.7%
Other REC Limits:100 PPM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM, SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:AROMATIC PETROLEUM DERIVATIVE SOLVENT
Fraction by Wt: <32%
Name:INERT INGREDIENTS
Fraction by Wt: 17%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (MALE RAT): 2.314 G/KG
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MODERATE IRRITANT, VISION
IMPAIRMENT. SKIN: IRRITATION. INGESTION: SLIGHTLY TOXIC TO INTERNAL
ORGANS. CAN DIRECTLY ENTER LUNGS & CAUSE SEVERE INJURY/DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, WEAKNESS,
CONSTRICTION OF PUPIL, BLURED/DARK VISION, EXCESSIVE
SALIVATION/NASAL DISCHARGE, PROFUSE SWEATING, ABDOMINAL CRAMPS,
NAUSEA, VOMITING, INCONTINENCE, UNCONSCI OUSNESS, CONVULSIONS.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH W/FRESH WATER FOR 15 MINS. REMOVE
CONTACT LENSES. SKIN: WASH THOROUGHLY W/SOAP & WATER. INGESTION:
GIVE WATER/MILK TO DRINK. DON'T MAKE VOMIT UNLESS DIRECTED TO DO SO
BY MEDICA L PERSONNEL. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE
TO PHYSICIANS: MATERIAL MATERIAL CONTAINS A CHOLINESTERASE
INHIBITOR. (SEE SUPP).
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:106F
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG
Fire Fighting Procedures:AVOID PERSONNEL & EQUIPMENT CONTACT
W/FALLOUT/RUNOFF. MIMIMIZING THE AMOUNT OF WATER USED. USE FULL
PROTECTIVE EQUIPMENT & SCBA. CONTAIN/ISOLATE RUNOFF & DEBRIS
Unusual Fire/Explosion Hazard:LIQUID EVAPORATES & FORMS VAPOR WHICH CAN
CATCH FIRE & BURN W/EXPLOSIVE VIOLENCE. INVISIBLE VAPOR SPREADS
EASILY & CAN BE SET ON FIRE BY SOURCES OF IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. CLEAN UP
IMMEDIATELY COVER W/GENEROUS AMOUNT OF ABSORBENT. USE A STIFF BROOM
TO MIX THOROUGHLY. SWEEP UP/PLACE IN A DISPOSABLE CONTAINER. SCRUB
AREA W/DETERGENT & WATER. PI CK UP W/ADDITIONAL ABSORBANT & PLACE
INCONTAINER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DON'T USE/STORE NEAR IGNITION SOURCES.
USE IN WELL VENTILATED AREA. REPLACE CAP/BUNG. EMPTIED CONTAINER
CONTAINS HAZARDOUS/EXPLOSIVE VAPOR.
Other Precautions:DON'T WELD/HEAT/DRILL CONTAINER. KEEP PESTICIDE IN
ORIGINAL CONTAINER. DON'T APPLY DIRECTLY TO
WATER/WETLANDS/CONTAMINATE WATER BY CLEANING OF EQUIPMENT/DISPOSAL
OF WASTE. DON'T STORE/TRANSPORT NEAR F OOD. AVOID EYE/SKIN/CLOTHING
CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION IS NORMALLY
REQUIRED. IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS
WHICH EXCEED THE RECOMMENDED EXPOSURE STANDARDS, THE USE OF AN
APPROVED RESPIRATOR IS REQ UIRED.
Ventilation:REQUIRED.
Protective Gloves:REQUIRED
Eye Protection:CHEMICAL GOGGLES/FACE SHIELD
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
FIRST AID CONT'D: MEASUREMENT OF BLOOD CHOLINESTERASE ACTIVITY MAY BE
USEFUL IN MONITORING EXPOSURE. IF SIGNS APPEAR, ATROPINE SULFATE IS
ANITDOTAL. 2-PAM MAY BE USED IN CONJUNCTION W/ATROPINE BUT NOT
ALONE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text: 300F
Melt/Freeze Pt:M.P/F.P Text:<-50F
Vapor Pres:<10
Vapor Density:4.5
Spec Gravity:1.07
Evaporation Rate & Reference:(N-BU AC =1): 0.2
Solubility in Water:MISCIBLE
Appearance and Odor:AMBER LIQUID W/GARLIC LIKE ODOR.
Percent Volatiles by Volume:35
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:TEMP >85F, HEAT, SPARKS, HOT SURFACES &
OTHER IGNITION SOURCES.
Hazardous Decomposition Products:CO, CO2, OXIDES OF SULFUR &
PHOSPHORUS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PARTIALLY FILLED CONTAINER MAY BE DISPOSED OF BY
SECURELY WRAPPING ORIGINAL CONTAINER IN SEVERAL LAYERS OF NEWSPAPER
& DISCARD IN TRASH. DON'T REUSE EMPTY CONTAINER. RINSE EMPTY
CONTAINER THOROUGHLY B EFORE DISCARDING IN TRASH IAW/FEDERAL,
STATE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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