===================== Product Identification =====================
MSDS NAME:CP3810005 ANHYDROUS HYDRAZINE
NIIN:00-753-4568
MSDS Number: BXNXQ
=== Responsible Party ===
Company:OLIN CORP
Address:120 LONG RIDGE RD
Box:1355
City:STAMFORD
State:CT
ZIP:06904-1355
Country:US
Info Phone Num:203-356-3449
Emergency Phone Num:203-356-3449
CAGE:8X135
=== Contractor Identification ===
Company:OLIN CORP
Address:51 CORPORATE WOODS 9393 W 110 ST
City:OVERLAND PARK
State:KS
ZIP:66210
Country:US
Phone:800-432-6546
CAGE:8X135
Company:OLIN CORPORATION
Address:501 MERRITT 7
Box:4500
City:NORWALK
State:CT
ZIP:06856-4500
Country:US
Phone:203-750-3000/800-511-MSDS
CAGE:99530
============= Composition/Information on Ingredients =============
Name:HYDRAZINE
INTENDED CHANGE (IC) = 0.01 MG/CUM
CAS:302-01-2
RTECS #:MU7175000
Fraction by Wt: >99.5%
OSHA PEL:0.1 PPM
ACGIH TLV:0.1 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 0-0.5%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 60 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: FATAL, IRRITATING TO
NOSE/THROAT/UPPER RESPIRATORY TRACT & LUNGS, PULMONARY EDEMA,
LUNG/LIVER/KIDNEY/BLOOD/CNS DAMGE, HEMOLYSIS OF BLOOD CELLS. SKIN:
FATAL IF ABSORBED, SEVERE IRRITATION/B URNS/DERMATITIS/ALLERGIC
REACTION. EYES: HARMFUL/IRRITATION/BURNS/PERMANENT CORNEAL DAMAGE.
INGESTION: FATAL, (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, INFLAMMATION, BRONCHITIS, VOMITING,
DIARRHEA, NAUSEA, DIZZINESS, CYANOSIS, CONVULSIONS, REDUCTION OF
PACKED CELL VOLUME, RASH, SWELLING, REDNESS, DISCHARGE, TEMPORARY
BLINDNESS, ABDOMINAL PAIN, BLEEDING, TISSUE ULCERATION.
Medical Cond Aggravated by Exposure:LIVER/KIDNEY/BLOOD/CARDIOVASCULAR
DISEASE & ASTHMA.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR 15
MINS. INGESTION: IMMEDIATELY DRINK LARGE AMOUNTS OF WATER. INDUCE
VOMITING. DON'T GIVE ANYTHING BY MOUTH IF UNCONSCIOUS/CONVULSIVE.
INHALAT ION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. KEEP
WARM & QUIET. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:100F
Lower Limits:4.7
Upper Limits:100
Extinguishing Media:ALCOHOL FOAM, CO2, WATER SPRAY.
Fire Fighting Procedures:USE WATER TO COOL FIRE EXPOSED CONTAINERS.
WEAR A POSITIVE PRESSURE SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:AUTO-IGNITION TEMP: 518F. ABSORPTION OF
ANHYDROUS HYDRAZINE BY RAGS/COTTON WASTE/SIMILIAR ORGANIC MATERIALS
WILL EVENTUALLY RESULT IN SPONTANEOUS COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE & ISOLATE AREA/REMOVE IGNITION
SOURCES/STOP SOURCE. AIR: SUPPRESS VAPORS W/WATER FOG. CONTAIN FOR
TREATMENT/DISPOSAL. WATER: SAFELY DIVERT WATER FLOW AROUND AREA.
LAND: DIKE/TRENCH/CONTAIN. D ILUTE TO 10% W/WATER & NEUTRALIZE.
(SEESUPP)
Neutralizing Agent:5-8% CALCIUM HYPOCHLORITE SOLUTION.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL VENTILATED AREA AWAY
FROM IGNITION SOURCES. DON'T STORE >124F, EXPOSE TO DIRECT LIGHT,
CONTAMINATE. MAINTAIN INERT ATMOSPHERE ALWAYS.
Other Precautions:DON'T TAKE INTERNALLY. AVOID CONTACT
W/SKIN/EYES/CLOTHING. ELECTRICALLY GROUND ALL CONTAINERS & HANDLING
EQUIPMENT. RETEST MATERIAL >5 YEARS OLD BEFORE USE. PACKAGE ONLY IN
TEFLON/HIGH DENSITY POLYETH YLENE/304L/347 STAINLESS STEEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF ANY EXPOSURE OCCURS.
Ventilation:LOCAL EXHAUST TO MAINTAIN LEVELS
Protective Gloves:BUTYL RUBBER
Eye Protection:SAFETY GLASSES & FACE SHIELD
Other Protective Equipment:BUTYL RUBBER BOOTS/APRON/PROTECTIVE SUIT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH AFTER HANDLING. RINSE & DISCARD ALL LEATHER PRODUCTS.
Supplemental Safety and Health
PH (1% SOLUTION IN NEUTRAL, DISTILLED WATER): 10.1-10.7. INCOMPATIBLES:
IRON/COPPER/LEAD MANGANESE/MOLYBDENUM. HEALTH CONT'D:
IRRITATION/BURNS TO GI TRACT/STOMACH/INTESTINE. HYDRAZINE IS
CONSIDERED MU TAGENIC. SPILLS: ABSORB NEUTRALIZED MATERIAL
W/CLAY/SAND/COMMERCIAL ABSORBENT. DECONTAMINATE AREA W/DETERGENT &
WATER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:236F
Melt/Freeze Pt:M.P/F.P Text:35F
Decomp Temp:Decomp Text:>482F
Vapor Pres:14.9
Vapor Density:1.1
Spec Gravity:1.004
pH:(SUPP)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/AMMONIA ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS/HYDROGEN PEROXIDE/NITROGEN TETROXIDE/FLUORINE/HALOGEN
FLUORIDES/FUMING NITRIC ACID/METAL OXIDES (SUPP)
Stability Condition to Avoid:TEMPS >124F, DIRECT LIGHT, HEAT, SPARKS,
OPEN FLAME & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:AMMONIA & HYDROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:AS HAZARDOUS WASTE, MUST BE DISPOSED OF IN A
PERMITTED HAZARDOUS WASTE TREATMENT/STORAGE & DISPOSAL FACILITY BY
INCINERATION IAW/FEDERAL, STATE & LOCAL REGULATIONS. POISON UN2029
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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