===================== Product Identification =====================
MSDS NAME:TOLUENE
NIIN:00-711-2187
MSDS Number: BXQFK
=== Responsible Party ===
Company:PHIBRO ENERGY USA INC
Address:500 DALLAS AVE SUITE 3200
City:HOUSTON
State:TX
ZIP:77002
Country:US
Info Phone Num:713-646-5135
Emergency Phone Num:713-923-6641, CHEMTREC800-424-9300
Preparer's Name:RON LOUVIER
CAGE:0V310
=== Contractor Identification ===
Company:EMULTEC INDUSTRIAL PRODUCTS INC
Address:1150 HAYDEN DR SUITE 100
Box:City:CHARROLLTON
State:TX
ZIP:75006
Country:US
Phone:972-417-1288
CAGE:0WA27
Company:PHIBRO ENERGY USA INC
Address:500 DALLAS AVE SUITE 3200
Box:City:HOUSTON
State:TX
ZIP:77002
Country:US
Phone:713-923-6641, CHEMTREC800-424-9300
CAGE:0V310
============= Composition/Information on Ingredients =============
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 99%+
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:SEVE IRRIT,BLUR
VISION,CONJ.INHAL:NASAL/RESP TRACT IRRIT,CNS EFFECTS,DEATH
RESULTING FRM LONG TERM &/OR HI CONCEN VAP EXPO.ANEMIA,IRREG HEART
RHYTHM.REPE/PROL EXPO BEHAV CHANGES.INGEST:HARMFUL/FAT
AL.NAU,VOMIT,DIARR.SEVE CHEM PNEUITIS/PULM EDEMA/HEMORR FRM
ASPIRATION INTO LUNG,GI DIST.SKIN:IRRIT,DERM,HI PRES INJECT.
Explanation of Carcinogenicity:PER MSDS:PRODUCT LISTED AS
CARCINOGEN/POTENTIAL CARCINOGEN BY:NTP/IARC/OSHA/OTHER:NO.CONTAINS
BENZENE/TOLUENE-CA PROP 65
Effects of
Overexposure:EYE:IRRIT,RED,TEAR,SKIN:IRRIT,DEFAT,CRACK,RED,ITCH,INF
LAMM,DERM,2ND INFECTION.HIG PRESS SKIN INJECT-TISSUE
SWOLLEN,DISCOLORED,EXTREMELY PAINFUL.INHLA:NASAL/RESP
IRRIT,CNS-EXCITATION,EUPH,CONTRACTED EY
EPUPILS,DIZZ,DROWS,FTG,NAU,HEAD,REFLEXESLOSS,TREMORS,CONVULS,SEZ,UN
CONSC,RESP ARREST.INGEST:VOMIT,DIARR,RESTLESSNESS.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN,HEART,CENTRAL
NERVOUS SYTEM & RESP DISORDERS AMY BE AGGRAVATED BY EXPOSURE TO
THIS PRODUCT. TARGET ORGANS:RESPIRATORY SYSTEM, SKIN.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH IMMED W/LG AMTS OF WATER FOR @LEAST 15MINS OEPENING
EYELIDS.PAIN/REDNESS CONTINUES GET MED ADVICE.SKIN:WASH WELL
W/SOAP/WATER.REMOVE CONTAMIN CLOTH IMMED.IRRIT PERSIST/SYMPT
DEVELOP GET MED ATTN.MIGH PRESSURE SKIN INJECTIONS AR SERIOUS MED
EMERGENCIES.GET IMMED MED ATTN.INHAL:REMOVE TO FRESH AIR.DIFFI
BREATH CLEAR AIRWAY/ADMIN OXY.NOT BREATH GIVE ART RESP/CPR.KEEP
WAR/QUIET.GET MED(SUPP)
===================== Fire Fighting Measures =====================
Flash Point:40.0F,4.4C
Autoignition Temp:Autoignition Temp Text:896F
Lower Limits:1.2
Upper Limits:7.1
Extinguishing Media:FLAMM LIQ. USE DRY CHEM,FOAM,CO2 TO EXTINGUISH
FIRE.CONSULT FOAM MFG FOR APPROP MEDAI,APPLICATION RATE,WATER/FOAM
RATIO.
Fire Fighting Procedures:COOL FIRE-EXPO CNTNR/STRUCTURE/PROT PEOPLE
W/H2O.IF LEAK/SPILL IGN VENTI AREA,USE H2OSPRAY TO DISPERSE
GAS/VAP/PROT PEOPLE.FLUSH SPILL FRM IGN W/H2O.(SUPPLEME)
Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPO TO HEAT/FLAME.VAP
FORM FLAM/EXPLO MIX W/AIR @RT.VAP/GAS SPREAD TO DISTANT IGN
SOURCE-FLASHBACK;ACCUMU IN LOW AREAS;CONCEN IN CONFINED (SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:START OIL/HAZ SUBS CONTING PLAN.STAY
UPWIND/AWAY FRM SPILL.WEAR APPROP PROT EQPMT AS NEEDED.KEEP IGN
SOURCE/HOT SURFACE AWAY.CONTAIN SPILL.RECOVER AS MUCH AS
POSSIBLE.STOP LEAK W/O RISK.DISPERSE VAP W /WATERSPRAY.PREVENT
SPILL INTO SEWERS/ETC.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLDS CNTNR IN COOL
DRY ISOLATED WELL VENTI AREA AWAY FRM HEAT/IGN SOURCE/INCOMPAT
MATL.USE NON-SPARK TOOLS/EXPLO PROOF EQMPT.GROUND.
Other Precautions:USE ADEQUATE GROUND/BONDING TO PREVENT STATIC
BUILDUP.TRANSFER TO/FRM COMMONLY BONDED/GROUNDED CNTNRS.CHECK
CONFINE/CLSD AREAS W/EXPLOSIMETERS/OXY METER BEF ENTERING.DO NOT
TRANSFER PROD TO ANOTHER CN TNR UNLESS UNLESS PROPERLY LABEL,ETC.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH EQPMT IF WORKPLACE EXPO LIMITS FOR
PROD/COMPO IS EXCEEDED.PROPER RESP SELECTION SHOULD BE DETERMINED
BY ADEQUA TRAINED PERSONNEL BASED ON CONTAMIN,DEGREE OF POT
EXPO/PUBLISHED RESP PROT FAC TORS.EQPMT AVAILABLE FOR
NONROUTINE/EMER
Ventilation:IN CONFINED SPACE MECH VENTI MAY BE NECESSARY TO REDUCE VAP
CONCEN TO LEVELS BELOW ALLOWABLE EXPO LIMITS.
Protective Gloves:NEOPRENE,NITRILE-BUTADIENE RUB,ETC.
Eye Protection:SAFETY GLASSES OR CHEMICAL SPLASH GOGG.
Other Protective Equipment:IMPERV BOOTS/CLOTH.SOURCE OF CLEAN WATER FOR
EYE/SKIN FLUSHING.
Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE.DISCARD CONTAMIN
LEATHER GOODS.USE GOOD PERS HYGIENE PRAC.WASH HANDS AFT USE/BEF
EAT/DRINK
Supplemental Safety and Health
FIRE:DON'T FLUSH DOWN SEWERS.WEAR PROPER PROT EQPMT(SCBA,FULLFACE
MASK)IN CONF/ENCLS AREA. EXPLO/FIRE HAZ:AREAS.FLOWING PROD IGN BY
SELF GENERATED STATIC ELECT.RUNOFF TO SEWER CAUSE FIRE/EXPLO
HAZ.CNT NR EXPLO IN HEAT;IRRIT/TOXIC SUBST EMITTED.
1STAID:INGEST:DO NOT INDUCE VOMIT.GIVE VEG OIL/CHARCOAL SLURRY.GET
MED ATTN.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:230F,110C
Vapor Pres:1.05 @100F
Vapor Density:3.1
Spec Gravity:0.87 @80F
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:COLORLESS LIQUID WITH AROMATIC HYDROCARBON ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING
AGENTSIPEROXIDE,DICHROMATE,PERMANGANATE,CHLORINE,ETC),STRONG
ACIDS,CAUSTICS & HALOGENS.
Stability Condition to Avoid:AVOID HEAT,SPRAKS,OPN FLAME,STATIC ELECT
OR ANY OTHER POTENTIAL IGN SOURCES.PREVENT VAP ACCUMULATION.DO NOT
SWITCH LOAD.
Hazardous Decomposition Products:COMBUSTIN MAY PRODUCE CARBON MONOXIDE,
CARBON DIOXIDE, REACTIVE HYDROCARBONS (ALDEHYDES, AROMATICS, ETC).
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IAW LOC/COUNTY/STATE/FED REGS.CONTACT
STATE/FED REGS TO DETERMINE WHETHER MATL CLASSIFIED AS HAZ/INDUST
WASTE;HANDLE ACCORDINGLY.EMPTY CNTNR MAY HAVE
TOX/FLAM/COMBUST/EXPLO RESIDUE/VAP.DO NOT CUT/GRIND/REUSE/ETC.SEC
313 TOX CHEM.RQ=1000LBS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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