===================== Product Identification =====================
MSDS NAME:NITRIC ACID
NIIN:00-222-9655
MSDS Number: BXQDC
=== Responsible Party ===
Company:OCCUPATIONAL HEALTH SERVICES, INC
Address:11 WEST 42ND, 12TH FLOOR
City:NEW YORK
State:NY
ZIP:10036
Country:US
Info Phone Num:212-789-3535/800-445-MSDS
Emergency Phone Num:212-789-3535/615-366-2000
CAGE:DO501
=== Contractor Identification ===
Company:OCCUPATIONAL HEA & SAFETY,FORD MOTOR CO
Address:900 PARKLANE TOWERS WEST
City:DEARBORNE
State:MI
ZIP:48126
Phone:800-959-3673
CAGE:DO501
Company:OCCUPATIONAL HEALTH SERVICES INC
Address:11 W 42ND ST 12 THE FLOOR
City:NEW YORK
State:NY
ZIP:10036
Country:US
Phone:212-789-3535
CAGE:0G9K0
============= Composition/Information on Ingredients =============
Name:NITRIC ACID (SARA 302/313) (CERCLA)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 70%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 PPM
ACGIH TLV:2 PPM/4 STEL; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CORR INHAL/SKIN/EYE/INGEST.HIGHLY
TOXIC BY INHAL.INHAL:100PPM IMMED DANGEROUS TO LIFE/HEALTH.SEV RESP
IRRIT.PULM EDEMA,CYANOSIS,RAPID PULSE,TEETH EROSION.SKIN:SEV
PAIN,BUNRS,EYLLOW STAINS,DERM.EYE:PAI
N,LACRIMATIN,PHOTOPHOBIA,BUNRS,BLINDNESS,CONJ.INGEST:CORR OF MUC
MEMB OF MOUTH/THROAT/EXOPHAGUS,PAIN,UNABLE TO (SUPPLEM)
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN:NONE.
Effects of Overexposure:INHAL:COUGH,CHOKE,YELLOWISH BURNS OF MUC
MEMB.DIZZ,HEAD,NAU,WEAK,TIGHTNESS IN CHEST,DYSPNEA,FROTHY
SPUTUM.SKIN:DERM,BURNS,YELLOW STAINS.EYE:PAIN,EYE DESTROYED,YELLOW
EYE COLOR,CONJ,CORNEA VASCULARIZED /OPAQUE.INGEST:SHOCK,WEAK,RAPID
PULSE,SHALLOW RESP,CLAMMY SKIN,CIRCULARTORY
COLLAPSE,ESOPHAGEAL/GASTRIC/PYLORIC STRICTUR
Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED PULMONARY
FUNCTION, PRE-EXISTING EYE & SKIN DISORDERS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED.STOP BREATH GIVE ART
RESP.GIVE OXY IF AVAILABLE BY QUAL PERSON.SKIN:REMOE CONTAMIN
CLOTH/SHOE IMMED.WASH W/SOAP/MILD DETERGENT/LOTS OF WATER
15-20MINS.CHEM BURN COVER W /STERILE DRY DRESS.BANDAGE
SECURELY.EYE:WASH IMMED W/LOTS OF WATER OPENING EYELIDS
15-20MINS.CONT W/NORMAL SALINE TIL PH NORMAL(3-60MINS).COVER
W/STERILE BANDAGES.INGEST:NO GASTRIC LAVAGE/EMESIS.(SUP)
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER,DRY CHEMICAL OR SODA ASH. LG FIRES:FLOOS AREA
W/WATER FROM A DISTANCE.
Fire Fighting Procedures:MOVE CNTNR FRM FIRE W/O RISK.APPLY COOL WATER
TO CNTNR SIDES EXPO TO FLAME TIL WELL AFAT FIRE IS OUT.STAY AWAY
FRM TKS ENDS.MASSIVE FIRE IN CARGO AREA USE(SUPP
Unusual Fire/Explosion Hazard:MAY IGN OTHER COMBUST
MATLS(WOOD,PAPER,OIL,ETC).RXS VIOLENTLY W/H2O/FUEL.FLAMM,POISONOUS
GAS MAY ACCUMU IN TKS/HOPPER CARS.RUNOFF TO SEWER CREATE FIRE/EXPLO
HAZ
================== Accidental Release Measures ==================
Spill Release Procedures:DIG HOLDING AREA(PIT/POND)TO CONTAIN.DIKE
SURFACE FLOW(SOIL BARRIER/SANDBAGS)ABSORB LIQ MASS W/FLY ASH/CEMENT
POWDER.NEUTRALIZE.APPLY WATERSPRAY TO RED VAP.DIKE RUNOFF.DO NOT
TOUCH SPILL.STOP LEAK W/O RISK.ISOLATE/DENY ENTRY.VENTI CLSD SPACE
BEF ENTR
Neutralizing Agent:SLAKED IME, SODIUM BICARBONATE OR CRUSHED LIMESTONE.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FED/STATE/LOC REGS WHEN
STORING MATL.PROT AGAINST PHYS DMG.SEPARTE FRM INCOMPA
MATLS.PROVIDE GOOD VENTI.AVOID DIRECT SUNLIGHT.SEE NFPA 43A
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPEC RESP SELECTED MUST BE BASED ON CONTAMIN
LEVELS IN WORKPLACE,MUST NOT EXCEED WORKING LIMITS OF RESP,JOINTLY
APPROVED BY NIOSH/MSHA.ONLY NON-OXIDIZABLE SORBENTS ALOWED(NOT
CHARCOAL).
Ventilation:PROCESS ENCLOSURE RECOMMENDED TO MEET PUBLISHED EXPO
LIMITS.
Protective Gloves:APPROPRIATE PROT GLOVES.(PVC,NITRILE)
Eye Protection:SPLASH-PROOF/DUST-RESIST SAF GOGG,FACSLD
Other Protective Equipment:APPROP PROT IMPERV CLOTH/EQPMT TO PREVENT
SKIN CONTACT.EYEWASH FOUNTIAN,QUICK DRENCH SHOWER W/IN IMMED
WORKAREA.
Work Hygienic Practices:WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
FIREFIGHT:UNMANNED HOSE HOLDER/MONITOR NOZZ.IF IMPOSSIBLE W/D LET FIRE
BURN.USE FLOOD AMTS OF H2O AS FOG.AVOID BREATH VAP.KEEP
UPWIND.CONSIDER EVACU DOWNWIND IF LEAKING. HEAL
HAZ:SWALLOW/TALK,THIRST,D IARR,VOMITUS W/BLOOD/MUCOSA,RENAL
FAILURE,DEATH,CONV. 1STAID:DILUTE W/100X.IN ALL CASES GET MED ATTN
IMMED.NO ANTIDOTE.
================== Physical/Chemical Properties ==================
HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=82.8C, 181.F
Melt/Freeze Pt:=-42.2C, -44.F
Vapor Pres:47.9 @20C
Vapor Density:3.2
Spec Gravity:1.5027 @25C
pH:ACID
Solubility in Water:VERY SOLUBLE
Appearance and Odor:COLORLESS TO PALE YELLOW LIQUID WITH A SUFFOCATING
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMBUST MATLS,METALLIC POWDERS,HYDROGEN SULFIDE,CARBIDES,ALCOHOLS,CORR
TO METALS,TURPENTINE,ORG ACIDS,READILY OXID MATLS
Stability Condition to Avoid:RXS W/WATER EXOTHERMICALLY.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:SARA TPQ&RQ/CERCLA RQ:1000LBS.OSHA
TQ:500LBS.SUBJ TO REPORTING.OBSERVE ALL FED/STATE/LOC REGS WHEN
DISPOSING THIS SUBSTANCE.DISPOSAL MUST BE IAW STD APPLICABLE TO
GENERATORS OF HAZ WASTE.EPA HAZ WASTE :D002.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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