o-phenylenediamine dihydrochloride supdat:keep upwind. efts of overexp:hemorrhage of lungs, necrosis & nephritis ing 3:cyanosis. some aromatic amines are strong sensits ing 4:irrit to sev burns. when applied to guinea pigs it ing 5:exposed persons. eye:may cause irrit to sev burns. ing 6:irrits & may be absorbed through digest tract causing ing 7:or prlngd cont may cause sensit derm. ing 8:by rtecs, admin to mice rsltd in first aid proc:until no evidence of chem remains (@ lst 15 ing 10:keep head lower/hips to help pvnt aspir. treat ing 11:antidote. treat symptomatically and supportively. resp prot:specific operation, must not exceed working lims ing 13:for occup sfty & hlth & mine sfty & hlth admin ing 14:w/high-efficiency particulate filter. any powered ing 15:air-purifying resp w/high-efficiency particulate ing 16:press-demand/other positive press/continuous-flow ing 17:to life/hlth cndtns:any scba that has full facepiece ing 18:mode. any supplied-air resp that has full facepiece ing 19:in combination w/auxiliary scba operated in eye prot:and full length face shield . other prot equip:fountain & deluge shower w/in immed work ing 22:(impervious) clthg & equip to pvnt rptd/prlngd skin
MSDS NAME:O-PHENYLENEDIAMINE DIHYDROCHLORIDE
NIIN:00N060147
MSDS Number: BXSRG
=== Responsible Party ===
Company:OCCUPATIONAL HEALTH SERVICES INC
Address:11 WEST 42ND ST 12TH FLOOR
City:NEW YORK
State:NY
ZIP:10036
Country:US
Info Phone Num:800-445-6737
Emergency Phone Num:615-366-2000
CAGE:DO501
=== Contractor Identification ===
Company:OCCUPATIONAL HEA & SAFETY,FORD MOTOR CO
Address:900 PARKLANE TOWERS WEST
City:DEARBORNE
State:MI
ZIP:48126
Phone:800-959-3673
CAGE:DO501
Company:OCCUPATIONAL HEALTH SERVICES INC
Address:11 W 42ND ST 12 THE FLOOR
City:NEW YORK
State:NY
ZIP:10036
Country:US
Phone:212-789-3535
CAGE:0G9K0
============= Composition/Information on Ingredients =============
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE BLUISH SKIN
COLOR & KIDNEY DMG. SKIN:MAY CAUSE IRRIT. MAY CAUSE ALLERGIC RXNS.
ADDNL EFTS MAY INCLUDE BURNS. EYES:MAY CAUSE IRRIT. ADDNL EFTS MAY
INCLUDE BURNS. INGEST:NO INFORMA TION AVAIL ON SIGNIFICANT ADVERSE
EFTS.CHRONIC:INHAL:NO INFORMATION AVAILABLE. SKIN:SAME AS ACUTE.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:EYES:SAME AS ACUTE. INGEST:NO
INFORMATION AVAILABLE ON SIGNIFICANT ADVERSE EFFECTS. TOX
INFO:IRRITANT-SKIN, EYE. TARGET EFFECTS-SENSITIZER-DERMAL.
POISONING MAY AFFECT THE LUNGS, LIVER, KIDN EYS AND BLOOD.
INHALATION:ACUTE:AROMATIC AMINES MAY CAUSE EDEMA AND (ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC.
KEEP PERSON WARM AND AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
GET MED ATTN. IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED. WASH
W/SOAP/ MILD DETERGENT & LG AMTS OF WATER UNTILNO EVIDENCE OF CHEM
REMAINS (AT LST 15-20 MIN). GET MED ATTN IMMED. EYES:WASH IMMED
W/LG AMTS OF WATER/NORMAL SALINE, OCCAS LIFTING UPPER & LOWER LIDS,
(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:(1993 EMER RESPONSE GUIDEBOOK, RSPA P 5800.6). DRY
CHEM, CARBON DIOXIDE, WATER SPRAY/REG FOAM. LARGER FIRES:(SUPP
DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. DO NOT
SCATTER SPILLED MATL W/HIGH-PRESS (SUPP DATA)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSURE TO HEAT
OR FLAME DUST-AIR MIXTURE MAY IGNITE OR EXPLODE.
Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED
MATERIAL INTO SEWER. KEEP UNNECESSARY PEOPLE AWAY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FED, STATE & LOC REGS WHEN
STORING SUBSTANCE. STORE & HNDL UNDER ARGON. STORE AT ROOM
TEMPERATURE. STORE IN A COOL, DRY PLACE.
Other Precautions:KEEP CNTNR TIGHTLY CLSD. PROT FROM EXPOS TO
AIR/LIGHT. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. PREVENT EYE
CONTACT. PREVENT REPEATED OR PROLONGED SKIN CONTACT.
Respiratory Protection:FOLLOWING RESPS ARE REC BASED ON INFO FOUND IN
PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER
FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORK PLACE, MUST BE BASED ON (ING 13)
Ventilation:PROVIDE LOC EXHST VENT. VENT EQUIP SHOULD BE EXPLO-PROOF IF
EXPLO CONCS OF DUST, VAP/FUME ARE PRESENT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 21)
Other Protective Equipment:WHERE THERE IS ANY POSS THAT AN EMPLOYEE'S
EYES MAY BE EXPOSED TO SUBSTANCE, EMPLOYER SHOULD PROVIDE AN EYE
WASH(ING 23)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MP:>495F,>257C(DECOMPOSES). APPEAR & ODOR:SOLID/NEEDLES W/AN IRRIT
ODOR. EXTING MEDIA:WATER SPRAY, FOG/REG FOAM. FIRE FIGHT PROC:WATER
STREAMS. DIKE FIRE-CTL WATER FOR LATER DISP (1993 EMER RESPONSE G
UIDEBOOK, RSPA P 5800.6, GUIDE PG 31). USE AGENTS SUITABLE FOR TYPE
OF SURROUNDING FIRE. AVOID BRTHG HAZ VAPS, (ING 2)
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Vapor Pres:0 @ 20C
Spec Gravity:1.0
Evaporation Rate & Reference:0 (BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS, CLEAR, WHITE TO TAN TO SLIGHTLY
REDDISH/VIOLET CRYSTALLINE (SUP DAT)
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
O-PHENYLENEDIAMINE DIHYDROCHLORIDE:OXIDZERS (STRONG):FIRE AND EXPLOSION
HAZARD.
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY.
AVOID CONTACT WITH STRONG OXIDIZERS, EXCESSIVE HEAT, SPARKS OR OPEN
FLAMES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC AND CORROSIVE FUMES OF HYDROGEN CHLORIDE & OXIDES OF
CARBON & NITROGEN.
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.