copper (sara 313) (cercla) spec grav:8.9 mp:1083c, 3601f nickel; (ni) (sara 313) (cercla) spec grav:8.9, mp:1453c tin; (sn) spec grav:7.3 mp:321c, 448f, vp:2260c, 4100f supdat:increased incidence of malignant lung tumors in ing 4:intratracheal instillations of ing 2 in hamsters ing 5:mesotheliomas & rhabdomyosarcomas. skin:rptd cont ing 6:ing 2 has caused tumors at site of injection in ing 7:for humans from nickel-cntning prostheses. ing 8:generally recognized as safe (gras) as direct human med cndtns:eventually lead to tiss necrosis & fribrosis, ing 10:hepatic) disease & neurologic changes. wilson's ing 11:liver (i.e. hepatic) failure. ing 2:skin cont can spill proc:likely to cause conc of airborne contams to ing 13:collected to recover metal values.
LD50 LC50 Mixture:SEE INGREDIENT 2
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ING 1:COPPER METAL DUST & FUME MAY BE
IRRIT TO RESP TRACT. IN USER OPERATIONS WHERE COPPER FUME IS
GENERATED, INHAL OF FUME CAN RSLT IN SYMPS OF METAL FUME FEVER SUCH
AS CHILLS, FEVER & SWEATING. SKIN :FEW INSTANCES OF ALLERGIC RASHES
HAVE BEEN REPORTED IN WORKERS EXPOSED TO METALLIC COPPER.
EYE:COPPER(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL/NICKEL CMPDS:IARC MONOGRAPHS ON
THE EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PH 257, 1990:GROUP
2B. (SUPDAT)
Effects of Overexposure:HLTH HAZS:METAL AS FOREIGN BODY CAN PROVOKE
INFLAM RXN RSLTING IN PUS FORM IN CONJUNCTIVA, CORNEA/SCLERA.
INGEST:GI EFTS. ING 2:INHAL:EPIDEMIOLOGICAL STUDIES OF WORKERS
EXPOSED TO ING 2 POWDER & TO DU ST & FUME GENERATED IN PRODUCTION
OF ING 2 ALLOYS & OF STAINLESS STEEL HAVE NOT INDICATED PRESENCE OF
(SUPP DATA)
Medical Cond Aggravated by Exposure:ING 1:WILSON'S DISEASE CAN OCCUR IN
CERTAIN INDIVIDUALS W/RARE, INHERITED METABOLIC DISORDER CHARACT BY
RETENTION OF EXCESSIVE AMTS OF COPPER IN LIVER, BRAIN, KIDNEYS &
CORNEAS. THESE DEPOSITS(ING 10)
======================= First Aid Measures =======================
First Aid:INGESTION:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FOR RASHES, SEEK
MEDICAL ATTENTION. CLEANSE WOUNDS THOROUGHLY TO REMOVE ANY PARTICL
ES. EYES:FOR COPPER FOREIGN BODIES, IMMEDIATELY FLUSH EYEBALLS WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:METAL FLAKE HEAT TREATED IN REDUCING
ATMOSPHERES MAY BECOME PYROPHORIC.
Spill Release Procedures:COLLECT SPILLS BY USING SWEEPING CMPD/BY
VACUUMING W/VACUUM EXHST PASSING THROUGH HIGH EFFICIENCY
PARTICULATE ARRESTING (HEPA) FILTER IF EXHST IS DISCHARGED INTO
WORKPLACE. WEAR APPROP NIOSH/MSHA APPR VD RESPS IF COLLECTION &
DISP OF SPILLSIS(ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT INHALE POWDER. KEEP CNTNR CLSD
WHEN NOT IN USE. VENT IS NORMALLY REQ WHEN HNDLG/USING PROD TO KEEP
EXPOS TO AIRBORNE CONTAMS BELOW PELS.
Other Precautions:MAINTAIN AIRBORNE NICKEL LEVELS AS LOW AS POSS. AVOID
RPTD SKIN CONT. DO NOT STORE NEAR ACID/REACTIVE SUBSTANCES. ING 1
CAN REACT VIOLENTLY W/SUBSTANCES SUCH AS NITRATES, BROMATES,
CHLORATES, IODATES, CHLORINE, FLUORINE, PEROXIDES, ETC.
Respiratory Protection:IF VENTILATION ALONE CANNOT CONTROL EXPOSURES,
USE NIOSH/MSHA-APPROVED RESPIRATORS SELECTED ACCORDING TO OSHA 29
CFR 1910.134. MAINTAIN AIRBORNE NICKEL LEVELS AS LOW AS POSSIBLE.
Ventilation:VENTILATION IS NORMALLY REQUIRED WHEN HANDLING OR USING
THIS PRODUCT TO KEEP EXPOS TO AIRBORNE CONTAMS BELOW PELS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER WHICH
MEET ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH SKIN THOROUGHLY AFTER HANDLING. LAUNDER
CLOTHING AND GLOVES AS NEEDED.
Supplemental Safety and Health
EXPLAN OF CARCIN:NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN. HUMAN:LUNG, NASAL CAVITIES. EFTS OF OVEREXP:SIGNIFICANT
RESP CANCER HAZ. RPTD INTRATRACHEAL INSTILLATION OF ING 2 PRDCED AN
INC REASED INCIDENCE OF MALIGNANT LUNG TUMORS IN RATS. RPTD
INTRATRACHEAL INSTILLATION OF ING 2 DID NOT PRDCE AN (ING 4)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:METAL FLAKE HEAT TREATED IN REDUCING
ATMOSPHERES MAY BECOME PYROPHORIC.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . SHOULD DISPOSAL BE DEEMED NECESSARY FOLLOW EPA AND
LOCAL REGULATIONS.
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This information is formulated for use by elements of the Department
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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.