===================== Product Identification =====================
MSDS NAME:GLUTARIC DIALDEHYDE 25 WT % SOLUTION IN WATER, G400-4
NIIN:00N072371
MSDS Number: CBYBZ
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:GLUTARALDEHYDE; (GLUTARIC DIALDEHYDE)
CAS:111-30-8
RTECS #:MA2450000
Fraction by Wt: 25%
OSHA PEL:C 0.2 PPM
ACGIH TLV:C 0.2 PPM
Name:FIRST AID PROC:DFCLT, GIVE OXYG. INGEST:WASH OUT MOUTH
W/WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL,RAT):134 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY BE FATAL IF INHALED,
SWALLOWED, OR ABSORBED THRU SKIN. MATL IS EXTREMELY DESTRUCTIVE TO
TISS OF MUC MEMBS & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE
FATAL AS RSLT OF SPASM, INFLAM & EDEMA OF LARYNX & BRONCHI, CHEM
PNEUM & PULMEDEMA. SYMPS OF EXPOS MAY INCLUDE BURNING SENSATION,
COUGHING,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:WHEEZING, LARYNGITIS, SHORTNESS OF
BRTH, HDCH, NAUS & VOMIT. MAY CAUSE ALLERGIC RESP & SKIN RXNS. TO
THE BEST OF MFR'S KNOWLEDGE, CHEM, PHYSICAL & TOX PROPERTIES HAVE
NOT BEEN THORO INVESTIG ATED. TARGET ORGAN DATA:BEHAVIORAL:ALTERED
SLEEP TIME, SOMNOLENCE, EXCITEMENT. PATERNAL EFTS:TESTES,
EPIDIDYMIS,(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:IN CASE OF ACCIDENT/YOU FEEL UNWELL, SEEK MED ADVICE IMMED
(SHOW LBL WHERE POSS). EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR
@ LST 15 MIN. ASSURE ADEQ FLUSHING BY SEPARATING LIDS W/FINGERS.
SKIN:IMM ED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN WHILE
REMOVING CONTAM CLTHG & SHOES. WASH CONTAM CLTHG BEFORE REUSE.
INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS
(ING 2)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH DRY
LIME OR SODA ASH, PICK UP, KEEP IN A CLOSED CONTAINER AND HOLD FOR
WASTE DISP. VENT AREA & WASH SPILL SITE AFTER MATL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
READILY ABSORBED THROUGH SKIN.
Other Precautions:HIGHLY TOXIC. SENSITIZER. KEEP TIGHTLY CLOSED. STORE
UNDER NITROGEN. STORE IN A COOL, DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:WEAR CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP:SPERM DUCT, PROSTATE, SEMINAL VESICLE, COWPER'S,
ACCESSORY GLANDS. EFTS ON EMBRYO OR FETUS:FETOTOX. ONLY SELECTED
REGISTRY OF TOX EFTS OF CHEM SUBSTANCES (RTECS) DATA IS PRESENTED
HERE . SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFO.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:214F,101C
Melt/Freeze Pt:M.P/F.P Text:21.2F,-6.0C
Vapor Pres:16.4 @ 20C
Vapor Density:3.5
Spec Gravity:1.062
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. MAY DISCOLOR ON EXPOSURE TO AIR.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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