===================== Product Identification =====================
MSDS NAME:NIGROSENE 1288 POWDER, 101-002-6
NIIN:00N072389
MSDS Number: CBYCR
=== Responsible Party ===
Company:KEYSTONE PACIFIC DIVISION
Address:13767 MILROY PLACE
City:SANTA FE SPRINGS
State:CA
ZIP:90670
Country:US
Info Phone Num:312-666-2015
Emergency Phone Num:800-255-3924; 602-931-7159
CAGE:GO189
=== Contractor Identification ===
Company:KEYSTONE ANILINE CORP
Address:13767 MILROY PLACE
Box:City:SANTA FE SPRINGS
State:CA
ZIP:90670
Country:US
Phone:213-802-3937; 312-666-2015
CAGE:0E4Y5
Company:KEYSTONE PACIFIC DIVISION
Address:13767 MILROY PLACE
City:SANTA FE SPRINGS
State:CA
ZIP:90670
Country:US
Phone:213-802-3937
CAGE:GO189
============= Composition/Information on Ingredients =============
Name:ACID BLACK 2. LD50:(ORAL,RAT) >5000 MG/KG.
CAS:8005-03-6
Fraction by Wt: >1%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT:WHEN MIXING, POURING/PROCESSING BULK AMTS OF
POWDERS, GROUND ALL CNTNRS & AVOID STATIC CHARGES, SPARKS, (ING 3)
RTECS #:9999999ZZ
Name:ING 2:SMOKING, OPEN FLAMES OR OTHER POSSIBLE CAUSES OF FIRE
OR EXPLOSION.
RTECS #:9999999ZZ
Name:FIRST AID PROC:HAVING DFCLTY BRTHG, GIVE OXYG. IF NOT
BRTHG, GIVE ARTF RESP. GET EMER MED HELP IMMED. CALL 911 IF(ING 5)
RTECS #:9999999ZZ
Name:ING 4:AVAIL IN YOUR AREA/OTHER MED EMER NUMBER. INGEST:GIVE
PERS SEVERAL GLASSES OF WATER & FORCE VOMIT. NEVER (ING 6)
RTECS #:9999999ZZ
Name:ING 5:GIVE ANY FLUIDS/FORCE VOMIT IF PERS IS UNCON/IS
HAVING CONVLS/HAS NO GAG REFLEX. CONT MD IMMED TO GET MED (ING 7)
RTECS #:9999999ZZ
Name:ING 6:HELP, CALL 911, OR OTHER MEDICAL EMERGENCY SERVICES
AVAILABLE IN YOUR AREA.
RTECS #:9999999ZZ
Name:SPILL PROC:DRUM & SEAL. PVNT FROM ENTERING FLOOR
DRAINS/SEWERS. DO NOT RELS TO SEWER W/OUT ALL PROPER ENVIRON (ING
9)
RTECS #:9999999ZZ
Name:ING 8:AUTHS PERMISSION. DO NOT RELEASE DYE/DYE SOLN INTO
ANY WATERWAYS/SEWER SYSTEM W/OUT PROPER GOVT AUTHORIZATION.
RTECS #:9999999ZZ
Name:WASTE DISP METH:WASTE TREATMENT PLANT AFTER PROPER TESTING
& APPROVAL OF WASTE SAMPLES. IF DISP OF IN IT'S (ING 11)
RTECS #:9999999ZZ
Name:ING 10:ORIGINAL UNUSED FORM, THIS MATL SHOULD BE TREATED, &
DISP OF AT APPRVD SITE/FACILITY/IN COMPLIANCE W/ALL (ING 12)
RTECS #:9999999ZZ
Name:ING 11:APPLIC FED, STATE & LOC ENVIRON REGS. YOU MUST CONT
PROPER GOVT AGENCIES FOR ADDNL DIRECTIONS. ALL WASTE (ING 13)
RTECS #:9999999ZZ
Name:ING 12:MATL & WASTE WATER SHOULD BE DISP OF CORRECTLY,
UNDER ALL FED, STATE, CITY & COUNTY LAWS. RCRA: NOT HAZ (ING 14)
RTECS #:9999999ZZ
Name:ING 13:IN IT'S PURCHASED FORM. HOWEVER, UNDER RCRA, IT IS
PROD USER'S RESPONSIBILITY TO DETERMINE AT TIME OF (ING 15)
RTECS #:9999999ZZ
Name:ING 14:DISPOSAL IF ANY MATERIAL CONTAINING PRODUCT OR
DERIVED FROM PRODUCT IS A HAZARDOUS WASTE.
RTECS #:9999999ZZ
Name:OTHER PREC:SPECIFIC OPERATIONS & PROCESSING CNDTNS. TAKE
INTO CONSIDERATION ALL CNDTNS & ALL CHEMS TO BE HNDLD/ (ING 17)
RTECS #:9999999ZZ
Name:ING 16:PROCESSED. HANDLE W/CARE, AVOID PERSONAL CONT. DO
NOT GET INTO EYES/ON SKIN. DO NOT BREATHE DUST OF PROD,(ING 18)
RTECS #:9999999ZZ
Name:ING 17:DO NOT SWALLOW. CNTNR REUSE:AN "EMPTY" CNTNR CAN
CONTAIN PROD RESIDUE & SHOULD NOT BE REUSED. IF NOT (ING 19)
RTECS #:9999999ZZ
Name:ING 18:PROFESSIONALLY CLEANED & RECONDITIONED, CRUSHING OR
OTHER MEANS IS RECOMMENDED TO PREVENT UNAUTHORIZED REUSE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:POSSIBLE EXPOSURES:EYES, SKIN,
BREATHING DUSTS, ACCIDENTAL SWALLOWING. TARGET ORGANS:EYES, SKIN.
EYE/SKIN EFFECTS (ANIMALS):SLIGHT IRRITANT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PERS W/BRTHG & LUNG PROBS CAN BE
AFFECTED BY BRTHG IN ANY TYPE OF DUSTY MATL. PERS W/ASTHMA,
ALLERGIES/OTHER BRTHG-RELATED PROBS SHOULD STAY AWAY FROM, NOT
HANDLE, & NOT BE EXPOS TO ANY DUSTY (SUPDAT)
======================= First Aid Measures =======================
Eyes:IMMED RINSE W/PLENTY OF CLEAN FLOWING WATER FOR AT LST
15-20 MINS, HOLDING EYELIDS OPEN TO RINSE COMPLETELY. CALL MD & GET
MED ATTN IMMED, AS PREC. SKIN:REMOVE AFFECTED CLTHG. WASH AFFECTED
AREA W/PLENTY OF SOAP & WATER. RINSE W/PLENTY OF WATER. WASH ALL
WORK CLOTHES BEFORE WEARING AGAIN. IF ANY REDNESS, SWELL, ITCH/PAIN
STARTS, SEE MD IMMED. INGEST:MOVE PERS TO FRESH AIR. IF PERS IS
(ING 4)
===================== Fire Fighting Measures =====================
Extinguishing Media:CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:IF MIXED W/AIR IN SUFFICIENT AMTS &
PROPORTIONS, ORG DUSTS CAN FORM FLAMM/EXPLO DUST/AIR MIXTS. AS
PREC, KEEP AREAS CLEAN & AVOID DUST BUILD-UP. HAVE (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPRVD RESP, W/ALL PROT CLTHG &
EQUIP AS DIRECTED IN PERSONAL PROT SECTION OF THIS MSDS. CONTAIN &
CLEAN UP SPILL IMMED. SWEEP PWDRS CAREFULLY, USING ABSORB (SWEEPING
CMPD) TO KEEP DOWN DUS T IN AREA. SCOOP MATL & ABSORB INTO DISP
(ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM MOISTURE. STORE IN COOL,
DRY PLACE UNDER LOW RELATIVE HUMIDITY, AWAY FROM EXCESSIVE HEAT.
STORE IN ORIGINAL/SIMILAR WATER-PROOF CNTNRS.
Other Precautions:RESEAL CNTNRS TIGHTLY AFTER EACH USE. TO HELP PROT
YOURSELF FROM EITHER EXPECTED/UNFORSEEN IRRIT/ALLERGIC RXNS,
WORKERS SHOULD, WHEN SELECTING PERSONAL PROT EQUIP & CLTHG, FOLLOW
ALL MFR SPECIFICATION S & RECS THAT APPLY TO YOUR (ING 16)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED DUST RESPIRATOR FOR YOUR
PARTICULAR OPERATION & MATERIALS BEING HANDLED.
Ventilation:LOCAL EXHAUST IS RECOMMENDED.
Protective Gloves:CHEMICALLY RESISTANT RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR COVERALLS & BOOTS TO MINIMIZE SKIN
CONT.
Work Hygienic Practices:CONT LENSES SHOULD NOT BE WORN WHEN WORKING
W/CHEMS. ALWAYS PRACTICE GOOD INDUST HYGIENE. WASH HANDS & FACE W/
(SUPDAT)
Supplemental Safety and Health
MED CNDTNS:PRODS/DUSTY CNDTNS AS PREC MEASURE. HYGIENE PRACT:MILD SOAP
& WATER BEFORE EATING, DRINKING, SMOKING/USING RESTROOM FACILITIES.
RINSE WELL AFTER HNDLG PROD. AFTER EACH SHIFT, COMPLETELY CLE AN
ALL PROT EQUIP, WASH WORK CLTHG & SHOWER. EXPLO HAZ:PLENTY OF GOOD
VENT. AVOID CREATING VERY DUSTY CNDTNS. (ING 2)
================== Physical/Chemical Properties ==================
Vapor Density:HVR/AIR
Spec Gravity:0
pH:7 @ 1%
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:SOLUBLE
Appearance and Odor:BLACK POWDER; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BURNING CAN PRODUCE OXIDES OF CARBON,
NITROGEN AND SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:IT IS REC THAT YOU SELECT ALTERNATIVE BELOW
ACCORDING TO FOLLOWING ORDER OF PREFERENCE, DEPENDING ON ENVIRON
IMPACT: 1)RECYCLE/REWORK MATL IF AT ALL POSS. 2)INCIN MATL AT
APPRVD FACILITY. 3)TREAT AT A CCEPT WASTE TREATMENT
FACILITY/MUNICIPAL (ING 10)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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