===================== Product Identification =====================
MSDS NAME:NICKEL BASED ALLOY STELL ALLOYS 200,400,600,800 SERIES
NIIN:00D003416
MSDS Number: CGLZN
=== Responsible Party ===
Company:MARMON/KEYSTONE CORP SUB OF THE MARMOM GROUP INC
Address:1312 VALVOLINE RD
Box:992
City:EAST BUTLER
State:PA
ZIP:16029
Country:US
Info Phone Num:412-283-3000
Emergency Phone Num:412-283-3000
CAGE:3A044
=== Contractor Identification ===
Company:MARMON/KEYSTONE CORP
Box:City:BUTLER
State:PA
ZIP:16001
Country:US
Phone:412-283-4500
CAGE:3A044
============= Composition/Information on Ingredients =============
Name:ALUMINUM (SARA 313)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 DUST
ACGIH TLV:10 MG/M3 DUST; 9596
Name:CHROMIUM (SARA 313) (CERCLA)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: .1-48%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:0-15LT (SARA 313)
CAS:7440-48-4
RTECS #:GF8750000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.02 MG/M3; A3; 9596
Name:COPPER (SARA 313) (CERCLA)
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: <2-68%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2 MG/M3 FUME; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: <1-84%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5MG(FE)/M3FUME,B2;96
Name:MANGANESE (SARA 313)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: <1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C, 5 MG/M3 (FUME)
ACGIH TLV:0.2 MG/M3; 9596
Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: 0-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM.
ACGIH TLV:10 PPM.
Name:NICKEL (SARA 313) (CERCLA)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 0.1-99%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9596
Name:NIOBIUM (ALSO CALLED COLUMBIUM)
CAS:7440-03-1
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9596
Name:TANTALUM
CAS:7440-25-7
RTECS #:WW5505000
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; DUST; 9596
Name:TITANIUM
CAS:7440-32-6
RTECS #:XR1700000
Fraction by Wt: <3-5%
Other REC Limits:NONE RECOMMENDED
Name:TUNGSTEN,AS W,SOLUBLE COMPOUNDS.
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOE ESTABLISHED
ACGIH TLV:1 MG/M3/3 STEL; 9596
Name:YTTRIUM
CAS:7440-65-5
RTECS #:ZG2980000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPO TO FUME/DUST MAY
PRODUCE EYE/RESP IRRIT.INHAL HI CONC OF FRESHLY FORM OXIDE
FUMES/FE/MN/CU MAY CAUSE METAL FUME FEVER CHARACTERIZED BY METALLIC
TASTE IN MOUTH,DRYNESS,IRRIT OF THROAT,I NFLUENZA-LIKE
SYMPT.CHRONIC INHAL OF HICONC OF FE-OXIDE FUME/DUST MAY LEAD TO
BENIGN PNEUMOCOMIOSIS(SIDEROSIS)(SIGN/SY)
Explanation of Carcinogenicity:PER MSDS:CHROMIUM & NICKEL HAVE BEEN ID
BY IARC/NTP AS POTENTIAL CARC CAUSING AGENTS.
Effects of Overexposure:HEALTH:INHAL HI CONC OF FERRIC OXIDE MAY
POSSIBLY ENHANCE RISK OF LUNG CAN DVLPMENT IN WORKERS EXPO TO PULM
CARC.EXPO TO HI CONC OF DUST/FUME CAN CAUSE SENSITIZATION
DERM,INFLAMM &/OR ULCERATION OF UP PER RESP TRACT & POSSIBLY CANC
OF NASALPASSAGES & LUNGS.
Medical Cond Aggravated by Exposure:INDIVIDUALS W/CHRONIC RESP
DISORDERS(ASTHMA,CHRONIC BRONCHITIS,EMPHYSEMA,ETC)MAY BE ADVERSELY
AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE MATTER EXPO.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR.CONDITION CONTINUES CONSULT
PHYSICIAN.EYE:FLUSH THOROUGHLY W/RUNNING WATER TO REMOVE
PARTICULATE.OBTAIN MED ATTN.SKIN:REMOVE PARTICLES BY WASHING
THOROUGHLY W/SOAP/WATER.SEEK MED ATTN IF CONDITION
PERISTS.INGEST:IF SIGNIFICANT AMTS OF METAL ARE INGESTED CONSULT
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NA.DONT USE H2O ON MOLTEN METAL/FIRES CAUSED BY
FINE METAL PARTICLES.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:STEEL PRODUCTS IN SOLID STATE PRESENT NO
FIRE OR EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:FINE TURNINGS AND SMALL CHIPS SHOULD BE SWEPT
OR VACUUMED.SCRAP METAL CAN BE RECLAIMED FOR REUSE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:IN WELD PRECAUT SHOULD BE TAKEN FOR
AIRBORNE CONTAM WHICH MAY ORIGINATE FROM CPMDS OF WELD ROD.
Other Precautions:%OF ALLOYING MATL VARIES WITH GRADE OF MATL.ARC/SPARK
GENERATED WHEN WEDLING/BURNING COULD BE SOURCE OF IGNITION FOR
COMBUSTION & FLAMM MATLS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROPRIATE DUST/MIST/FUME RESPIRATOR SHOULD BE
USED TO AVOID EXCESSIVE INHAL OF PARTICULATES.IF EXPO LIMITS ARE
REACHED OR EXCEEDED USE NIOSH APPROVED EQUIPMENT.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:PROTECTIVE GLOVES FOR WELD/BURN/HNDLG
Eye Protection:SAF GLASSES-GRIND/CUT,FC SHIELD-WELD/CUT
Other Protective Equipment:AS REQUIRED DEPENDING ON OPERATIONS AND
SAFETY CODES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:2300F
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:7
pH:NA
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:NA
Appearance and Odor:SOLID, GREY-BLACK, ODORLESS
Percent Volatiles by Volume:NA
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
RXS W/STRONG ACIDS TO FORM HYDROGEN GAS.
Stability Condition to Avoid:NA
Hazardous Decomposition Products:METALLIC DUST OR FUMES MAY BE PRODUCED
DURING WELDING/BURNING/GRINDING/POSSIBLY MACHINING.REFER TO ANSI
Z49.1.
==================== Disposal Considerations ====================
Waste Disposal Methods:USED OR UNUSED PRODUCT SHOULD BE DISPO OF IAW
LOCAL, STATE AND FEDERAL REGULATIONS/LAWS.DISPOSER MUST COMPLY
W/LOCAL, STATE AND FEDERAL DISPOSAL OR DISCHARGE LAWS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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