===================== Product Identification =====================
MSDS NAME:180 7007 FLEXICOLOR RA FIXER AND REPLENISHER WORKING SOLUTN
NIIN:00D006041
MSDS Number: CGLZW
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-477-3194 MSDS :800- 242-2424
Emergency Phone Num:716-722-5151
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 70-75%
Other REC Limits:NONE RECOMMENDED
Name:AMMONIUM THIOCYANATE (CERCLA)
CAS:1762-95-4
RTECS #:XK7875000
Fraction by Wt: 10-15%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Name:AMMONIUM SULFITE (CERCLA)
CAS:10196-04-0
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE TO THIOCYANATES HAS BEEN
SHOWN TO CAUSE THYROID PROBLEMS. EXPECTED TO LOW HAZARD IF INHALED;
HOWEVER, TOXIC HYDROGEN CYANIDE GAS RELEASED ON CONTACT
W/INCOMPATIBLE. CONTACT WITH SKIN & EYES M AY CAUSE IRRITATION;
HARMFUL IF ABSORBED THROUGH SKIN. HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:THIOCYANATE EXPOSURE-THYROID ENLARGEMENT,
DECREASE IN METABOLIC RATE, HYPOTHYROIDISM. INHALED (HYDROGEN
CYANIDE EXPOSURE)-DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID
PULSE, UNCONSCIOUSNESS, CONVULSI ONS, DEATH. INGESTED-NONE STATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. EYES-IMMEDIATELY FLUSH WITH WATER FOR
15 MINUTES. GET MEDICAL ATTENTION. SKIN-FLUSH WITH WATER. GET
MEDICAL ATTEN TION. INGESTED-INDUCE VOMITING AS DIRECTED BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2),
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND SELF-CONTAINED
BREATHING APPARATUS. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH ALRGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE INA CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE REDIUAL CO NTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. AVOID
CONTACT WITH SKIN & EYES. KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE MATERIALS.
Other Precautions:DO NOT ADD CLEANING AGENTS TO PROCESSOR TANKS UNLESS
THE TANK & RECIRCULATION LINES HAVE BEEN COMPLETELY DRAINED AND
THOROUGHLY RINSED WITH WATER. ADDITION OF THESE CLEANING AGENTS MAY
LIBERATE POISON OUS GASES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS
FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH
APPROVED AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29
CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (10 ROOM AIR CHANGES PER HOUR)
SHOULD BE USED.VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Protective Gloves:IMPERVIOUS-RUBBER, PVC.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER, WASHING
FACILITIES.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
FOR CONCENTRATE SEE PNI A, THIS NSN. MAKES 5 LITERS.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.113
pH:6.5
Evaporation Rate & Reference:NONE SPECIFIED BY MFR.
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, LIGHT YELLOW, SLIGHT VINEGAR ODOR.
Percent Volatiles by Volume:70-75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS (EG SODIUM HYPOCHLORITE OR BLEACH); STRONG
ACIDS (EG SULFURIC ACID); BASES.
Stability Condition to Avoid:CONTACT W/STRONG OXIDIZING AGENTS/ACIDS/
BASES LIBERATES FLAMM MATL.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
AMMONIA, CHLORAMINE, CYANIDES, CARBONYL SULFIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO LOCAL, STATE AND FEDERAL REGULATIONS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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