=====================  Product Identification  =====================

MSDS NAME:POLYMERIC HEXAMETHYLENE DIISOCYANATE, D-120
NIIN:00N083258
MSDS Number: CGPYQ
=== Responsible Party ===
Company:SPRAYLAT CORP
Address:716 SOUTH COLUMBUS AVE
City:MT VERNON
State:NY
ZIP:10550
Country:US
Info Phone Num:914-699-3030
Emergency Phone Num:800-424-9300(CHEMTREC)
Preparer's Name:LALIT RAYTHATTHA
CAGE:87354
=== Contractor Identification ===
Company:SPRAYLAT CORPORATION
Address:716 SOUTH COLUMBUS AVENUE
Box:City:MT. VERNON
State:NY
ZIP:10550
Country:US
Phone:914-699-3030;310-559-2335
CAGE:87354

=============  Composition/Information on Ingredients  =============

Name:ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (HOMOPOLYMER
    OF HDI).  VP: 7.5 X 10-5 MMHG @ 20C.
CAS:28182-81-2
RTECS #:NQ9170000
Fraction by Wt: 100%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)
    (HDI) (CERCLA)
CAS:822-06-0
RTECS #:MO1740000
Fraction by Wt: <0.7%
OSHA PEL:N/K 
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Name:SUPDAT: TO REMOVE. EYES:LIQ, AEROSOLS & VAPS ARE IRRIT &
    CAN CAUSE PAIN, TEARING, REDDENING & SWELL W/STINGING (ING 4)
RTECS #:9999999ZZ

Name:ING 3: SENSATION &/OR FEELING LIKE FINE DUST IN EYES.
    INGEST:CAN RSLT IN IRRIT & POSS CORR ACTION IN MOUTH, STOM (ING 5)
RTECS #:9999999ZZ

Name:ING 4: TISS & DIGEST TRACT. CHRONIC:AS RSLT OF PREVIOUS
    RPTD OVEREXP/SINGLE LG DOSE, CERTAIN PERS WILL DEVELOP (ING 6)
RTECS #:9999999ZZ

Name:ING 5: ISOCYANATE SENSIT (CHEM ASTHMA) CAUSING THEM TO
    REACT TO LATER EXPOS TO ISOCYANATE AT LEVELS WELL BELOW (ING 7)
RTECS #:9999999ZZ

Name:ING 6: TLV/MGL. SYMPS OF CHEST TIGHTNESS, WHEEZING, COUGH,
    SHORTNESS OF BRTH/ASTHMATIC ATTACK, COULD BE IMMED OR (ING 8)
RTECS #:9999999ZZ

Name:ING 7: DELAYED UP TO SEVERAL HRS AFTER EXPOS. SIMILAR TO
    MANY NON-SPECIFIC ASTHMATIC RESPONSES, RPTS THAT ONCE (ING 9)
RTECS #:9999999ZZ

Name:ING 8: SENSITIZED PERS CAN HAVE SYMPS ON EXPOS TO DUST,
    COLD AIR/IRRITANTS. THIS INCRD LUNG SENSITIVITY CAN LAST(ING 10)
RTECS #:9999999ZZ

Name:ING 9: WKS & IN SEV CASES, YRS. RPTS THAT CHRONIC OVEREXP
    TO ISOCYANATES CAN CAUSE LUNG DMG INCL DECR IN LUNG (ING 11)
RTECS #:9999999ZZ

Name:ING 10: FUNC; MAY BE PERM. SENSIT MAY BE TEMPORARY/PERM.
    SKIN:ISOCYANATE CNTCT CAN CAUSE REDDENING, SWELL, RASH,(ING 12)
RTECS #:9999999ZZ

Name:ING 11: SCALING/BLISTERING. IN THOSE W/SKIN SENSIT, THESE
    SYMPS CAN DEVELOP AS RSLT OF CNTCT W/VERY SM AMTS OF (ING 13)
RTECS #:9999999ZZ

Name:ING 12: LIQ MATL/EVEN AS RSLT OF VAP-ONLY EXPOS. EYES:MAY
    RSLT IN CORNEAL OPACITY (CLOUDING OF EYE SURF). (ING 14)
RTECS #:9999999ZZ

Name:ING 13: TOXICITY DATA: FOR MORE INFO CONTACT NEHC .
RTECS #:9999999ZZ

Name:FIRST AID: INHAL:MOVE TO AREA FREE OF EXPOS RISK. ADMIN
    O*2/ARTF RESP AS NEC. OBTAIN MED ATTN. ASTHMATIC-TYPE (ING 16)
RTECS #:9999999ZZ

Name:ING 15: SYMPS MAY DEVELOP & MAY BE IMMED/DELAYED SEVERAL
    HRS. TREATMENT IS ESSNTLY SYMPTOMATIC. CONSULT MD. (ING 17)
RTECS #:9999999ZZ

Name:ING 16: INGEST:DO NOT INDUCE VOMIT. GIVE 1-2 CUPS
    MILK/WATER TO DRINK. DO NOT GIVE ANYTHING BY MOUTH TO UNCON OR(ING
    18)
RTECS #:9999999ZZ

Name:ING 17: CONVULSING PERSON. CONSULT MD. NOTE TO MD: FOR MORE
    INFO, CONTACT NEHC .
RTECS #:9999999ZZ

Name:SPILL PROC:SOLN OVER SPILL AREA; ALLOW TO REACT FOR @ LST
    10 MIN. COLLECT MATL IN OPEN CNTNRS & ADD FURTHER AMTS(ING 20)
RTECS #:9999999ZZ

Name:ING 19: OF DECONTAM SOLN. REMOVE CNTNRS TO SAFE PLACE,
    COVER LOOSELY & ALLOW TO STAND 24-48 HRS. WASH DOWN AREA (ING 21)
RTECS #:9999999ZZ

Name:ING 20: W/DECONTAM SOLNS. DECONTAM SOLNS: NONIONIC
    SURFACTANT UNION CARBIDE'S TERGITOL TMN-10 (20%) & WATER (ING 22)
RTECS #:9999999ZZ

Name:ING 21: (80%); CONCENTRATED AMMONIA (3-8%), DETERGENT (2%)
    & WATER (90-95%).
RTECS #:9999999ZZ

Name:HNDLG/STOR: MOISTURE CONTAM. DO NOT RESEAL IF CONTAM
    SUSPECTED. AT MAX STOR TEMPS, MATLS MAY SLOWLY POLYM W/OUT (ING 24)
RTECS #:9999999ZZ

Name:ING 23: HAZ. IDEAL STOR TEMP: 50-81F(10-27C). AVOID CNTCT
    W/SKIN & EYES. EMPLOYEE EDUCATION & TRAINING REQD BY OSHA.
RTECS #:9999999ZZ

Name:VENT: FEASIBLE. EXHST AIR MAY NEED TO BE CLEANED BY
    SCRUBBER/FILTERS TO REDUCE CONTAM. FOR MORE INFO CNTCT NEHC .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL, RAT) >10,000 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:HDI VAPS/MIST AT CONCS
    ABOVE TLV/MGL CAN IRRIT (BURNING SENSATION) MUC MEMBS IN RESP TRACT
    (NOSE, THROAT, LUNGS) CAUSING RUNNY NOSE, SORE THROAT, COUGH, CHEST
    DISCOMFORT, SHORTNESS OF BRT H & REDUCED LUNG FUNC (BRTHG
    OBSTRUCTION). PERS W/PREEXISTING, NONSPECIFIC BRONCH
    HYPERREACTIVITY CAN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: RESPOND TO CONCS BELOW TLV/MGL
    W/SIMILAR SYMPS AS WELL AS ASTHMA ATTACK. EXPOS WELL ABOVE TLV/MGL
    MAY LEAD TO BRONCH, BRONCH SPASM & PULM EDEMA; EFTS USUALLY
    REVERSIBLE. CHEM/HYPERSENS PNEUM IT W/FLU-LIKE SYMPS (EG FEVER,
    CHILLS) REPORTED. SKIN: ISOCYANATES REACT W/SKIN PROTEIN & MOISTURE
    & CAN CAUSE (SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
    DISORDERS (BRONCHITIS, EMPHYSEMA, HYPERREACTIVITY), SKIN ALLERGIES,
    ECZEMA.

=======================  First Aid Measures  =======================

Eyes:FLUSH W/CLEAN, LUKEWARM WATER (LOW PRESS) FOR AT LST 15
    MIN WHILE LIFTING LIDS. REFER TO MD/OPHTHALMOLOGIST FOR IMMED
    FOLLOW-UP. SKIN:REMOVE CONTAMD CLTHG IMMED. WASH AFFECTED AREAS
    THOROUGHLY W/ SOAP & WATER. WASH CONTAMD CLTHG THOROUGHLY BEFORE
    REUSE. FOR SEV EXPOS,GET UNDER SFTY SHOWER AFTER REMOVING CLTHG
    THEN GET MED ATTN. FOR LESSER EXPOS,SEEK MED ATTN IF IRRIT
    DEVELOPS/PERSISTS.(ING 15)

=====================  Fire Fighting Measures  =====================

Flash Point Method:SCC
Flash Point:385F,196C
Extinguishing Media:DRY CHEMICAL; CARBON DIOXIDE; FOAM; WATER SPARY FOR
    LARGE FIRES.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING FIRE, HDI VAPS & OTHER IRRIT,
    HIGHLY TOX GASES MAY BE GENERATED BY THERMAL DECOMP/COMBUST (SEE
    REACTIVITY SECTION). CLSD CNTNR MAY EXPLODE WHEN (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE NONESSNTL PERS. REMOVE ALL IGNIT
    SOURCES & VENT AREA. NOTIFY APPROP AUTHS IF NEC. PUT ON PERSONAL
    PROT EQUIP. DIKE/IMPOUND SPILLED MATL & CTL FURTHER SPILL IF
    FEASIBLE. VERMICULITE, FULLER'S  EARTH/OTHER ABSORB MATL. POUR
    DECONTAM (ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STOR
    TEMP(MIN/MAX):-30F(-34C)/122F(50C). SHELF LIFE:6 MOS @ 77F(25C)
    AFTER RECEIPT OF MATL BY CUSTOMER. STORE IN TIGHTLY CLSD CNTNRS TO
    PVNT (ING 23)
Other Precautions:IF CNTNR IS EXPOSED TO HIGH HEAT, IT CAN BE
    PRESSURIZED & POSS RUPTURE EXPLOSIVELY. HDI REACTS SLOWLY W/WATER
    TO FORM CO*2 GAS. THIS GAS CAN CAUSE SEALED CNTNRS TO EXPAND & POSS
    RUPTURE EXPLOSIVELY.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPRVD RESP REC FOR USE IN ISOCYANATE
    CNTNG ENVIRONMENTS (AIR PURIFYING/FRESH-AIR SUPPLIED) MAY BE NEC
    FOR SPRAY APPLICATNS/OTHER SITUATIONS SUCH AS HIGH TEMP USE WHICH
    MAY PRDCE INHAL EXPOS. CN TCT NEHC FOR SPECIFIC RESP INFO .
Ventilation:GOOD INDUS HYGIENE PRACT DICTATES WORKER PROT SHOULD BE
    ACHIEVED THRU ENGINEERING CTLS SUCH AS VENT WHENEVER (ING 25)
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . COVER
    EXPOS SKIN W/APPROP CLTHG. KEEP AREAS PROT BY SKIN CREAM ONLY TO
    MIN.
Work Hygienic Practices:TAKE PRECS SO PERS HNDLG PROD DO NOT ALLOW
    CNTCT W/EYES/SKIN. IN SPRAY OPERATIONS, PROT AGAINST VAP & SPRAY
    MIST EXPOS.
Supplemental Safety and Health
SOL IN H*2O: RESIN IS INSOL-REACTS SLOWLY W/WATER TO LIBERATE CO*2 GAS.
    % VOLAT: NEGLIGIBLE (WT). EXPLO HAZ: EXPOSED TO EXTREME HEAT/BURST
    WHEN CONTAMD W/WATER (CO*2 EVOLVED). EFTS OF OVEREXP: IRRIT W
    /SYMPS OF REDDENING, SWELL, RASH, SCALES/BLISTERS. SOME PERS MAY
    DEVELOP SENSIT FROM CNTCT. CURED MATL IS DFCLT (ING 3)

==================  Physical/Chemical Properties  ==================

Vapor Pres:SEE ING 1
Spec Gravity:1.11-1.13
Solubility in Water:SUPDAT
Appearance and Odor:CLEAR/PALE YELLOW LIQUID; NEGLIGIBLE ODOR.
Percent Volatiles by Volume:SUPDAT

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS. METAL COMPOUNDS AND SURFACE
    ACTIVE MATERIALS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE: CARBON DIOXIDE,
    CARBON MONOXIDE, OXIDES OF NITROGEN, HCN, HDI.
Conditions to Avoid Polymerization:CONTACT W/MOISTURE OR OTHER MATLS
    WHICH REACT W/ISOCYANATES OR TEMPERATURES ABOVE 400F(204C) MAY
    CAUSE POLYMERIZATION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE MUST BE DISPOSED OF I/A/W FED, STATE &
    LOCAL ENVIRONMENTAL CTL REGS. INCIN IS PREFERED METHOD. EMPTY
    CNTNRS MUST BE HANDLED W/CARE DUE TO PROD RESIDUE. DECONTAMINATE
    CNTNRS PRIOR TO DISPOSAL. DO  NOT HEAT/CUT EMPTY CNTNR W/ELEC OR
    GASTORCH.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***