===================== Product Identification =====================
MSDS NAME:HAZE GRAY LATEX, D10167
NIIN:00N073311
MSDS Number: CGTBV
=== Responsible Party ===
Company:PPG INDUSTRIES INC
Address:1 PPG PL
City:PITTSBURGH
State:PA
ZIP:15272-0001
Country:US
Info Phone Num:412-434-3131
Emergency Phone Num:412-434-3131
CAGE:DO542
=== Contractor Identification ===
Company:PPG INDUSTRIES INC
Box:UNKNOW
CAGE:PPGND
Company:PPG INDUSTRIES INC. COATINGS & RESINS GP
Address:4325 ROSEANNA DR PO BOX 9
Box:9
City:ALLISON PARK
State:PA
ZIP:15101
Phone:412-492-5555
CAGE:DO542
============= Composition/Information on Ingredients =============
Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 2-5%
OSHA PEL:0.1 MG/M3 RDUST(MFR)
ACGIH TLV:0.1 MG/M3 RDUST
Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 5-10%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:WATER; (TAP WATER)
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 15-20%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 1-2%
OSHA PEL:50 PPM (MFR)
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:2-2-PROPOXY ETHANOL; (DIETHYLENE GLYCOL MONOPROPYL ETHER)
CAS:6881-94-3
Fraction by Wt: 2-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:WATER; (DEIONIZED WATER)
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30-35%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:PROPIONIC ACID, 2-METHYL-, MONOESTER
W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL; (2,2,4-TRIMETHYL-1,3-PENTANEDIOL
ISOBUTYRATE)
CAS:25265-77-4
RTECS #:UF6000000
Fraction by Wt: 1-2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BENZYL ALCOHOL
CAS:100-51-6
RTECS #:DN3150000
Fraction by Wt: 1-2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:FILM FORMERS, RESINS, & ADDITIVES
Fraction by Wt: 25-30%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:GLYCOL ETHERS
Fraction by Wt: 2-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT:RESPIRABLE SILICA/QUARTZ, SO POTNTL HAZ FOR HUMANS
IS LTD. THIS PROD CONTAINS TITANIUM DIOXIDE. ANIMALS (ING 12)
RTECS #:9999999ZZ
Name:ING 11:INHALING MASSIVE QTYS OF TITANIUM DIOXIDE DUST IN
LONG-TERM STUDY DEVEL LUNG TUMORS. STUDIES W/HUMANS (ING 13)
RTECS #:9999999ZZ
Name:ING 12:INVOLVED IN MFR OF THIS PIGMENT INDICATE NO INCR
RISK OF CANCER FROM EXPOS. POTNTL FOR INHAL OF TITANIUM (ING 14)
RTECS #:9999999ZZ
Name:ING 13:DIOXIDE DUSTS FROM COATINGS IS VERY LTD. SINCE
OVEREXP ARE NOT EXPECTED, THERE IS NO SIGNIFICANT HAZ FOR (ING 15)
RTECS #:9999999ZZ
Name:ING 14:MAN. THIS PROD CONTAINS ETHYLENE GLYCOL WHICH MAY
CAUSE KIDNEY & LIVER DMG & WHICH HAS BEEN SHOWN TO (ING 16)
RTECS #:9999999ZZ
Name:ING 15:CAUSE BIRTH DEFECTS IN LAB ANIMALS. NO EVID OF THESE
EFTS HAS BEEN FOUND IN HUMANS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:HARMFUL/FATAL IF
SWALLOWED. EYE CONT:CAUSES IRRIT. REDNESS, ITCH, BURNING SENSATION
& VISUAL DISTURBS MAY INDICATE EXCESSIVE CONT. SKIN CONT:MAY CAUSE
SLIGHT IRRIT. DRYNESS, ITCH, CRACKIN G, BURNING, REDNESS & SWELL
ARE CNDTNS ASSOC W/EXCESSIVE CONT. INHAL:VAP & SPRAY MIST MAY BE
HARMFUL IF(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, VOL 68, 1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS,
1994:ANTIC TO BE CARCIN.
Effects of Overexposure:HLTH HAZ:INHALED. SANDING & GRINDING DUSTS MAY
BE HARMFUL IF INHALED. VAP GENERATED AT ELEVATED TEMPS IRRITS EYES,
NOSE & THROAT. CHRONIC:AVOID LONG TERM & RPTD CONT. LONG-TERM EXPOS
TO CRYSTALLINE SI LICA/QUARTZ MAY ALSO LEAD TO DISABLING INJURY
KNOWN AS SILICOSIS. THESE EFTS ARE ASSOC W/BRTHG EXCESSIVE AMTS
OF(SUPDAT)
======================= First Aid Measures =======================
First Aid:INGEST:DO NOT INDUCE VOMIT. EYES:FLUSH IMMED W/PLENTY OF
WATER FOR AT LST 15 MINS. SKIN:FLUSH IMMED W/PLENTY OF WATER
FOLLOWED BY WASHING W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR.
APPLY ARTF RESP & O THER SUPPORTIVE MEASURES AS REQD. NOTE:IF
INGEST, ANY TYPE OF OVEREXP/SYMPS OF OVEREXP OCCUR DURING/FOLLOWING
USE OF THIS PROD, CONT POIS CTL CTR, EMERGENCY ROOM/MD IMMED; HAVE
MSDS INFO AVAILABLE.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Extinguishing Media:USE NPFA CLASS B EXTINGS (CARBON DIOXIDE, DRY
CHEM/UNIVERAL AQ FILM FORMING FOAM) DESIGNED TO EXTING NFPA CLASS
(SUPDAT)
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. WATER SPRAY MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & POSS (SUPP DATA)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST
(DUE TO BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:PROVIDE MAXIMUM VENT. ONLY PERSONNEL EQUIPPED
W/PROPER NIOSH APPROVED RESP & SKIN EYE PROT SHOULD BE PERMITTED IN
AREA. REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST,
VERMICULITE/OTHER A BSORB MATL & PLACE INTO CNTNRS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE >120F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA
CLASS IIIB COMBUSTIBLE LIQS. PROTECT FROM FREEZING.
Other Precautions:IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT
SYSTEM, READ MSDS(S) FOR OTHER COMPONENT(S) BEFORE BLENDING AS
RESULTING MIXTURE MAY HAVE HAZARDS OF ALL OF ITS PARTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE VENTILATION IS INADEQUATE, USE A SUITABLE
NIOSH APPROVED RESPIRATOR.
Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO
KEEP CONC OF INGS BELOW LOWEST SUGGESTED EXPOS LIMS, LEL(SUPDAT)
Protective Gloves:NITRILE, NEOPRENE OR LATEX GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR PROT CLOTHING INCL IMPERMEABLE APRON.
Work Hygienic Practices:CLEAN OR DISCARD CONTAMINATED CLOTHING & SHOES.
Supplemental Safety and Health
EXTING MEDIA:IIIB COMBUST LIQ FIRES. FIRE FIGHT PROC:AUTOIGNIT/EXPLO
WHEN EXPOS TO EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREF.
VENT:BELOW STATED LIM & TO REMOVE DECOMP PRODS DURING WELDING/FLAM
E CUTTING. EFTS OF OVEREXP:SILICA DUST.APPLICATION OF THIS PROD IS
NOT EXPECTED TO GENERATE EXCESSIVE AMTS OF (ING 11)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>208F,>98C
Vapor Pres:17
Vapor Density:HVR/AIR
Spec Gravity:1.11
Evaporation Rate & Reference:30 (BUOAC=100)
Solubility in Water:57.1%
Appearance and Odor:VISCOUS LIQUID W/ODOR CHARACTERISTIC OF CHEM FAMILY
& ANY SOLVS LISTED IN INGS.
Percent Volatiles by Volume:66.40
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRODUCE HAZ DECOMP PRODS WHEN
HEATED. WELDING, BRAZING OR FLAME-CUTTING MAY PRDCE FUMES
INCLUDING: CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF I/A/W
FEDERAL, STATE, PROVINCIAL & LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH AN APPROVED WASTE MANAGEMENT F ACILITY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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