===================== Product Identification =====================
MSDS NAME:72375 PROCLIN 300 PRESERVATIVE
NIIN:00F055838
MSDS Number: CGVTS
=== Responsible Party ===
Company:ROHM & HAAS CO
Address:100 INDEPENDENCE MALL WEST
City:PHILADELPHIA
State:PA
ZIP:19106-2399
Country:US
Info Phone Num:215-592-3000
Emergency Phone Num:215-592-3000
CAGE:GO264
=== Contractor Identification ===
Company:ROHM & HAAS CO
Address:100 INDEPENDENCE MALL WEST
City:PHILADELPHIA
State:PA
ZIP:19106-2399
Country:US
Phone:215-592-3000
CAGE:GO264
Company:ROHM AND HAAS CO
Address:100 INDEPENDENCE MALL WEST
Box:City:PHILADELPHIA
State:PA
ZIP:19106-2399
Country:US
Phone:215-592-2521/215-592-3000
CAGE:77902
============= Composition/Information on Ingredients =============
Name:5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE, KATHON *98-1*
CAS:26172-55-4
RTECS #:NX8156850
Fraction by Wt: 2.1-2.9%
Name:2-METHYL-4-ISOTHIAZOLIN-3-1
CAS:2682-20-4
RTECS #:NX8157000
Fraction by Wt: 0.6-1.1%
Name:GLYCOLS
Fraction by Wt: 91-94%
Name:MODIFIED ALKYL CARBOXYLATE
Fraction by Wt: 3-3.6%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 500-2000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION OF
NOSE & THROAT. EYES: SEVERE IRRITANT, POSSIBLE PERMANENT INJURY.
HARMFUL IF ABSORBED THROUGH THE SKIN. MAY CAUSE CORROSION,
IRRITATION EFFECTS CAN BE DELAYED FOR HO URS. INGESTION: HARMFUL.
MATERIAL CAN CAUSE ALLERGIC CONACT DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. GIVE CPR IF BREATHING HAS
STOPPED. INGESTION: GIVE 2 GLASSES OF WATER TO DRINK. NEVER GIVE
ANYTHING BY MOUTH IF UNCONSCIOUS. EYES: IMMMEDIATELY FLUSH W/LARGE
AMOUNT OF W ATER FOR 15 MINS. SKIN: WASH THOROUGHLYW/SOAP & WATER.
OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: MAY NOT
BE ADVISABLE TO INDUCE VOMITING. TREAT FOR CIRCULATORY
SHOCK/CONVULSIONS.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>151F
Extinguishing Media:CO2, DRY CHEMICAL, POLAR SOLVENT (ALCOHOL FOAM),
WATER SPRAY
Fire Fighting Procedures:WEAR SCBA W/PRESSURE DEMAND MSHA/NIOSH
APPROVED & FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL CONTAINERS
EXPOSED TO FIRE. MINIMIZE EXPOSURE. CONTAIN RUN-OFF.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. CONTAIN W/INERT
MATERIAL. TRANSFER LIQUIDS & SOLID DIKING MATERIAL TO SEPARATE
CONTAINERS FOR RECOVERY/DISPOSAL. WEAR MSHA/NIOSH APPROVED POSITIVE
PRESSURE SCBA/A FULL FACE PIECE AIRLINE RESPIRATOR IN POSITIVE
PRESSURE MODE
Neutralizing Agent:DECONTAMINATE SOLUTION: 10% SODIUM BISULFITE IN
WATER. (SEE SUPP)
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE TEMP: 100F. STORE IN A WELL
VENTILATED AREA. LIMIT INDOOR STORAGE TO APPROVED AREAS EQUIPPED
W/AUTOMATIC SPRINKLERS.
Other Precautions:KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DON'T
BREATHE VAPORS. DON'T STORE THIS MATERIAL IN CONTAINERS MADE OF
STEEL. CONTAINERS ARE HAZARDOUS WHEN EMPTY. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW MSDS/LABEL WARNINGS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UP TO 10 TIMES THE EXPOSURE LIMIT: A MSHA/NIOSH
APPROVED HALF-MASK, AIR PURIFYING RESPIRATOR. UP TO 100: A
MSHA/NIOSH APPROVED FULL-FACEPIECE, AIR PURIFYING RESPIRATOR,
FULL-FACEPIECE/AIRLINE RESPIRAT OR IN THE DEMAND MODE. (SEE
SUPP)
Ventilation:EXPLOSION PROOF LOCAL EXHAUST W/A MINIMUM CAPTURE VELOCITY
OF 150 FT/MIN. AT THE POINT OF DUST/MIST EVOLUTION.
Protective Gloves:BUTYL RUBBER, NITRILE
Eye Protection:CHEMICAL SPLASH GOGGLES/FACE SHIELD
Other Protective Equipment:CHEMICAL RESISTANT APRON, IMPERVIOUS
CLOTHING, EYEWASH FACILITY, SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. REMOVE/DISCARD CONTAMINATED SHOES, BELTS & OTHER LEATHER
ARTICLES.
Supplemental Safety and Health
PH: 4.1 10% SOLUTION. SPILL PROC CONT'D: KEEP RELEASES & CLEANING
RUNOFFS OUT OF MUNICIPAL SEWERS & OPEN BODIES OF WATER. RESPIRATORY
PROTEC CONT'D: 100 TIMES EXPOSURE LIMIT: WEAR MSHA/NIOSH APPROVED
SELF CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND
MODE/MSHA/NIOSH APPROVED FULL-FACEPIECE/AIRLINE RESPIRATOR.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:372F
Melt/Freeze Pt:M.P/F.P Text:-40F
Vapor Pres:0.06
Vapor Density:>1
Spec Gravity:1.03
pH:(SUPP)
Evaporation Rate & Reference:(BUTYL ACETATE=1): <1
Solubility in Water:COMPLETE
Appearance and Odor:PALE YELLOW LIQUID
Percent Volatiles by Volume:<95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, REDUCING AGENTS, AMINES, MERCAPTANS
Hazardous Decomposition Products:BY THERMAL DECOMPOSITION: HYDROGEN
CHLORIDE, SULFUR DIOXIDE, OXIDES OF NITROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:RINSE DECONTAMINATED SOLUTION TO A CHEMICAL
SEWER AFTER STANDING FOR 30 MINS. INCINERATE LIQUID & CONTAMINATED
SOLIDS IAW/LOCAL, STATE & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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