=====================  Product Identification  =====================

MSDS NAME:H0904 HYDROGEN PEROXIDE ACS REAGENT
NIIN:00F055767
MSDS Number: CGVRX
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076

=============  Composition/Information on Ingredients  =============

Name:HYDROGEN PEROXIDE
CAS:7722-84-1
RTECS #:MX0900000
Fraction by Wt: 30%
Other REC Limits:1 PPM
OSHA PEL:1.4 MG/CUM
ACGIH TLV:1.4 MG/CUM

=====================  Hazards Identification  =====================

Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED
    THROUGH SKIN. EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS
    MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN. INHALATION: MAY
    BE FATAL AS A RESULT OF EDEMA OF THE  LARYNX & BRONCHI, CHEMICAL
    PNEUMONITIS& PULMONARY EDEMA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SPASM, INFLAMMATION, BURNING SENSATION,
    COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
    NAUSEA, VOMITING.

=======================  First Aid Measures  =======================

First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS.
    INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
    INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL
    ATTENTION IN ALL CAS ES.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:WATER SPRAY, STRONG OXIDIZER.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:CONTACT W/OTHER MATERIAL MAY CAUSE FIRE.
    CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE AREA. WEAR SCBA, RUBBER BOOTS & HEAVY
    RUBBER GLOVES. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED
    CONTAINERS FOR DISPOSAL. FLUSH AREA W/COPIOUS AMOUNTS OF WATER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:REFRIGERATE. PROTECT FROM LIGHT. KEEP
    AWAY FROM COMBUSTIBLE MATERIALS, HEAT, SPARKS & OPEN FLAME. KEEP
    TIGHTLY CLOSED. DON'T STORE NEAR CLOTHING.
Other Precautions:HARMFUL LIQUID. DON'T GET IN EYES, SKIN/CLOTHING.
    AVOID INHALATION. DON'T BREATHE VAPOR.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES/FACE SHIELD (8-INCH MIN)
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
    BATH.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
    REUSE. DISCARD CONTAMINATED SHOES. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
DISPOSAL CONT'D: IF MANGANESE, CHROMIUM/MOLYBDENUM ARE PRESENT ADJUST
    THE SOLUTION TO 7 & TREAT W/SULFIDE TO PRECIPITATE FOR BURIAL AS
    HAZARDOUS WASTE, IAW/FEDERAL, STATE & LOCAL REGULATIONS. DESTROY 
    EXCESS SULFIDE, NEUTRALIZE & FLUSH THE SOLUTION DOWN THE DRAIN.
    MATERIALS CONT'D: FINELY POWDERED METALS, IRON/IRON SALT

==================  Physical/Chemical Properties  ==================

Appearance and Odor:LIQUID

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS/REDUCING AGENTS/BRASS/COPPER/COPPER ALLOYS/GALVANIZED
    IRON/ZINC/NICKEL/LEAD/RUST. (SEE SUPP)
Stability Condition to Avoid:LIGHT, HEAT, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:COMBUSTION: OXYGEN, WATER.

====================  Disposal Considerations  ====================

Waste Disposal Methods:CAUTIOUSLY ACIDIFY A 3% SOLUTION/A SUSPENSION OF
    MATERIAL W/SULFURIC ACID. ADD 50% OF AQUEOUS SODIUM BISULFITE
    W/STIRRING AT ROOM TEMP. AN INCREASE IN TEMP INDICATES A REACTION
    IS TAKING PLACE. IF NOT  INITIATE BY CAUTIOUSLY ADDING MORE ACID.
    (SUPP)

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

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