===================== Product Identification =====================
MSDS NAME:SILVALOY 15 SILVER-COPPER-PHOSPHORUS BRAZING ALLOY
NIIN:00-204-2555
MSDS Number: CHKWV
=== Responsible Party ===
Company:ENGLEHARD CORP. SPECIALTY METALS DIV.
Address:235 KILVERT ST
City:WARWICK
State:RI
ZIP:02886
Country:US
Info Phone Num:401-739-9550
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:86337
=== Contractor Identification ===
Company:ENGELHARD CORP
Address:235 KILVERT ST
Box:City:WARWICK
State:RI
ZIP:02886
Country:US
Phone:401-739-9550
CAGE:86337
Company:ENGELHARD CORP SPECIALTY CHEM DIV RESEARCH DEPT
Address:MENLO PARK
Box:City:EDISON
State:NJ
ZIP:08817
Country:US
Phone:908-205-5000
CAGE:9A166
============= Composition/Information on Ingredients =============
Name:COPPER (SARA 313) (CERCLA)
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 74-94%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2 MG/M3 FUME; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SILVER (SARA 313) (CERCLA)
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: 0.5-19%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:PHOSPHOROUS (YELLOW) (SARA 302/313) (CERCLA)
CAS:7723-14-0
RTECS #:TH3500000
Fraction by Wt: 2-8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.02 PPM; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN:IRRIT.INHAL:IRRIT RESP
TRACT.SHORTTERM OVEREXPO MAY CAUSE FLU-LIKE ILLNESS(METAL FUME
FEVER).TYPICALLY METAL FUME FEVER BEGINS 4-12HRS AFT SUFFICIENT
EXPO TO FRESHLY FORMED FUMES.SYNDROME RUN S ITS COURSE IN
24-48HRS.INGEST:HARMFUL.MAY CAUSE ABDOMINAL
PAIN,NAU,VOMIT,DIARR.COPPER POIS CAN RESULT IN (SUPPLEMENTA)
Explanation of Carcinogenicity:PER
MSDS:CARCINOGENICITY:NPT/IARC/OSHA:NO.
Effects of Overexposure:OVEREXPO MAY CAUE KIDNEY/LIVER DMG,BLOOD
DISORDERS.MAY CAUSE RESP TRACT IRRIT.OVEREXPO TO FRESHLY FORMED
FUMES MAY CAUSE FLU-LIKE ILLNESS CALLED METAL FUME FEVER.HARMFUL IF
LG AMTS SWALLOWED.MAY CAUSE GI IRRIT,NAU,VOMIT,DIARR.MAY CAUSE
EYE/SKIN IRRIT.
Medical Cond Aggravated by Exposure:MAY ADVERSELY AFFECT EXISTING MED
CONDITIONS SUCH AS EYE,SKIN,RESPIRATORY,BLOOD,LIVER, &/OR KIDNEY
AILMENTS.INDIVIDUALS W/WILSONS DISEASE @INCR RISK OF COPPER POIS.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/PLENTY OF WATER.IRRIT DVLPS CALL DR.SKIN:IMMED
WASH W/SOAP/PLENTY OF WATER.IRRIT PERSIST CALL DR.INHAL:EXPO TO
EXCESSIVE LEVELS OF METAL FUMES REMOVE TO FRESH AIR.SEEK MED
ATTN.INGEST:PROC EDURES NORMALLY NOT NEEDED.IF LARGE QUANTITIES
INGESTED SEEK MED ADVICE.
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NOT APPLICAE
Upper Limits:NOT APPLICAE
Extinguishing Media:USE CO2,CHEM FOAM,DRY CHEM.USE ANY MEANS FOR
EXTINGUISHING SURROUNDING FIRE.DONT USE WATER ON METAL FIRES.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROV POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING AS
SEPCIFIED IN 29CFR1910.156.
Unusual Fire/Explosion Hazard:NOT FIRE/EXPLO HAZ IN SOLID FORM.FINELY
DIVIDED DUST MAY IGNITE,BURN RAPIDLY WHEN MIX W/AIR IN PROPER
PROPORTIONS.TOXIC METAL FUMES MAY BE RELEASED IN FIRE SITU
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN.SCOPP UP/VACUUM.NOTIFICATION OFNAT
RESP CNTR 800-424-8802 MAY BE REQUIRED.REFER EPA/DOT/APPLIC
STAT/LOC REGS FOR CURRENT RESPONSE INFO.RECOMMEND EA USER ESTABLISH
SPCC-INCLUDE PROPER STORAGE/C NTR/CLEANUP,RESUE/DISPO.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL DRY LOCATION AWAY FROM
INCOMPATIBLE MATLS.AVOID CONTACT W/DUST/MIST/FUMES RESULTING FROM
USE OF PRODUCT.USE ONLY W/ADEQUATE VENTILATION.
Other Precautions:DONT EAT/DRINK/SMOKE IN WORKAREA.PESONNEL SMPL
PROCEDURE:CU:NIOSH MANUAL ANALYTICAL METHODS,4TH ED,METHOD
7029;PHOSPHORUS:SAME MANUAL ABOVE,METHOD 7905;SILVER:SAME MANUAL
ABOVE,METHOD 7300. DISPO:CHEM ADDN/PROCES/ALTER MATL MAKE INFO
INACCU
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DUST/FUME GENERATED,NIOSH/MSHA APPROV RESP MAY
BE NECESSARY.FOLLOW ALL REQMTS FOR RESP PROGRAMS/SELECTION SET
FORTH IN OSHA REG(29CFR1910.134) & ANSI Z99.2(PRACTICES FOR RESP
PROTECTION).
Ventilation:GEN/LOC EXHAU VENTI AS NECESSARY TO CONTROL ANY AIR
CONTAMINANTS TO W/IN PELS/TLVS DURING USE OF PRODUCT.
Protective Gloves:REFER TO ANSI/ASC Z49.1-94
Eye Protection:SAFETY GLASSES(W/SIDE SHIELDS).
Other Protective Equipment:BODY PROTECTION AS NECESSARY TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG. SARA SEC 313
CHEMS:YES.
Supplemental Safety and Health
HEALTH:HEMOLYTIC ANEMIA,KID/LIV/SPLEEN DMG.POT HEALTH EFFECTS DESCRIBED
ABOVE ONLY APPLY IF DUST/FUME FORMED.CHRONIC:PROL OVEREXPO TO
PHOSPORUS CAUSE GI DISTRESS,GARLIC BREATH,NECROSIS,DEFORMITY IN JA
W.SYSTEMIC EFFECTS(CARDIAC,LIV,KID,DYSFUNCTION)RESULT DUE TO PROL
FUME INHAL.ARGYRIA(PERM LOC BLUE-FREY DISCOLOR EYE/SK)
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NE
Melt/Freeze Pt:M.P/F.P Text:1178F,637C
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:7.40-8.54
pH:NA
Viscosity:NP
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC WIRE,ROD,STRIP; ODOLRESS
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS/BASES,OXIDIZING AGENTS,ACETYLENE,AMMONIA,H2O2,MG
METAL,AMMONIUM NITRATE,HYDROGEN SULFIDE,CHLORINATED RUBB.
Stability Condition to Avoid:NONE EXPECTED.
Hazardous Decomposition Products:TOXIC METAL OXIDES ARE EMITTED WHEN
HEATED ABOVE MELTING POINT.AMT OF FUME EVOLVED INCREASES AS TEMP
RISES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAINS AG/AG CMPDS-DISPO MAY BE REG UNDER HAZ
WASTE D011.BEF DISPO PROD/MIX W/PROD SHOULD BE TESTED FOR TC UNDER
EPA HAZ WASTE REGS TCLP TEST PROCEDURES(40CFR261 ET
SEQ).DISPO/RECYCL/RECLAMA REQMTS VARY BY LOC/TYP OF DISPO
SELECTED.CONSULT AUTHORIT
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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