===================== Product Identification =====================
MSDS NAME:ETHANOL SDA 3A 200 PROOF
NIIN:00D005104
MSDS Number: CHLCL
=== Responsible Party ===
Company:ASHLAND CHEMICAL COMPANY
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:800-274-5236 0R 800-ASHLAND
CAGE:34897
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Phone:614-790-3333/800-274-5263
CAGE:34897
============= Composition/Information on Ingredients =============
Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 93-97%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 4.8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 96
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT CAUSES IRRITATION. SKIN
CONTACT MAY CAUSE MILD IRRITATION. PROLONGED/REPEATED SKIN CONTACT
MAY CAUSE DRYING/CRACKING/REDNESS/BURNING. SWALLOWING MAY BE
HARMFUL. BREATHING SMALL AMOUNTS OF MATERIAL DURING NORMAL
HANDLING NOT LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE
MAOUNTS MAY BE HARMFUL.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:STOMACH OR INTESTINAL UPSET, NAUSEA, VOMITING,
DIARRHEA, NOSE/THROAT/AIRWAYS IRRITATION, DIZZINESS, DROWSINESS,
WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS, VISUAL
IMPAIRMENT, BLINDNESS, DEAT H.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
FLUSH UNDER LIDS BY LIFTING THEM OR ROLLING EYES. SEE DOCTOR ASAP.
SKIN: FLUSH WITH WATER. REMOVE CLOTHING AND CONTINUE FLUSHING.
INHALATION : REMOVE TO FRESH AIR AND RESTORE BREATHING. GET MEDICAL
HELP. INGESTION: SEEK MEDICAL ATTENTION. IF VICTIM IS ALERT, INDUCE
VOMITING. IF DROWSY OR UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:60.0F,15.6C
Lower Limits:3.3
Upper Limits:19.0
Extinguishing Media:ALCOHOL FOAM OR WATER FOG OR CARBON DIOXIDE OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE DEMAND MODE WHEN
FIGHTING FIRES.
Unusual Fire/Explosion Hazard:VAPOR IS FLAMMABLE AND HEAVIER THAN AIR
AND MAY TRAVEL TO SOURCE OF IGNITION AND FLASHBACK. USE WATER TO
KEEP FIRE EXPOSED CONTAINERS COOL TO REDUCE PRESSURE.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT,
OR OTHER MATERIA AND TRANSFER TO HOOD. ELIMINATE ALL IGNITION
SOURCES. TRANSFER CONTAMINATED ABSORBENT TO CONTAINERS FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINS METHANOL. CANNOT BE MADE
NONPOISONOUS. ALL FIVE-GALLON PAILS & LARGER METAL CONTAINERS
SHOULD BE GROUNDED/BONDED WHEN MATERIAL IS TRANSFERRED
Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE AND CAN BE DANGEROUS.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY OR OTHER
SOURCES OF IGNITION. THEY MAY EXPLODE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE LIMITS OF PRODUCT OR ANY COMPONENT
ARE EXCEEDED, A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS
ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROLS.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION AS
REQUIRED TO MAINTAIN EXPOSURE LEVELS.
Protective Gloves:RESISTANT GLOVES SUCH AS NEOPRENE.
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
FORMAULATION CHANGE.
================== Physical/Chemical Properties ==================
HCC:F5
Boiling Pt:B.P. Text:171F,77C
Melt/Freeze Pt:M.P/F.P Text:<148F,<64C
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:48.50
Vapor Density:1.56
Spec Gravity:0.794
Evaporation Rate & Reference:2.67 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, ALCOHOL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID ALL SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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