===================== Product Identification =====================
MSDS NAME:1416281 INDUST MAINT/TOUCH UP SPRAY COLORS,2001 HUNTER GREEN
NIIN:00D007261
MSDS Number: CHLDF
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO THE SPECIALTY DIV.
Address:31500 SOLON RD
City:SOLON
State:OH
ZIP:44146-5000
Country:US
Info Phone Num:800-777-2966/247-3266
Emergency Phone Num:216-566-2917/216-292-7400
CAGE:DO642
=== Contractor Identification ===
Company:SCHOOL SPECIALTY INC DBA SCHOOL SPECIALTY SUPPLY
Address:3525 S 9TH ST
Box:1547
City:SALINA
State:KS
ZIP:67401-7883
Country:US
Phone:913-827-0451
CAGE:4A560
Company:SHERWIN-WILLIAMS CO THE SPECIALTY DIV.
Address:6830 COCHRAN RD.
Box:6709
City:SOLON
State:OH
ZIP:44139-3908
Phone:216-292-7400
CAGE:DO642
Company:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
CAGE:09800
============= Composition/Information on Ingredients =============
Name:PROPANE (PROPELLANT)
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 13%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9596
Name:BUTANE (PROPELLANT)
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 7%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9596
Name:ETHYL BENZENE (SARA 313)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125STEL;9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 35%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:50 PPM/75 STEL; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
CAS:108-65-6
RTECS #:AI8295000
Fraction by Wt: 7%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT ESTABLISHED.
ACGIH TLV:NOT ESTABLISHED.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPO MAY BE INHAL &/OR SKIN OR EYE
CONTACT,DEPENDING ON CONDITIONS OF USE.TO MIN EXPO FOLLOW
RECOMMENDATIONS FOR PROPER USE/VENTI/PPE.IRRIT EYE/SKIN/RESP
SYST.MAY CAUSE NERV SYS DEPRESS.EXTREME OVEREX PO MAY RESULT IN
UNCONSCIOUSNESS & POSSIBLY DEATH.
Explanation of Carcinogenicity:PER MSDS:NO INGRED IN PRODUCT IA AN
IARC/NTP/OSHA LISTED CARCINOGEN.CALIFORNIA PROP 65.
Effects of Overexposure:HEAD,DIZZ,NAU,LOSS OF COORDINATION INDICATIONS
OF EXCESSIVE EXPO TO VAP/SPRAY MISTS.RED,ITCH OR BURNING SENS MAY
INDICATE EYE OR EXCESSIVE SKIN EXPO.PROL OVEREXPO TO SOLVT INGREDS
MAY CAUSE ADVERSE EF FECTS TO
LIV,URINARY,BLOOD-FORM/CARDIOVASCULAR/REPROD SYS.MEK INCR NERV SYS
EFFECTS OF OTHER SOLVTS.REPORTS HAVE (SUPPL)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:IF AFFECTED REMOVE FRM EXPO.RESTORE BREATH.KEEP
AWARM/QUIET.SKIN:WASH AREA THOROUGHLY W/SOAP/WATER.REMOVE CONTAM
CLOTH.LAUNDER BEFORE REUSE.EYE:FLUSH W/LG AMTS OF WATER FOR
15MINS.GET MED ATTN.I NGEST:GET MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F,<-18C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:0.9
Upper Limits:13.1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROT EQPMT INCLUDE SCBA SHOULD BE
USED.H2OSPRAY MAY BE INEFFECTIVE.H2O USED FOG NOZZ PREF.H2O MAY BE
USED TO COOL CLSD CNTNR TO PREVENT PRESSURE (SUPPLEME)
Unusual Fire/Explosion Hazard:ISOLATE FRM HEAT/ELECTR EQPMT/SPARK/OPN
FLAME.APPLICATION TO HOT SURF REQUIRES SPECIAL PRECAUT.DURING EMERG
CONDITIONS OVEREXPO TO DECOMPO PRODS MAY CAUSE(SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION.VENTILATE AND
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY W/ADEQ VENTI.COAT MAY CONTAIN
MATLS CLASS AS NUISANCE PARTICULATES-PRESENT @HAZ LEVELS ONLY
DURING SAND/ABRADE OF DRIED FILM.STORAGE CAT=1A.
Other Precautions:DURING USE/TIL VAP GONE KEEP AREA VENTI-DONT
SMOKE.EXT ALL FLAME,PILOT LIGHT,HEATER.TURN OFF STOVE/ELEC
TOOLS/APPLIANCES/IGN SOURCES.CONSULT NFPA CODE.USE APPROV
BOND/GROUND PROCEDURES.CONTENTS UNDER PRESSURE.HEAT/ETC CAUSE
CNTNR TO BURST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PERS EXPO CANT BE CNTRL BEL APPLIC LIMITS BY
VENTI WEAR PROPERLY FITTED ORG VAP/PARTICU NIOSH/MSHA APRPOV RESP
FOR PROTECTION AGAINST INGREDS.SAND/ABRADE DRIED FILM WEAR
DUST/MIST NIOSH/MSHA APPROV RE SP FOR DUST FRM PROD/UNDER
PAINT/ABRASIV
Ventilation:LOC EXHAU PREFER.GEN EXHAU ACCEPTABLE IF EXPO TO MATLS
MAINTAINED BEL APPLICABLE EXPO LIMITS.REF OSHA 1910.94;.107;.100.
Protective Gloves:NONE-NORM APPLIC;CHEM RESIST-LONG EXPO.
Eye Protection:SAF SPECTACLES W/UNPERFORATED SIDESHIELD
Other Protective Equipment:INTENTIONAL MISUSE BY DELIBERATELY CONCEN &
INHAL CONTENTS CAN BE HARMFUL OR FATAL.
Work Hygienic Practices:AVOID BREATH VAP/SPRAY MIST & CONTACT
W/SKIN/EYES.WASH HANDS AFT USING.KEEP OUT OF REACH OF CHILDREN.DONT
TAKE INTERNALY
Supplemental Safety and Health
FIREFIGHT:BUILDUP/POSSIBLE AUTOIGN/EXPLO WHEN EXPO TO EXTREME HEAT.
FIRE/EXPLO:HEALTH HAZ.SYMPT MAY NOT BE IMMED APPARENT.OBT MED ATTN.
SIGN/SYMPT:ASSOC REP/PROL OVEREXPO TO SOLVTS W/PERM BRAIN/NERV S YS
DMG. DISPO:TEST FOR EXTRACTABILITY.DONT INCINERATE.DEPRESSURE
CNTNR.DISPO OF IAW FED/STATE/LOC REGS REGARDING POLLUTN
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:<-18.C, -.4F
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
Vapor Pres:NP
Vapor Density:>AIR
Volatile Org Content %:86
Spec Gravity:NA
pH:NP
Viscosity:NP
Evaporation Rate & Reference:FASTER THAN ETHER
Solubility in Water:NA
Appearance and Odor:HUNTER GREEN,CONTENTS UNDER PRESSURE.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:KEEP AWAY FRM HEAT/SPARKS/OPEN FLAME.VAP
WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE,CARBON
MONOXIDE, OXIDES OF METALS INGREDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAINS INGREDS SUBJ TO REPORT REQMTS OF SARA
SEC 313/40CFR372.65C.WASTE FRM PROD MAY BE HAZ AS DEF UNDER RCRA
40CFR261.WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
AP0PLICABLE EPA HAZ WASTE#.W ASTE FRM PROD CONTAINING MEK OR CU MAY
REQUIRE(SU)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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