===================== Product Identification =====================
MSDS NAME:128554 1 5-HEXADIENE 97%
NIIN:00F056396
MSDS Number: CHNBL
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:1,5-HEXADIENE *98-2*
CAS:592-42-7
RTECS #:MM2000000
Fraction by Wt: 97%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED/SWALLOWED. MATERIAL
IS IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. EYES:
MAY CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN
MEDICAL ATTEN TION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:-17F
Lower Limits:1.2
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CONTAINER EXPLOSION MAY OCCUR UNDER FIRE
CONDITIONS. MAY FORM EXPLOSIVE MIXTURES IN AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF
IGNITION. WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/AN
ACTIVATED CARBON ABSORBENT, TAKE UP & PLACE IN CLOSED CONTAINERS.
TRANSPORT OUTDOORS. VENTILA TE & WASH SITE AFTE MATERIAL PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED & AWAY FROM
HEAT/SPARKS & OPEN FLAME. REFRIGERATE. WEAR SUITABLE PROTECTIVE
CLOTHING, GLOVES, EYE/FACE PROTECTION.
Other Precautions:DON'T BREATHE VAPOR. AVOID CONTACT W/EYES, SKIN &
CLOTHING. NO SMOKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:SAFETY SHOWER, EYE BATH
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:140F
Melt/Freeze Pt:M.P/F.P Text:-221.8F
Vapor Pres:367
Spec Gravity:0.692
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Stability Condition to Avoid:FIRE, HEAT, SPARKS, OPEN FLAMES & OTHER
IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER BUT EXERT CARE IN IGNITING AS THIS MATERIAL
IS HIGHLY FLAMMABLE. DISPOSE OF IAW/LOCAL, STATE & FEDERAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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