===================== Product Identification =====================
MSDS NAME:269824 METHYL-D3 ALCOHOL-D 99.8% ATOM D
NIIN:00F056339
MSDS Number: CHMZH
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:METHYL-D3 ALCOHOL-D
CAS:811-98-3
Fraction by Wt: 99.8%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED, INGESTED/ABSORBED
THROUGH SKIN. IRRITATING TO THE EYES, MUCOUS MEMBRANES & UPPER
RESPIRATORY TRACT. SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, GI DISTURBANCES, CONVULSIONS.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15MINS.
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL
ATTENTION IN ALL CASE S.
===================== Fire Fighting Measures =====================
Flash Point:52F
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPOR MAY TRAVEL
CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF SOURCES OF IGNITION.
WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/DRY LIME,
SAND/SODA ASH. PLACE IN COVERED CONTAINERS USING NON-SPARKING TOOLS
& TRANSPORT OUTDOORS. VENTILATE AREA & WASH AFTER PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP AWAY
FROM HEAT, SPARKS & OPEN FLAME. KEEP TIGHTLY CLOSED. STORE UNDER
NITROGEN.
Other Precautions:DON'T USE IF SKIN IS CUT/SCRATCHED. AVOID
PROLONGED/REPEATED EXPOSURE. AVOID CONTACT W/EYES, SKIN & CLOTHING.
DON'T BREATHE VAPOR. HYGROSCOPIC. NO SMOKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH.
Work Hygienic Practices:DISCARD CONTAMINATED CLOTHING & SHOES. WASH
THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:149.72F
Spec Gravity:0.888
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS, REDUCING
AGENTS, ALKALI METALS.
Stability Condition to Avoid:MOISTURE, HEAT, SPARKS & OPEN FLAME.
Hazardous Decomposition Products:COMBUSTION: CO, CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE, IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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