===================== Product Identification =====================
MSDS NAME:TOLUENE-D8 99+ ATOM % D
NIIN:00N091151
Status Code:A
MSDS Number: CJHBJ
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010;314-771-5750(INTL)
Emergency Phone Num:1-314-771-5765
Resp. Party Other MSDS Num.:T9021
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:TOLUENE-D8 99+ ATOM % D
CAS:2037-26-5
> Wt:99.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. CAUSES EYE IRRITATION. HIGH
CONCENTRATIONS ARE EXTREMELY DESTRUCTIVE TO TISSUES OF MUC MEMB &
UPPER RESP TRACT, EYES & SKIN. SYMPTOMS OF EXPOSURE MAY INCL
BURNING SENSATION, COUGH, WHEEZING, LARYNGITIS, SHORTNESS OF
BREATH, HDCH, NAUS & VOMIT. EXPOSURE CAN CAUSE: LUNG IRRIT, CHEST
PAIN & EDEMA WHICH MAY BE FATAL. CHRONIC: MAY CAUSE NE RV SYS
DISTURBANCES. INHAL STUDIES ON TOLUENE HAVE DEMONSTRATED
DEVELOPMENT OF INFLAMMATORY & ULCEROUS LESIONS OF THE PENIS,
PREPUCE & SCROTUM IN ANIMALS. TARGET ORGAN(S): (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: BRAIN, LIVER, KIDNEYS, BLADDER.
ADDITIONAL INFORMATION: EXPSOURE TO AND/OR CONSUMPTION OF ALCOHOL
MAY INCREASE TOXIC EFFECTS. TOLUENE APPEARS ON THE NAVY
OCCUPATIONAL CHEMICAL REPRODUCTIVE H AZARDS LIST. SEEK
CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE
INFORMATION .
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. IF INHALED, REMOVE TO FRESH AIR.
IF NOT BREATHI NG GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Flash Point:=10.C, 50.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM. WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT
EXTINGUISHMENT.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DANGER: EXTREMELY FLAMMABLE. VAPOR MAY
TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK.
CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF
IGNITION. WEAR NIOSH APPRVD SCBA, RUBBER BOOTS AND HEAVY RUBBER
GLOVES. COVER WITH AN ACTIVATED CARBON ABSORBENT, TAKE UP AND PLACE
IN CLOSED CONTAINERS. TRANSPO RT OUTDOORS. VENTILATE AREA AND WASH
SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:FLAMMABLE (USA). HIGHLY FLAMMABLE (EU)
TOXIC. TOXIC BY INHAL, IN CONT W/SKIN & IF SWALLOWED. CAUSES SEV
IRRIT. TARGET ORGAN(S): LIVER , KIDNEYS. DO NOT BREATHE VAP. DO NOT
GET IN EYES, ON SKIN, ON CLT HG. AVOID PRLNGD/RPTD EXPOSURE.
READILY ABSORBED THROUGH SKIN.
Other Precautions:KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS, AND
OPEN FLAME. STORE IN A COOL DRY PLACE. KEEP AWAY FROM ALL SOURCES
OF IGNITION - NO SMOKING. IN CASE OF ACCIDENT/IF YOU FEEL UNWELL,
SEEK MED ADVIC E IMMED (SHOW LABEL WHERE POSSIBLE). WEAR SUITABLE
PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTI ON.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:MEDIA SUITABLE FOR SURROUNDING FIRE .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:0.943
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS. PROTECT FROM MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURN AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATI ONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
Federal Regulatory Information:EUROPEAN INFORMATION. HIGHLY FLAMMABLE.
TOXIC R 11. HIGHLY FLAMMABLE. 4 20. HARMFUL BY INHALATION. S 16.
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. NAME: S 25 AVOID
CONTACT WITH EYES. S 29 DO NO T EMPTY INTO DRAINS. S 33 TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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