===================== Product Identification =====================
MSDS NAME:LITHIUM PERCHLORATE 95+% ACS REAGENT 205281
Status Code:A
MSDS Number: CJGZF
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:LITHIUM PERCHLORATE
CAS:7791-03-9
> Wt:95.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL BY INHALATION/INGESTION/SKIN
ABSORPTION. EYES/SKIN: IRRITATION. INHALATION: IRRITATION TO MUCOUS
MEMBRANES & UPPER RESPIRATORY TRACT. LARGE DOSES OF LITHIUM ION CAN
CAUSE KIDNEY DAMAGE IF SODI UM INTAKE IS LIMITED. THYROID
DISTURBANCES.
Effects of Overexposure:IRRITATION. LARGE DOSES OF LITHIUM ION:
DIZZINESS & PROSTRATION. DEHYDRATION, WEIGHT LOSS, DERMATOLOGICAL
EFFECTS & THYROID DISTURBANCES, SLURRED SPEECH, BLURRED VISION,
SENSORY LOSS, ATAXIA & CONVULS IONS, VOMITING & NEUROMUSCULAR
EFFECTSS SUCH AS TREMOR, CLONUS & HYPERACTIVE REFLEXES
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/WATER FOR AT LEAST 15 MIN. INHALATION:
REMOVE TO FRESH AIR. APPLY CPR/OXYGEN IF NECESSARY. INGESTION:
WASH MOUTH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN/EYES. OXIDIZER.
Unusual Fire/Explosion Hazard:CONTACT W/OTHER MATERIAL MAY CAUSE FIRE.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR SELF CONTAINED BREATHING
APPARATUS & PROTECTIVE CLOTHING. COVER W/ DRY LIME/SODA ASH, PICK
UP, KEEP IN A CLOSED CONTAINER & HOLD FOR WASTE DISPOSAL.
VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM COMBUSTIBLE
MATERIALS/HEAT/SPARKS/OPEN FLAME. USE ONLY IN A CHEMICAL FUME
HOOD. AVOID PROLONGED/REPEATED EXPOSURE. KEEP TIGHTLY CLOSED.
HYGROSCOPIC. STORE IN ACOOL DRY PLACE. WEAR SELF CONTAINED
BREATHING APPARATUS & PROTECTIVE CLOTHING, GLOVES/EYE/FACE
PROTECTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA-APPROVED RESPIRATOR.
Ventilation:REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT/HEAVY RUBBER.
Eye Protection:SAFETY GOGGLES.
Other Protective Equipment:SAFETY SHOWER & EYE BATH. RUBBER BOOTS
Work Hygienic Practices:DON''T GET ON EYES/SKIN/CLOTHING. WASH
THOROUGHLY BEFORE EATING/DRINKING/SMOKING & AT END OF
WORKDAY.REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=236.C, 456.8F
Spec Gravity:2.428
Appearance and Odor:WHITE GRANULES
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS/NITROMETHANE, HYDRAZINE/1,3-DIOXOLANE.
Stability Condition to Avoid:TEMPERATURES > 752F, MOISTURE.
Hazardous Decomposition Products:LITHIUM CHLORIDE & OXYGEN.
=================== Toxicological Information ===================
Toxicological Information:TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL,
PHYSICAL & TOXOCOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED.
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL QUANTITIES:CAUTIOUSLY ADD TO LARGE
STIRRED EXCESS OF WATER. ADJUST PH TO NEUTRAL, SEPARATE ANY
INSOLUBLE SOLIDS/LIQUIDS & PACKAGE. FLUSH THE AQUEOUS SOL. DOWN
THE DRAIN W/ PLENTY OF WATER. HY DROLYSIS & NEUTRALIZATION
REACTIONS MAY GENERATE HEAT/ FUMES WHICH CAN BE CONTROLLED.
DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT ALDRICH CHEMICAL CO. FOR TRANSPORT
INFORMATION.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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