===================== Product Identification =====================
MSDS NAME:MONOETHANOLAMINE
NIIN:00-922-0866
Status Code:A
MSDS Number: CJJGH
=== Responsible Party ===
Company:UNION CARBIDE CORP LINDE DIV
Address:39 OLD RIDGEBURY RD
City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Info Phone Num:203-744-3487
Emergency Phone Num:800-UCC-HELP (304-744-3487)
Resp. Party Other MSDS Num.:000000001592
CAGE:36346
=== Contractor Identification ===
Company:EMULTEC INDUSTRIAL PRODUCTS INC
Address:1150 HAYDEN DR SUITE 100
Box:City:CHARROLLTON
State:TX
ZIP:75006
Country:US
Phone:972-417-1288
Contract Num:SP0450-99-M-C213
CAGE:0WA27
Company:UNION CARBIDE CORP
Address:39 OLD RIDGEBURY ROAD
Box:City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Phone:800-822-4357/732-563-5522 (MSDS)
CAGE:61637
Company:UNION CARBIDE CORP LINDE DIV
Address:39 OLD RIDGEBURY RD
Box:City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Phone:800-822-4357; 304-744-3487
CAGE:36346
Company:UNION CARBIDE CORP CHEMICALS AND PLASTICS DIV
Address:308 HARPER DR
Box:City:MOORESTOWN
State:NJ
ZIP:08057
Country:US
Phone:201-646-1111
CAGE:7L938
============= Composition/Information on Ingredients =============
Name:MONOETHANOLAMINE
CAS:141-43-5
RTECS #:KJ5775000
> Wt:99.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:6 MG/M3;3 PPM
OSHA STEL:15 MG/M3, 6 PPM
ACGIH TLV:7.5 MG/M3;3 PPM
ACGIH STEL:15 MG/M3;6 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT, MALE) 1.19 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, LUNG, LIVER,
KIDNEY (HMIS). ACUTE - INHALATION: MAY CAUSE IRRITATION OF
RESPIRATORY TRACT, EXPERIENCED AS NASAL DISCOMFORT AND DISCHARGE,
COUGHING, CHEST PAIN. PROLONGED OVER EXPOSURE MAY CAUSE INJURY. EYE
CONTACT: LIQUID CAUSES SEVERE IRRITATION, DISCOMFORT OR PAIN,
EXCESS BLINKING AND TEARING, REDNESS AND SWELLING OF CONJUNCTIVA
AND BURNS OF CORNEA. SKIN CONTACT: CAUSES DISCOMFORT OR PAIN,
SEVERE REDNESS AND SWELLING, TISSUE DESTRUCTION. SKIN ABSORPTION:
TOXIC. SWALLOWING: ASPIRATION INTO LUNGS CAUSES LUNG INJURY. CAUSES
BURNS, STOMACH PAIN, DIZZINESS, COMA. CHRONIC - MAY CAUSE LIVER
AND KIDNEY DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NASAL DISCOMFORT AND DISCHARGE, COUGHING, AND
POSSIBLY ACCOMPANIED BY CHEST PAIN, LUNG INJURY, SEVERE IRRITATION,
PAIN, EXCESS BLINKING AND TEARING, REDNESS AND SWELLING OF
CONJUNCTIVA AND CHEMICAL BU RNS OF CORNEA, SKIN SEVERE EXCESS
REDNESS AND SWELLING, TISSUE DESTRUCTION, FISSURES, ULCERATION AND
POSSIBLY BLEEDING INTO INJURED AREA, NAUSEA, VOMITING, DIARRHEA,
STOMACH PAIN, DIZZINESS, DROWSINES S, THIRST, FAINTNESS, WEAKNESS,
CIRCULATORY COLLAPSE AND COMA
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS. INHALATION OF MATERIAL MAY AGGRAVATE ASTHMA
AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN MAY BE
GIVEN BY QUALIFIED PERSONNEL. OBTAIN MEDICAL ATTENTION. EYE
CONTACT: IMMEDIATEL Y FLUSH EYES WITH WATER AND CONTINUE WASHING
FOR AT LEAST 15 MINUTES. DO NOT REMOVE CONTACT LENSES, IF WORN.
OBTAIN MEDICAL ATTENTION WITHOUT DELAY, PREFERABLY FROM AN
OPHTHALMOLOGIST. SKIN: IMMEDIATE LY REMOVE CONTAMINATED CLOTHING
AND SHOES. WASH SKIN WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION.
SWALLOWING: IF PATIENT IS FULLY CONSCIOUS, GIVE 2 GLASSES OF MILK
OR WATER. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION WITHOUT
DELAY.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=96.1C, 205.F
220 OC
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:APPLY ALCOHOL-TYPE OR ALL-PURPOSE TYPE FOAM BY
MANUFACTURER'S RECOMMENDED TECHIQUES FOR LARGE FIRES. USE CARBON
DIOXIDE OR DRY CHEMICAL MEDIA FOR SMALL FIRES.
Fire Fighting Procedures:DO NOT DIRECT A SOLID STREAM OF WATER OR FOAM
INTO BURNING MOLTEN MATERIAL; THIS MAY CAUSE SPATTERING AND SPREAD
THE FIRE. USE SELF-CONTAINED BREATHING APPARATUS, EYE PROTECTION
AND PROTECTIVE CLOTHI NG.
Unusual Fire/Explosion Hazard:DURING FIRE, OXIDES OF NITROGEN MAY BE
EVOLVED.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT FOR DISPOSAL. WEAR SUITABLE PROTECTIVE
EQUIPMENT. AVOID CONTACT WITH EYES AND SKIN. AVOID RUNOFF TO
WATERWAYS AND SEWERS. MONOETHANOLAMINE IS TOXIC TO AQUATIC LIFE AT
RELATIVELY LOW CONCENTRAT IONS IN WATER.
Neutralizing Agent:ACETIC ACID, DILUTE PHOSPHORIC OR SULFURIC ACID
====================== Handling and Storage ======================
Handling and Storage Precautions:STABILITY - MONOETHANOLAMINE AND IRON
FORM A COMPLEX MOLECULE THAT CAN SPONTANEOUSLY DECOMPOSE AT
TEMPERATURES BETWEEN 130 AND 160 C, AND HAS BEEN SUSPECTED OF
CAUSING A FIRE IN A NEARLY EMPTY STORAGE TANK CONTAINING A "HEEL"
OF MEA IN CONTACT WITH CARBON STEEL COILS. WHEN THAWING, HEAT BELOW
130C.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT
SWALLOW. AVOID BREATHING VAPORS. KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR
INDUSTRIAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS IN HIGH
VAPOR CONCENTRATIONS
Ventilation:GENERAL MECHANICAL ROOM VENTILATION IS EXPECTED TO BE
SATISFACTORY WHERE THIS PRODUCT IS STORED AND HANDLED IN CLOSED
EQUIPMENT.
Protective Gloves:PVC-COATED RUBBER
Eye Protection:MONOGOGGLES
Other Protective Equipment:EYE BATH, SAFETY SHOWER, AND CHEMICAL APRON.
SPECIAL LOCAL VENTILATION IS NEEDED AT POINTS WHERE VAPORS CAN BE
EXPECTED TO ESCAPE TO THE WORKPLACE AIR.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH BEFORE EATING, DRINKING OR SMOKING.
Supplemental Safety and Health
NOTE TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE. TREATMENT SHOULD BE
DIRECTED AT THE CONTROL OF SYMPTOMS AND CLINICAL CONDITION OF THE
PATIENT. THE HAZARDS OF THIS MATERIAL ARE DUE MAINLY TO ITS SEVE
RELY IRRITANT POPERTIES ON SKIN AND MUCOSAL SURFACES. THE STOMACH
SHOULD BE EVACUATED CAREFULLY IN CASE OF POISONING.
================== Physical/Chemical Properties ==================
HCC:B2
Boiling Pt:=170.3C, 338.7F
Melt/Freeze Pt:=10.6C, 51.F
Vapor Pres:0.2 MMHG
Vapor Density:2.1
Spec Gravity:1.017
Evaporation Rate & Reference:0.02 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:LIQUID, TRANSPARENT COLORLESS, MILD AMMONICAL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS, ALDEHYDES,
KETONES, ACRYLATES, ORGANIC ANHYDRIDES, ORGANIC HALIDES, FORMATES,
LACTONES, OXALATES.
Stability Condition to Avoid:TEMPERATURES ABOVE 250 DEGREES C. MAY
UNDERGO SELF-SUSTAINING DECOMPOSITION.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN
=================== Toxicological Information ===================
Toxicological Information:PERORAL: RAT LD50 MALE 1.19 (0.79 - 1.80)
ML/KG; PERORAL: RAT LD50 FEMALE 1.07 (0.72 - 1.59) ML/KG;
PERCUTANEOUS: RABBIT LD50 24 HR OCCLUDED FEMALE 2.83 (1.61 - 4.98)
ML/KG; PERCUTANEOUS: RABBIT LD50 24 HR OCCLUDED MALE 2.46 (1.76 -
3.39) ML/KG
===================== Ecological Information =====================
Ecological:BOD (% OXYGEN CONSUPTION): DAY 5, 60%; DAY 10, 75%, DAY 20,
100%. ECOTOXICITY: ECOTOXICITY TO MICRO-ORGANISMS: LC50 700 -
2000 MG/L; ECOTOXICITY TO AQUATIC INVERTEBRATES: DAPHNIA LC50 48 H
33 MG/L ; ECOTOXICITY TO AQUATIC INVERTEBRATES: DAPHNIA LC50 48 H
93 MG/L; CONFIDENCE LIMITS: 83 - 103 MG/L; ECOTOXICITY TO FISH:
FATHEAD MINNOW LC50 96 H 125 MG/L; ECOTOXICITY TO FISH: FATHEAD
MINNOW L C50 96 H 206 MG/L; CONFIDENCE LIMITS: 176 - 240 MG/L
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE LOCAL, STATE, AND FEDERAL REGULATIONS. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, PROVINCIAL, AND
LOCAL ENVIRONMENTAL REGULATI ONS. EMPTY CONTAINERS SHOULD BE
RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT
FACILIT Y.
===================== Regulatory Information =====================
SARA Title III Information:CERCLA (COMPREHENSIVE ENVIROMENTAL RESPONSE,
COMPENSATION, AND LIABILITY ACT OF 1980 SECTION 103):
DIETHANOLAMINE.SARA TITLE III SECTION 311 AND 312: DELAYED HAZARD:
YES, IMMEDIATE HEALTH HAZARD: YES.
Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE
INCLUDED ON OR EXEMPTED FROM LISTING ON THE TOXIC SUBSTANCE CONTROL
ACT (TSCA) INVENTORY OF CHEMICAL SUBSTANCES.
State Regulatory Information:PENNSYLVANIA (WORKER AND COMMUNITY RIGHT
TO KNOW ACT): MONOETHANOLAMINE. MASSACHUSETTS (HAZARDOUS
SUBSTANCE DISCOLSURE BY EMPLOYERS): MONOETHANOLAMINE. THIS PRODUCT
CONTAINS NO LISTED SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM, AT LEVELS
WHICH WOULD REQUIRE A WARNING UNDER THE STATUTE. CALIFORNIA SCAQMD
(SOUTH COAST AIR QQUALITY MANAG EMENT DISTRICT) RULE 443.1: VOC
1014 G/L.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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