===================== Product Identification =====================
MSDS NAME:SPECIALLY DENATURED ALCOHOL 3A
NIIN:00-201-0906
Status Code:A
MSDS Number: CJJSQ
=== Responsible Party ===
Company:PHOENIX INDUSTRIES INC
Address:11028 LEADBETTER RD UNIT 10
City:ASHLAND
State:VA
ZIP:23005
Country:US
Info Phone Num:804-264-5183
Emergency Phone Num:804-264-5183
Chemtrec Ind/Phone:(800)424-9300
CAGE:0YED2
=== Contractor Identification ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP0450-99-M-C807
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:ETHYL ALCOHOL
CAS:64-17-5
RTECS #:KQ6300000
Minumum % Wt:90.
Maxumum % Wt:95.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1900 MG/M3;1000 PPM
ACGIH TLV:1880 MG/M3;1000 PPM
Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 7,060 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, CNS,
RESPIRATORY AND GI TRACTS (HMIS). ACUTE - EYE: CAN CAUSE
IRRITATION. SPLASHES MAY CAUSE PAIN AND BLURRED VISION. SKIN:
CAUSES IRRITATION, CRACKING OR FLAKING DUE TO DEFA TTING.
INHALATION: MAY CAUSE IRRITATIONTO MUCOUS MEMBRANES OF UPPER
RESPIRATORY TRACT. PROLONGED EXPOSURE TO HIGH CONCENTRATIONS MAY
CAUSE DROWSINESS, LOSS OF APPETITE AND INABILITY TO CONCENTRATE. IN
GESTION: CAUSE HEADACHES, GASTRITIS, INTOXICATION, BLINDNESS AND,
IN ACUTE CASES, DEATH. CHRONIC - SKIN DRYNESS. MAY AFFECT NERVOUS
SYSTEM, LIVER, BLOOD REPRODUCTIVE SYSTEM. CONTINUED INGESTION OF
SMA LL AMOUNTS COULD RESULT IN BLINDNESS.
Explanation of Carcinogenicity:ETHANOL HAS BEEN LINKED TO CANCER IN
HUMANS. CHRONIC ETHANOL INGESTION IS ASSOCIATED WITH LIVER CANCER.
MOST INDUSTRIAL ETHANOL CONTAINS DENATURANTS THAT RENDER IT
UNDESIRABLE TO DRINK.
Effects of Overexposure:EYE PAIN AND BLURRED VISION, SKIN IRRITATION,
CRACKING OR FLAKING DUE TO DEHYDRATION AND DEFATTING, IRRITATION TO
MUCOUS MEMBRANES OF UPPER RESPIRATORY TRACT, DROWSINESS, LOSS OF
APPETITE AND INABILIT Y TO CONCENTRATE, HEADACHES,
GASTRITIS,INTOXICATION, BLINDNESS AND, IN ACUTE CASES, DEATH,
BLINDNESS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY MAY BE MORE
SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN. INGESTION: INDUCE VOMITING IMMEDIATELY AS
DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTHTO AN
UNCONSCIOUS PERSON. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING.
WASH SKIN WITH SOAP OR MILD DETERGENT AND WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENT ION IF IRRITATION DEVELOPS OR PERSISTS.
EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES,, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY.
GET MEDICAL ATTENTION IMMEDIAT ELY.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=13.C, 55.4F
Autoignition Temp:=422.C, 791.6F
Lower Limits:3.3
Upper Limits:19
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,ALCOHOL FOAM,OR CARBON
DIOSIDE. WATER MAY BE INEFFECTIVE
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING& NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN
PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. WATER SPRAY CAN BE
USED TO EXTINGUISH FIRE & COOL FIRE EXPO CONTAINER. USE WATER TO
FLUSH SPILL AWAY FROM EXPOSURE AND TO DILUTE SPILL TO NONFLAMMABLE
MIXTURE
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE
EXPLOSIVE WITHIN FLAMMABLE LIMITS. VAPOR CAN FLOW ALONG SURFACE TO
DISTANT IGNITION SOURCES AND FLASH BACK. SEALED CONTAINERS MAY
RUPTURE WHEN HEATED. SENSITI VE TO STATIC DISCHARGE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF SPILL. REMOVE ALL SOURCES
OF IGNITION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
ISOLATE HAZARD AREA. CONTAIN AND RECOVER LIQUID WHEN POSSIBLE. USE
NON-SPARKING TOOLS. COLLECT LIQUID IN AN APPROPRAITE CONTAINER
ORABSORB WITH AN INERT MATERIAL (E.G., VERMICULITE, DRY SAND), AND
PLACE IN A CHEMICAL WASTE CONTAINER. DO NOT USE COMBUSTIBLE
MATERIALS. DO NOT FLUSH TO SEWERS
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
LOCATION, AWAY FROM FIRE HAZARD AREA. OUTSIDE OR DETACHED STORAGE
IS PREFERRED. SEPARATE FROM INCOMPATIBLES. CONTAINERS SHOULD BE
BONDED AND GROUNDED FOR TRANSFER S TO AVOID STATIC SPARKS. STORAGE
AND USE AREA SHOULD BE NO SMOKING AREAS.
Other Precautions:PROTECT AGAINST PHYSICAL DAMAGE. USE NON-SPARKING
TYPE TOOLS AND EQUIPMENT, INCLUDING EXPLOSION PROOF VENTILATION.
CONTAINERS OF THIS MATERIAL MAY BE HZARDOUS WHEN EMPTY SINCE THEY
RETAIN PRODUCT RESI DUES (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND
PRECAUTIONS LISTED FOR THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED. WEAR A SUPPLIED-AIR, FULL
FACEPIECE RESPIRATOR, AIRLINED HOOD, OR FULL FACEPIECE SELF
CONTAINED BREATHING APPARATUS.
Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EXPOSURES BELOW EXPOSURE LIMITS. LOCAL EXHAUST VENTILATION IS
GENERALLY PREFERRED.
Protective Gloves:IMPERVOIUS
Eye Protection:CHEMICAL SAFETY GOGGLES AND/OR FULL FACE SHIELD
Other Protective Equipment:IMPERVIOUS CLOTHING, INCLUDING BOOTS, LAB
COAT,APRON OR COVERALLS, AS APPROPRIATE TO PREVENT SKIN CONTACT.
EYE WASH FOUNTAIN AND QUICK DRENCH FACILITIES IN WORK AREA.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING,
DRINKING OR SMOKING.
Supplemental Safety and Health
HCC PER TECHNICAL SUPPORT. POISON! DANGER! MAY BE FATAL IF SWALLOWED.
HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. FLAMMABLE! AFFECTS
CENTRAL NERVOUS SYSTEM. MAY CAUSE BLINDNESS. CANNOT BE MADE NONPOI
SONOUS. CAUSES IRRITAITON TO SKIN, EYES,AND RESPIRATORY TRACT. MAY
AFFECT LIVER, BLOOD, REPRODUCTIVE SYSTEM.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=78.C, 172.4F
B.P. Text:ETHANOL
Melt/Freeze Pt:=-114.C, -173.2F
M.P/F.P Text:ETHANOL
Vapor Pres:40 @ 66F ETHANOL
Vapor Density:1.6 ETHANO
Spec Gravity:0.79
pH:NO INFO
Evaporation Rate & Reference:CA. 1.4 (CCL4=1)ETHANOL
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR ODORLESS LIQUID. MILD PLEASANT WHISKEY-LIKE
ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS,SILVER SALTS,ACID CHLORIDES,ALKALI METALS,METAL
HYDRIDES,HYDRAZINE,AND MANY OTHER SUBSTANCES.
Stability Condition to Avoid:HEAT,FLAMES,IGNITION SOURCES AND
INCOMPATIBLES
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
FORM WHEN HEATED TO DECOMPOSITION.
=================== Toxicological Information ===================
Toxicological Information:INHALATION RAT LC50: 20,000 PPM/10H;
IRRITATION DATA, YE, RABBIT:500 MG/24 H SEVERE; METHYL ALCOHOL:
ORAL RAT LD50: 5628 MG/KG; INHALATION RAT LC50: 64000 PPM/4H.
ETHANOL HAS BEEN LINKED TO BIRTH DEFE CTS IN HUMANS.
===================== Ecological Information =====================
Ecological:WHEN ETHANOL RELEASED INTO SOIL, IT IS EXPECTED TO READILY
BIODEGRADE, TO LEACH INTO GROUNDWATER, TO QUICKLY EVAPORATE. WHEN
RELEASED INTO WATER, THIS MATERIAL IS EXPECTED TO REDILY
BIODEGRADE, MODERA TELY EVAPORATE. ETHANOL IS NOT EXPECTEDTO
SIGNIFICANTLY BIOACCUMULATE. WHEN RELEASED INTO AIR, IT IS EXPECTED
TO BE READILY DEGRADED BY REACTION WITH PHOTOCHEMICALLY PRODUCED
HYDROXY RADIACALS, REMOVE D FROM ATMOSPHERE BY DRY AND WET
DEPOSITION AND HAVE A HALF-LIFE OF 1 AND 10 DAYS. IT IS NOT
EXPECTED TO BE TOXIC TO AQUATIC LIFE. THE LC50/96-HOUR VALUES FOR
FISH ARE OVER 100 MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE AND SENT TO A RCRA
APPROVED INCINERATOR OR DISPOSED IN A RCRA APPROVED WASTE FACILITY.
PROCESSING, USE OR CONTAM INATION OF THIS PRODUCT MAY CHANGE THE
WASTE MANAGEMENT OPTIONS. STATE AND LOCAL DISPOSAL REGULATION S MAY
DIFFER FROM FEDERAL.
===================== Regulatory Information =====================
SARA Title III Information:US REGULATIONS (CERCLA) REQUIRE REPORTING
SPILLS AND RELEASES TO SOIL, WATER AND AIR IN EXCESS OF REPORTABLE
QUANTITIES. THE TOLL FREE NUMBER FOR THE US COAST GUARD NATIONAL
RESPONSE CENTER IS (800) 4 24-8802. ETHANOL IS NOT ON SARA 313
LISTBUT METANOL IS. RCRA-CERCLA: REPORTABLE QUANTITY FOR METHANOL
IS 5000 LBS.
State Regulatory Information:
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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