===================== Product Identification =====================
MSDS NAME:ENPLATE CU-406A
NIIN:00N091361
Status Code:A
MSDS Number: CJJTZ
=== Responsible Party ===
Company:ENTHONE-OMI INC
Box:1900
City:NEW HAVEN
State:CT
ZIP:06508
Country:US
Info Phone Num:203-934-8611
Emergency Phone Num:800-424-9300
Resp. Party Other MSDS Num.:3317-005
Preparer's Name:EARL R DARR
Chemtrec Ind/Phone:(800)424-9300
CAGE:02258
=== Contractor Identification ===
Company:ENTHONE-OMI INC.
Box:1900
City:NEW HAVEN
State:CT
ZIP:06508
Country:US
Phone:203-934-8611/ FAX 203-799-8179
CAGE:02258
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
< Wt:75.
Name:N,N,N',N'-TETRAKIS(2-HYDROXYPROPYL)ETHYLENEDIAMINE. LD50:
(ORAL,RAT) >500 MG/KG
CAS:102-60-3
RTECS #:UB5604000
< Wt:15.
Name:COPPER(II) SULFATE. LD50: (ORAL,RAT) 300 MG/KG
CAS:7758-98-7
RTECS #:GL8800000
< Wt:10.
OSHA PEL:1 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:FORMALDEHYDE. LD50: (ORAL,RAT) 100 MG/KG
CAS:50-00-0
RTECS #:LP8925000
< Wt:10.
OSHA PEL:0.75 PPM
ACGIH STEL:C0.37 MG/M3;C0.3 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:METHANOL. LD50: (ORAL,RAT) 5628 MG/KG
CAS:67-56-1
RTECS #:PC1400000
< Wt:2.
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: INHALATION: HIGHLY IRRITATING
TO NASAL PASSAGES. CAN CAUSE INFLAMMATION OF LINING OF NOSE,
THROAT, AND LUNGS. OVER EXPOSURE MAY CAUSE HEADACHE, NAUSEA,
DIZZINESS, AND BLURRING OF VISION. SKIN C ONTACT: CAN CAUSE
IRRITATION AND DERMATITIS. EYE CONTACT: VAPOR CAUSES IRRITATION AND
INFLAMMATION OF MOUTH, THROAT, AND STOMACH, AS WELL AS BLINDNESS,
STUPOR, NAUSEA, VOMITING, AND POSSIBLE DEATH. CH RONIC: MAY CAUSE
SENSITIZATION AND REDUCED VISION. LIFETIME INHALATION STUDY OF RATS
EXPOSED TO FORMALDEHYDE GAS INDICATED DEVELOPMENT OF NASAL CANCERS.
Explanation of Carcinogenicity:FORMALDEHYDE: IARC MONOGRAPHS,
SUPPLEMENT, VOL 7, PG 211, 1987: GROUP 2A. NTP 7TH ANNUAL REPORT ON
CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGEN. OSHA REGULATED
29CFR1910.1048
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:SKIN CONT: IMMED WASH CONTAMD SKIN W/PLENTY OF WATER FOR 15
MINS. REMOVE CONTAMD CLTHG & FOOTWEAR. WASH CLTHG BEFORE REUSE.
DISCARD FOOTWEAR IF IT CANNOT BE DECONTAMD. SEEK IMMED MED ATTN.
EYE CONT: I MMED FLUSH W/PLENTY OF WATER FOR AT LST15 MINS HOLDING
LIDS APART TO ENSURE FLUSHING OF ENTIRE SURF. WASHING EYES W/IN
SEVERAL SECONDS OF EXPOS IS ESSTNL TO MINIMIZE DMG. SEEK IMMED MED
ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON, OBTAIN
IMMED MED ATTN. IF VOMIT OCCURS SPONTANEOUSLY, KEEP AIRWAY CLEAR.
IF SWALLOWED DO NOT (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER FOG OR SPRAY. USE CARBON DIOXIDE. USE DRY
CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:AT HIGH TEMPERATURES MAY RELEASE TOXIC
OXIDES OF NITROGEN AND SULFUR.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID CONT W/SKIN, EYES, AND CLTHG. WEAR
PROTECTIVE EQUIPMENT (SEE EXPOSURE CONTROLS & PERSONAL PROTECTION
SECTION). DO NOT BREATHE MIST OR VAPORS. CONTAIN SPILL & SOAK UP IN
SUITABLE ABSORBENT. SHOVE L UP INTO PLASTIC-LINED STEEL CONTAINERS
AND COVER. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP AWAY
FROM ALKALIES AND OXIDIZERS. LOOSEN COVER CAUTIOUSLY WHEN OPENING.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN AIR
CONCENTRATION IS GREATER THAN THE TLV OR PEL. USE FULL FACE
NIOSH-APPROVED FORMALDEHYDE OR ACID GAS CARTRIDGE RESPIRATOR WITHIN
USE LIMITATIONS OF THESE DEVICES; IN ALL OTHER SITUATIONS, USE
NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS (SCBA).
Ventilation:LOCAL EXHAUST RECOMMENDED.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . CHEMICALLY RESISTANT COVERALLS, HAT, AND SHOES OR BOOTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRST AID PROC: INDUCE VOMIT, GIVE LG AMTS OF WATER. SEEK IMMED MED
ATTN. INHAL: REMOVE PERSON FROM CONTAMD AREA. IF BRTHG HAS STOPPED,
RESUSCITATE & ADMIN OXYG IF AVAIL. SEEK IMMED MED ATTN.
================== Physical/Chemical Properties ==================
Boiling Pt:=98.9C, 210.F
Melt/Freeze Pt:=-15.6C, 4.F
Spec Gravity:1.093
pH:5.6 CA.
Evaporation Rate & Reference:NON VOLATILE
Solubility in Water:COMPLETE
Appearance and Odor:BLUE LIQUID. PUNGENT, IRRITATING ODOR.
Percent Volatiles by Volume:2 BY WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIS, STRONG ACIDS, AND OXIDIZERS. SECONDARY AMINES.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS. SEE
INCOMPATIBILITY INFORMATION.
Hazardous Decomposition Products:OXIDES OF CARBON. COPPER SALTS.
=================== Toxicological Information ===================
Toxicological Information:N,N,N',N'-TETRAKIS (2-HYDROXYPROPYL)
ETHYLENEDIAMINE: ROUTE-ORAL, SPECIES-RAT,ADULT, EXPSOURE &
DOSE-LD50 >500 MG/KG. COPPER (II) SULFATE: ROUTE-ORAL, SPECIES-RAT,
ADULT, EXPOSURE & DOSE-300 MG/KG. FO RMALDEHYDE: ROUTE-ORAL,
SPECIES-RAT, ADULT, EXPOSURE & DOSE-LD50 100 MG/KG. METHANOL:
ROUTE-ORAL, SPECIES-RAT, ADULT, EXPOSURE & DOSE-LD50 5628 MG/KG.
===================== Ecological Information =====================
Ecological:ECOLOGICAL INFORMATION ON THIS PRODUCT IS NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR WASTE DISPOSAL OF OPERATING SOLUTIONS
CONSULT ENTHONE-OMI WASTE DISPOSAL PROCEDURES. FOR MAJOR SPILLS
CONSULT ENTHONE-OMI FOR DISPOSAL ASSISTANCE. DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE, AND F EDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:PLEASE CONTACT THE REGULATORY AFFAIRS DEPARTMENT
AT (203) 799-4917 FOR THE MOST CURRENT SHIPPING INFORMATION.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III SECTION 313: THIS PROD
CONTAINS FOLLOWING TOXIC CHEMS SUBJECT TO RPTG REQUIREMENTS OF
SECTION 313 OF EMER PLANNING & COMMUNITY RIGHT TO KNOW ACT OF 1986
AND OF 40 CFR 372: INGRED NAME: COPPER (II) SULFATE, CAS #
7758-98-7, PERCENT <10. INGRED NAME: FORMALDEHYDE, CAS # 50-00-0,
PERCENT <10. INGRED NAME: METHANOL, CAS #67-56-1, PERCENT <2.
Federal Regulatory Information:ALL INGREDIENTS COMPLY WITH APPLICABLE
RULES OR ORDERS UNDER TSCA. HMIS HAZARD RATING: HEALTH:3, FIRE: 0,
REACTIVITY: 0.
State Regulatory Information:PROP 65 (CARCINOGEN). WARNING: THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER: INGREDIENT NAME: FORMALDEHYDE; CAS#: 50-00-0;
PERCENT: <10.0.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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