===================== Product Identification =====================
MSDS NAME:1-BUTANOL, ACS
NIIN:00-241-4709
Status Code:A
MSDS Number: CJJST
=== Responsible Party ===
Company:PHOENIX INDUSTRIES INC
Address:11028 LEADBETTER RD UNIT 10
City:ASHLAND
State:VA
ZIP:23005
Country:US
Emergency Phone Num:804-264-5183/800-424-8802
Chemtrec Ind/Phone:(800)424-9300
CAGE:0YED2
=== Contractor Identification ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SPO450-99-M-NC36
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA)
CAS:71-36-3
RTECS #:EO1400000
Minumum % Wt:99.
Maxumum % Wt:100.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 790 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION-CAUSES IRRITATION TO UPPER
RESPIRATORY TRACT. INGESTION-MAY HAVE NARCOTID EFFECT. LARGE DOSES
MAY EFFECT KIDNEYS & LIVER. MAY EFFECT HEARING. SKIN-AN ITTITANT
TO THE SKIN, CAUSING A LOSS O F NATURAL OILS. EYE-VAPORS ARE
IRRITATING. SPLASHES CAUSE INFLAMMATION AND BLURRED VISION.
CHRONIC: PROLONGED SKIN CONTACT MAY CAUSE DRYING & CRACKING OF
SKIN. HEARING LOSS HAS BEEN REPORTED IN WORKE RS CHRONICALLY
EXPOSED TOBUTYL ALCOHOL. MAY AFFECT SENSE OF BALANCE, LIVER AND
KIDNEYS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION-DIFFICULT BREATHING, COUGHING,
HEADACHE, DIZZINESS AND DROWSINESS MAY OCCUR. INGESTION-MAY CAUSE
ABDOMINAL PAIN, NAUSEA, HEADACHE, DIZZINESS AND DIARRHEA.
EYE-VAPORS CAN CAUSE TEARING AND P AIN.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE/SKIN: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES, GET
MEDICAL ATTENTION . SKIN-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
15 MIN. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING
BEFORE RESU E. CALL A PHYSICIAN. INGESTION-INDUCE VOMITING
IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION-REMOVE TO FRESH AIR.
IF NOT BREATHING, GI VE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=37.2C, 99.F
Autoignition Temp:=342.8C, 649.F
Lower Limits:1.4
Upper Limits:11.2
Extinguishing Media:USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. WATER
SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. WATER MAY BE USED TO
FLUSH SPILLS AWAY FROM EXPOSURES AND TO DILUTE SPILLS TO
NON-FLAMMABLE MIXTURES.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. USEN NON-SPARKING TOOLS AND EQUIPMENT.
COLLECT LIQUID IN AN APPROPRIATE CONTAINER OR ABSORB WITH AN INERT
MATERIAL (VERMCULITE , DRY SAND OR EARTH) FOR REUSE/RECYCLINGOR
DISPOSAL. PREVENT LIQUID FROM ENTERING SEWERS, WATERWAYS OR LOW
AREAS.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. STORE
IN COOL, VENTILATED AREA, AWAY FROM IGNITION SOURCES &
INCOMPATIBLES. KEEP CONTAINER TIGHTLY CLOSED. OUTSIDE OR DETACHED
STORAGE IS PREFERRED. SEPERATE FROM INCO MPATIBLES. CONTAINERS
SHOULD BE BONDED AND GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS.
Other Precautions:WARNING! FLAMMABLE. "EMPTY" CONTAINERS RETAIN RESIDUE
AND CAN BE DANGEROUS. FOLLOW LABEL INSTRUCTIONS. KEEP OUT OF REACH
OF CHILDREN. AVOID BREATHING VAPORS. DO NOT GET IN EYE, ON SKIN OR
ON CLOTHING. STORAGE AND USE AREAS SHOULD BE NO SMOKING AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A FULL
FACEPIECE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE MAY BE WORN UPTO
50 TIMES THE EXPOSURE LIMIT OR THE MAXIMUM LIMIT SUPPLIED BY THE
RESPIRATOR SUPPLIER, WHIC HEVER IS LOWEST. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RUBBER, NEOPRENE
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLESS
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE
AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=117.8C, 244.F
B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:-128F,-89C
Vapor Pres:5 @ 68F
Vapor Density:3.6
Spec Gravity:0.87
Evaporation Rate & Reference:0.46 (N-BUTYL ACETATE=1)
Solubility in Water:9 ML/100ML @ 25C/77F
Appearance and Odor:CLEAR, COLORLESS LIQUID - MILD ALCOHOLIC ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, HALOGENS, ALUMINUM,
CHROMIUM TRIOXIDE, ALKALI METALS
Stability Condition to Avoid:HIGH HEAT, SPARKS, FLAMES, HOT SURFACES
AND INCOMPATIBLES.
Hazardous Decomposition Products:MAY EMIT CARBON MONOXIDE, CARBON
DIOXIDE.
=================== Toxicological Information ===================
Toxicological Information:ORAL RAT LD50= 790 MG/KG, INHALATION RAT
LC50= 8000 PPM/4H: SKIN RABBIT LD50= 3400 MG/K; IRRITATION,
STANDARD DRAIZE, SKIN, RABBIT, 20 MG/24H MODERATE; IRRITATION,
STANDARD DRAIZE, EYE, RABBIT, 2 MG/ 24H SEVERE; INVESTIGATED AS A
MUTAGEN,REPRODUCTIVE EFFECTOR.
===================== Ecological Information =====================
Ecological:WHEN RELAEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO
QUICKLY EVAPORATE AND READILY BIODEGRADE AND LEACH INTO GROUND
WATER. WHEN RELEASED INTO WATER, THIS MATERIAL IS EXPECTED TO
QUICKLY EVAPORAT E AND READILY BIODEGRADE. THIS MATERIALHAS A LOG
OCTANOL-WATER PARTITION COEFFICENT OF LESS THAN 3.0. IT DOES NOT
SIGNIFICANTLY BIOACCUMULATES. WHEN RELEASED INTO AIR THIS MATEIAL
IS EXPECTED TO READ ILY DEGRADED BY REACTION WITH PHOTOCHEMICALLY
PRODUCED HYDROXYL RADICALS, ANDHAS A HALF LIFE OF 1 TO 10 DAYS IN
AIR. THE LC50/96 HOUR VALUES FOR FISH ARE OVER 100 MG/L. THIS
MATERIAL IS NOT EXPECTED TO BE TOXIC TO AQUATIC LIFE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZ WASTE AND SENT TO A RCRA
APPROVED INCINERATOR OR DISPOSED OF IN A RCRA APPROVED WASTE
FACILITY. DISCHARGE, TREATMENT/ DISPO SAL IS SUBJECT TO FEDERAL,
STATE OR LOCAL LAWS.
=================== MSDS Transport Information ===================
Transport Information:PDOMESTIC * ROPER SHIPPING NAME: BUTANOLS. HAZARD
CLASS: 3. UN NO: UN1120. PACKING GROUP: III. ICAO, AIR * PROPER
SHIPPING NAME: BUTANOLS. HAZARD CLASS: 3. UN NO: UN1120. PACKING
GROUP: III.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313: LISTED. RCRA-CERCLA: 5000 LBS.
TSCA -261.33: U031
Federal Regulatory Information:RG= 5000 LBS
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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