===================== Product Identification =====================
MSDS NAME:KRYLON FOOD GRADE SILICONE SPRAY (L6), 1328
NIIN:00N092033
Status Code:A
MSDS Number: CJMJD
=== Responsible Party ===
Company:SHERWIN-WILLIAMS COMPANY
Address:101 PROSPECT AVE N W
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:800-832-2541
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:PROPANE. VP: 760.00
CAS:74-98-6
RTECS #:TX2275000
= Wt:15.
OSHA PEL:1800 MG/M3;1000 PPM
ACGIH TLV:2500 PPM
Name:HEXANE. VP: 127.00
CAS:110-54-3
RTECS #:MN9275000
= Wt:46.
OSHA PEL:1800 MG/M3;500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ISOHEXANE; (ISOHEXANE ISOMERS) VP: 250.00
CAS:107-83-5
RTECS #:SA2985000
= Wt:32.
OSHA PEL:500 PPM
ACGIH TLV:500 PPM
Name:CYCLOHEXANE. VP: 100.00
CAS:110-82-7
RTECS #:GU6300000
= Wt:2.
OSHA PEL:1050 MG/M3;300 PPM
ACGIH TLV:1030 MG/M3;300 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR
SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE
EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION, AND
PERSONAL PROTECTIVE EQUIPMENT. A CUTE: IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
SIGNS & SYMPTOMS OF OVEREXPOSURE: HEA DACHE, DIZZINESS, NAUSEA, AND
LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO
VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: CHRONIC: PROLONGED AND REPEATED
EXPOSURE TO HEXANE MAY CAUSE DAMAGE TO NERVE TISSUE OF THE ARMS AND
LEGS (PERIPHERAL NEUROPATHY), RESULTING IN MUSCULAR WEAKNESS AND
LOSS OF SENSATION. THIS E FFECT MAY BE INCREASED BY THE PRESENCE OF
METHYL ETHYL KETONE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES: FLUSH W ITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE CONSCIOUS
PATIENT SEVERAL GLAS SES OF WATER. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:<-17.8C, 0.F
PROPELLANT
Lower Limits:1.0%
Upper Limits:9.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESSUR E BUILD-UP AND POSSIBLE AUTOIGNITION OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS, & OPEN FLAME. CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PREC.
DURING EMERGENCY CNTNRS OVEREX P TO DECOMP PROD MAY CAUSE HLTH HAZ.
SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MED ATTN.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STOR CATEGORY: 1A. KEEP AWAY FROM
HEAT, SPARKS, & OPEN FLAME. VAP WILL ACCUM READILY & MAY IGNITE
EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE, KEEP AREA VENT.
DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF
STOVES, ELECTRIC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNIT.
Other Precautions:CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING
PROC. TEMP ABOVE 120F, HEAT FROM SUNLIGHT, RADIATIORS, STOVES, HOT
WATER, & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE
INTERNALLY. KEE P OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY
DELIB CONCENTRATING & INHALING CONTENTS CAN BE HAR
MFUL/FATAL.(SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS IN SECT ION 2.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE
EXPOSURE LIMITS. (SUPDAT)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
OTHER PRECS: USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR
AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. VENT: REFER TO
OSHA STANDARDS 1910.94, 1910.107, 1910.108. PHYSICAL DATA: PRODU CT
WEIGHT: 5.42 LB/GAL. VOLATILE WEIGHT: 95.00% (LESS FEDERALLY EXEMPT
SOLVENTS). HMIS: 2 * 4 0.
================== Physical/Chemical Properties ==================
Boiling Pt:<-17.8C, 0.F
B.P. Text:<0-305F
Melt/Freeze Pt:M.P/F.P Text:N.A
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.65
Evaporation Rate & Reference:FASTER THAN ETHER
Solubility in Water:N.A
Percent Volatiles by Volume:96
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE
APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DO NOT INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF IN ACORDANCE WITH FEDERAL, STAT
E, AND LOCAL REGULATIONS REGARDING POLLUTION.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: CAS NO #: 110-54-3, CHEMICAL/COMPOUND: HEXANE, % BY
WT: 46. CAS NO #: 110-82-7, CHEMICAL/COMPOUND: CYCLOHEXANE, % BY WT
2.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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